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Technical Paper

Understanding Catalyst Overheating Protection (COP) as a Source of Post-TWC Ammonia Emissions from Petrol Vehicle

2022-08-30
2022-01-1032
TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated.
Technical Paper

Kinetic Measurements of HNCO Hydrolysis over SCR Catalyst

2018-09-10
2018-01-1764
To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.
Journal Article

Prediction of Spray Behavior in Injected by Urea SCR Injector and the Reaction Products

2017-10-08
2017-01-2375
In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.
Technical Paper

The Application of Solid Selective Catalytic Reduction on Heavy-Duty Diesel Engine

2017-10-08
2017-01-2364
Urea SCR technology is the most promising technique to reduce NOx emissions from heavy duty diesel engines. 32.5wt% aqueous urea solution is widely used as ammonia storage species for the urea SCR process. The thermolysis and hydrolysis of urea produces reducing agent ammonia and reduces NOx emissions to nitrogen and water. However, the application of urea SCR technology has many challenges at low temperature conditions, such as deposits formation in the exhaust pipe, lack deNOx performance at low temperature and freezing below -12°C. For preventing deposits formation, aqueous urea solution is hardly injected into exhaust gas stream at temperature below 200°C. The aqueous urea solution used as reducing agent precursor is the main obstacle for achieving high deNOx performances at low temperature conditions. This paper presents a solid SCR technology for control NOx emissions from heavy duty diesel engines.
Technical Paper

Analysis of Spray Feature Injected by Tailpipe Injector for Aftertreatment of Diesel Engine Emissions

2017-10-08
2017-01-2373
Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.
Technical Paper

Effects of Electrically Heated Catalyst on the Low Temperature Performance of Vanadium-Based SCR Catalyst on Diesel Engine

2014-04-01
2014-01-1527
The NOx conversion efficiency of vanadium-based SCR catalyst is lower under low temperature. Utilizing an exhaust analyzer, the effects of electrically heated catalyst on the performance of vanadium-based SCR catalyst under low temperature was studied on the engine test bench. The inlet temperature of SCR catalyst without the electrically heated catalyst were in the range of 150°C∼270°C under various steady engine modes, and the NSR (Normalized Stoichiometric Ratio) was set as 0.4,0.6,0.8,1.0. The results showed that under the space velocity of 20000h−1, with the application of the electrically heated catalyst, the inlet temperature of SCR increased about 19.9°C on average and the NOx conversion efficiency improved about 8.0%. The NOx conversion efficiency increased 1.7%∼8.6% at the temperatures of 150°C∼174°C, and 1.0%∼15.9% at the temperatures of 186°C∼270°C.
Journal Article

Comparison of Fires in Lithium-Ion Battery Vehicles and Gasoline Vehicles

2014-04-01
2014-01-0428
Electric vehicles have become more popular and may be involved in fires due to accidents. However, characteristics of fires in electric vehicles are not yet fully understood. The electrolytic solution of lithium-battery vehicles is inflammable, so combustion characteristics and gases generated may differ from those of gasoline cars. Therefore, we conducted fire tests on lithium-ion battery vehicles and gasoline vehicles and investigated the differences in combustion characteristics and gases generated. The fire tests revealed some differences in combustion characteristics. For example, in lithium-ion battery vehicles, the battery temperature remained high after combustion of the body. However, there was almost no difference in the maximum CO concentration measured 0.5 to 1 m above the roof and 1 m from the side of the body. Furthermore, HF was not detected in either type of vehicle when measured at the same positions as for CO.
Technical Paper

Impact of Fuel Metal Impurities on the Durability of a Light-Duty Diesel Aftertreatment System

2013-04-08
2013-01-0513
Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).
Technical Paper

Advanced Urea SCR System Study with a Light Duty Diesel Vehicle

2012-04-16
2012-01-0371
U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.
Technical Paper

A Visualization Test Setup for Investigation of Water-Deposit Interaction in a Surrogate Rectangular Cooler Exposed to Diesel Exhaust Flow

2012-04-16
2012-01-0364
Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.
Journal Article

An Experimental Study on the Fire Response of Vehicles with Compressed Hydrogen Cylinders

2010-04-12
2010-01-0134
To investigate the events that could arise when fighting fires in vehicles with carbon fiber reinforced plastic (CFRP) hydrogen storage cylinders, we conducted experiments to examine whether a hydrogen jet diffusion flame caused by activation of the pressure relief device (PRD) can be extinguished and how spraying water influences the cylinder and PRD. The experiments clarified that the hydrogen jet flame cannot be extinguished easily with water or dry powder extinguishers and that spraying water during activation of the PRD may result in closure of the PRD, but is useful for maintaining the strength of CFRP composite cylinders for vehicles.
Technical Paper

Impact Study of High Biodiesel Blends on Exhaust Emissions to Advanced Aftertreatment Systems

2010-04-12
2010-01-1292
In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).
Technical Paper

An Experimental Investigation on Removing PM and NOX Simultaneously from Diesel Exhaust

2008-06-23
2008-01-1793
In order to achieve simultaneous removal of particulate matters (PM) and NOX in diesel exhaust, a new kind of aftertreatment prototype has been developed. The prototype combined effects of static, cyclone, non-thermal plasma and hydrocarbon selective catalytic reduction. Experiments have been carried out with standard gases simulating diesel exhaust. Physical and chemical effects that took place in the prototype are as follows: the collection of PM by electrostatic-cyclone system, the oxidative combustion of PM, the selective catalytic reduction of NOX, and the reaction between PM and NOX. The effect of non-thermal plasma makes the density of NO decrease and that of NO2 increase, whereas, the amount of NOX remains the same. Employing catalyst coupled with non-thermal plasma debase the temperature by about 50◻, there the peak value of transform rate appears.
Technical Paper

Thermal Behavior in Hydrogen Storage Tank for FCV on Fast Filling (2nd Report)

2008-04-14
2008-01-0463
If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.
Technical Paper

Safety Evaluation on Fuel Cell Stacks Fire and Toxicity Evaluation of Material Combustion Gas for FCV

2007-04-16
2007-01-0435
Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.
Technical Paper

Potential of Nanoparticle Formation by Vehicles

2006-04-03
2006-01-0622
For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.
Technical Paper

Analysis of Low Concentration Aldehyde and Ketone Compounds in Automotive Exhaust Gas by New Collection Reagent.

2005-05-11
2005-01-2152
Acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are commonly used for the collection of automotive exhaust carbonyl compounds. There are some DNPH-carbonyl compounds in not in use DNPH cartridges and DNPH solution. Furthermore, concentrations of automotive exhaust carbonyl compounds are decreasing according to improvement of the purification technology for automotive exhaust. Automotive exhaust carbonyl compounds become to be difficult to be analyzed with DNPH collection method, because of these two reasons. It is thought that reliable analysis of acrolein in automotive exhaust is very difficult because concentration of DNPH-acrolein in extracted solution is not stable. Furthermore, it is found out that DNPH-acrolein in DNPH-cartridge is disappeared for short time storage in this research.
Technical Paper

Lubricity of Liquefied Gas Assessment of Multi-Pressure/Temperature High-Frequency Reciprocating Rig (MPT-HFRR) -DME Fuel for Diesel

2004-06-08
2004-01-1865
In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.
Technical Paper

Feasibility Study of Urea SCR Systems on Heavy Duty Commercial Vehicles

2004-06-08
2004-01-1944
Four urea SCR systems were developed and evaluated on a C/D and on the road to investigate their potential for Japanese emission regulations in 2005 and beyond. Test results showed that NOx conversion ratios were 50 to 70% during the Japanese D13 mode cycle, and the ratios under the transient driving cycle were lower than those tested during a steady state. Unregulated emissions, such as benzene, aldehyde and benzo[a]pyrene, existed either at a trace level using the oxidation catalyst, or lower than a base diesel engine, when no oxidation catalyst was used. The health effects of particulate matter emitted from the SCR system were almost the same as those from conventional diesel engines, as evaluated by the Ames test and in vitro micronucleus test. Thermal degradation products, such as cyanuric acid and melamine, were two to four figures lower compared with the toxicological information of Safety Information Resources Inc. (SIRI).
Technical Paper

Regional Trade and Emission Gas in Asian Automobile Industry

2001-11-12
2001-01-3761
This paper is an attempt to estimate the traffic demand of private vehicles in the Philippines and Thailand toward 2030. Estimation of road traffic volume is one of the most important elements for determining fuel consumption and emission gas levels. The level of passenger car ownership is still low, but there has been a distinct shift toward passenger cars due to the lack of mass transport. In Asian countries, inspection and maintenance and emission standards are the most important policy measures. The projections of car stock are evaluated as the emissions of PM, CO and NOx by applying these policy measures in the case of Thailand.
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