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In-cylinder flow motion has a significant effect on mixture preparation and combustion. Therefore, it is vital that CFD engine simulations are capable of accurately predicting the in-cylinder velocity fields. High-speed planar Particle Image Velocimetry (PIV) experiments have been performed on a single-cylinder GDI optical engine in order to validate CFD simulations for a range of engine conditions. Novel metrics have been developed to quantify the differences between experimental and simulated velocity fields in both alignment and magnitude. The Weighted Relevance Index (WRI) is a variation of the standard Relevance Index that accounts for the local velocity magnitudes to provide a robust comparison of the alignment between two vector fields. Similarly, the Weighted Magnitude Index (WMI) quantifies the differences in the local magnitudes of the two velocity fields.