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A fuel reforming technology using a low temperature oxidation was developed to improve a NOx reduction performance of HC-SCR (Hydrocarbons Selective Catalytic Reduction) system, which does not require urea. The low-temperature oxidization of a diesel fuel in gas phase produces NOx reduction agents with high NOx reduction ability such as aldehydes and ketones. A pre-evaporation-premixing-type reformer was adopted in order to generate a uniform temperature field and a uniform fuel/air premixed gas, and to promote the low temperature oxidation efficiently. As a fundamental study, elementary reaction analysis for n-hexadecane/air premixtures was carried out to investigate the suitable reformer temperature and fuel/air equivalence ratio for generation of oxygenated hydrocarbons. It was found that the reforming efficiency was highest at the reforming temperature around 623 to 673K, and aldehydes and ketones were produced.

Understanding and prediction of flash-boiling spray behavior in gasoline direct-injection (GDI) engines remains a challenge. In this study, computational fluid dynamics (CFD) simulations using the homogeneous relaxation model (HRM) for not only internal nozzle flow but also external spray were evaluated using CONVERGE software and compared to experimental data. High-speed extinction imaging experiments were carried out in a real-size axial-hole transparent nozzle installed at the tip of machined GDI injector fueled with n-pentane under various ambient pressure conditions (Pa/Ps = 0.07 - 1.39). The width of the spray during injection was assessed by means of projected liquid volume, but the structure and timing for boil-off of liquid within the sac of the injector were also assessed after the end of injection, including cases with different designed sac volumes.

An accurate prediction of internal nozzle flow in fuel injector offers the potential to improve predictions of spray computational fluid dynamics (CFD) in an engine, providing a coupled internal-external calculation or by defining better rate of injection (ROI) profile and spray angle information for Lagrangian parcel computations. Previous research has addressed experiments and computations in transparent nozzles, but less is known about realistic multi-hole diesel injectors compared to single axial-hole fuel injectors. In this study, the transient injector opening and closing is characterized using a transparent multi-hole diesel injector, and compared to that of a single axial hole nozzle (ECN Spray D shape). A real-size five-hole acrylic transparent nozzle was mounted in a high-pressure, constant-flow chamber. Internal nozzle phenomena such as cavitation and gas exchange were visualized by high-speed long-distance microscopy.

An on board burner that enables DPF regeneration even when an engine is at standstill has been researched. By employing pre evaporative combustion with a wick burner, miniaturization of the burner system was successfully accomplished as well as stable ignition and combustion. Total heat necessary for DPF regeneration was reduced in comparison to the active DPF regeneration by means of engine control and an oxidation catalyst. Uneven temperature distribution in DPF and excessive temperature rise, which had been recognized as issues in the regeneration of a DPF while engine is at standstill, were solved by increase of combustion air amount and multi-step control of regeneration temperature and reliable regeneration was accomplished.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

In order to improve the brake thermal efficiency of the engine, such as cooling and friction losses from the theoretical thermal efficiency, it is necessary to minimize various losses. However, it is also essential to consider improvements in theoretical thermal efficiency along with the reduction of the various losses. In an effort to improve the brake thermal efficiency of heavy-duty diesel engines used in commercial vehicles, this research focused on two important factors leading to the engine's theoretical thermal efficiency: the compression ratio and the specific heat ratio. Based on the results of theoretical thermodynamic cycle analyses for the effects of the above two factors, it was predicted that raising the compression ratio from a base engine specification of 17 to 26, and increasing the specific heat ratio would lead to a significant increase in theoretical thermal efficiency.

Urea selective catalyst reduction (SCR) systems have a high NOx conversion rate because the ammonia formed by the hydrolyzing urea solution reacts with NOx efficiently as a reducing agent. Systems combining urea-SCR and a diesel particulate filter (DPF) have been adopted in heavy duty vehicles to meet the post new long term emissions regulations in Japan. This study examined the emissions reduction performance of these systems after 160,000 km. The emissions that were examined included both regulated emissions (NOx, PM, HC, and CO) and unregulated emissions. As a result, the cleanness of diesel emissions from a urea-SCR and DPF system was confirmed.

1 To meet the Japan Post New-Long-Term (Japan 2009) emissions regulation introduced in 2009, The Hydrocarbon Selective Catalytic Reduction (HC-SCR) system for the NOx emission with a diesel fuel was chosen among various deNOx after-treatment systems (the Urea-SCR, the NOx storage-Reduction Catalyst and so on). The HC-SCR was adopted, in addition to combustion modification of diesel engine (mainly cooled EGR) as the New DPR system. The New DPR system for medium and light duty vehicles was developed as a world's first technology by Hino Motors. Advantages of the New DPR are compact to easy-to-install catalyst converter and no urea solution (DEF) injection (regardless urea infrastructure) as compared the Urea-SCR system.

Diesel engine has a good fuel economy and high durability and used widely for power source such as heavy duty in the world. On the other hand, it is required to reduce NOx (Nitrogen Oxides) and PM (Particulate Matter) emissions further from diesel exhaust gases to preserve atmosphere. The urea-SCR (Selective Catalytic Reduction) system is the most promising measures to reduce NOx emissions. DPF (Diesel Particulate Filter) system is commercialized for PM reduction. However, in case that a vehicle has a slow speed as an urban area driving, a diesel exhaust temperature is too low to activate SCR catalyst for NOx reduction in diesel emissions. Moreover, the diesel exhaust temperature becomes lower as a future engine has less fuel consumption. The purpose of this study is reduction of NOx emission from a heavy-duty diesel engine using the Urea SCR system at the low temperature.

To reduce NOx emissions from a heavy-duty engine at low exhaust temperature conditions, the plasma-assisted SCR (Selective Catalytic Reduction) system was evaluated. The plasma-assisted SCR system is mainly composed of an ammonia gas supply system and a plasma reactor including a pellet type SCR catalyst. The preliminary test with simulated gases of diesel exhaust showed an improvement in the NOx reduction performance by means of the plasma-assisted SCR system, even below 150°C conditions. Furthermore, NOx reduction ratio was improved up to 77% at 110°C with increase in the catalyst volume. Also NOx emissions from a heavy-duty diesel engine over the transient test mode in Japan (JE05) were reduced by the plasma-assisted SCR system. However, unregulated emissions, e.g., aldehydes, were increased with the plasma environment. This paper reports the advantages and disadvantages of the plasma-assisted SCR system for a heavy-duty diesel engine.

EPA 2010 emissions regulations - currently the strictest standards in the world - place particular emphasis on exhaust gas thermal control technology. The Burner System, a device developed to control exhaust gas temperatures, is the most effective means of raising exhaust gas temperature, as this system can function under any engine conditions, including low engine speed and torque. The Burner System begins operating immediately when the engine is started, activating the Diesel Exhaust Fluid (DEF) - Selective Catalytic Reduction (SCR) System immediately, because the Burner System is active, it enables the diesel particulate filter active regeneration under any engine operating conditions as well. This technical paper reports Burner System (ActiveClean™ Thermal Regenerator) development results.

The U.S. Environmental Protection Agency (EPA) issued new emissions regulations, which came into effect in January, 2010. These EPA 2010 regulations are the most stringent emissions standards in the world, reducing both particulate matter (PM) and nitrogen oxides (NOx) to nearly zero levels. Hino Motors improved upon its previous EPA 2007-compliant engine, developing a new exhaust after-treatment system in which a Diesel Particulate active Reduction System (DPR), a Urea-Selective Catalytic Reduction (SCR) System and a Burner System are employed to meet EPA 2010 emissions regulations for medium duty commercial vehicles. DPR was already developed and utilized to reduce PM to meet EPA 2007 standards, but the Urea-SCR System is newly developed technology used to reduce NOx emissions to comply with EPA2010 emissions regulations. In addition, a Burner System is used to elevate exhaust gas temperatures in order to improve both SCR performance and DPR active Regeneration.

The new Diesel Particulate active Reduction (DPR) system was developed for a medium-duty commercial vehicle as a deNOx catalyst combined with the conventional DPR system to achieve the Japan Post New-Long-Term (JPNLT) emissions regulations. It consists of a catalyst converter named as the new DPR cleaner, a fuel dosing injector, NOx sensors, temperatures and pressure sensors. The new DPR cleaner was constructed from a Front Diesel Oxidation Catalyst (F-DOC), a catalyzed particulate Filter (Filter), and a Rear Diesel Oxidation Catalyst (R-DOC). A newly developed Hydrocarbon Selective Catalyst Reduction (HC-SCR) catalyst was employed for each catalyst aiming to reduce NOx emissions with diesel fuel supplied from the fuel dosing injector. While the total volume of the catalyst was increased, the compact and easy-to-install catalyst converter was realized through the optimization of the flow vector and flow distribution in it by means of Computational Fluid Dynamics (CFD) analysis.

This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

The emissions reduction potential of neat GTL (Gas to Liquids: Fischer-Tropsch synthetic gas-oil derived from natural gas) fuels has been preliminarily evaluated by three different latest-generation diesel engines with different displacements. In addition, differences in combustion phenomena between the GTL fuels and baseline diesel fuel have been observed by means of a single cylinder engine with optical access. From these findings, one of the engines has been modified to improve both exhaust emissions and fuel consumption simultaneously, assuming the use of neat GTL fuels. The conversion efficiency of the NOx (oxides of nitrogen) reduction catalyst has also been improved.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.