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The Mars Science Laboratory will be the next Martian mobility system that is scheduled to launch in the fall of 2011. The ChemCam Instrument is a part of the MSL science payload suite. It is innovative for planetary exploration in using a technique referred to as laser breakdown spectroscopy to determine the chemical composition of samples from distances of up to about 9 meters away. ChemCam is led by a team at the Los Alamos National Laboratory and the Centre d'Etude Spatiale des Rayonnements in Toulouse, France. The portion of ChemCam that is located inside the Rover, the ChemCam Body Unit contains the imaging charged-coupled device (CCD) detectors. Late in the design cycle, the ChemCam team explored alternate thermal design architectures to provide CCD operational overlap with the Rover's remote sensing instruments. This operational synergy is necessary to enable planning for subsequent laser firings and geological context.

Thermal characterization was performed on a vapor compression heat pump using a novel, hybrid two phase loop design. Previous work on this technology has demonstrated its ability to provide passive phase separation and flow control based on capillary action. This provides high quality vapor to the compressor without relying on gravity-based phase separation or other active devices. This paper describes the subsequent work done to characterize evaporator performance under various startup scenarios, tilt angles, and heat loads. The use of a thermal expansion valve as a method to regulate operation was investigated. The effect of past history of use on startup behavior was also studied. Testing under various tilt angles showed evaporator performance to be affected by both adverse and favorable tilts for the given compressor. And depending on the distribution of liquid in the system upon startup, markedly different performance can result for the same system settings and heat loads.

Passively activated thermal control valves were developed for use in a mechanically pumped single-phase fluid liquid loop (MPFL) of the Mars Science Laboratory (MSL) rover. A key approach to the thermal control of the rover with the fluid loop is to control the flow through the rover's heat generating or heat rejecting components. This is achieved by either splitting or mixing the fluid stream coming from different branches of the system at different temperatures; actively or passively controlled flow valves are typically used for such purposes. To meet the thermal control requirements of the Mars Science Laboratory (MSL) rover, a splitting and a mixing thermal control valves with gradual control capabilities using a linear thermal actuator and a spool was developed at Jet Propulsion Laboratory (JPL). The key feature of these control valves is the balancing of the flow through the various branches of the fluid loop in order to balance the heat loads of the whole thermal system.

The Internal Active Thermal Control System (IATCS) aboard the International Space Station (ISS) contains an aqueous, alkaline fluid (pH 9.5±0.5) that aids in maintaining a habitable environment for the crew. Because microbes have significant potential to cause disease, adverse effects on astronaut health, and microbe-induced corrosion, the presence of both bacteria and viruses within IATCS fluids is of concern. This study sought to detect and identify viral populations in IATCS samples obtained from the Kennedy Space Center as a first step towards characterizing and understanding potential risks associated with them. Samples were concentrated and viral nucleic acids (NA) extracted providing solutions containing 8.87-22.67 μg NA per mL of heat transfer fluid. After further amplification viral DNA and cDNA were then pooled, fluorescently labeled, and hybridized onto a Combimatrix panvira 12K microarray containing probes for ∼1,000 known human viruses.

Phoenix, NASA's first Mars Scouts mission, will be launched in 2007 and will soft-land inside the Martian Arctic Circle, between north 65° and 72° North latitude, in 2008 to study the water history and to search for habitable zones. Similar to the IDD (Instrument Deployment Device) on the Mars Exploration Rovers (MER), Phoenix has a Robotic Arm (RA) which is equipped with a scoop to dig into the icy soil and to deliver the soil samples to instruments for scientific observations and measurements. As with MER, the actuators and the bearings of the Phoenix RA in a non-operating condition can survive the cold Martian night without any electrical power or any thermal insulation. The RA actuators have a minimum operating allowable flight temperature (AFT) limit of -55°C, so, warm-up heaters are required to bring the temperatures of all the RA actuators above the operating AFT limit prior to early morning operation.

Future planetary science missions planned for Mars are expected to be more complex and thermally challenging than any of the previous missions. For future rovers, the operational parameters such as landing site latitudes, mission life, distance traversed, and rover thermal energy to be managed will be significantly higher (two to five times) than the previous missions. It is a very challenging problem to provide an effective thermal control for the future rovers using traditional passive thermal control technologies. Recent investigations at the Jet Propulsion Laboratory (JPL) have shown that mechanical pump based fluid loops provide a robust and effective thermal control system needed for these future rovers. Mechanical pump based fluid loop (MPFL) technologies are currently being developed at JPL for use on such rovers. These fluid loops are planned for use during spacecraft cruise from earth to Mars and also on the Martian surface operations.

Certain Eubacteria enter a viable but nonculturable (VBNC) state upon encountering unfavorable environmental conditions. VBNC cells do not divide on conventional media yet remain viable and in some cases retain virulence. Here, we describe the VBNC state of two opportunistic pathogens previously isolated from ISS potable waters, Burkholderia cepacia and Stenotrophomonas maltophilia. Artificially inoculated microcosms were exposed to the biocidal agents copper (CuSO4) and iodine (I2) in an attempt to induce nonculturablility. Viability was assessed via fluorescent microscopy (direct viable count assay coupled with BacLight™ staining) and metabolic activity was monitored by quantifying both intracellular ATP and transcribed rRNA (reverse transcriptase quantitative PCR). Culturablility was lost in both B. cepacia and S. maltophilia within two days of exposure to copper or high concentrations of iodine (6 or 8 ppm).

Mechanically pumped single-phase fluid loops are well suited for transporting and rejecting large amounts of waste heat from spacecraft electronics and power supplies. While past implementations of such loops on spacecraft have used moderate operating temperatures (less than 60ºC), higher operating temperatures would allow equivalent heat loads to be rejected by smaller and less massive radiators. A high temperature (100 to 150ºC) mechanically pumped fluid loop is currently being investigated at the Jet Propulsion Laboratory (JPL) for use on future Mars missions. This paper details the trade study used to select the high temperature working fluid for the system and the initial development testing of loop components.

The Mars Exploration Rover (MER) flight system uses mechanical, paraffin-actuated heat switches as part of its secondary battery thermal control system. This paper describes the design, flight qualification, and performance of the heat switch. Although based on previous designs by Starsys Research Corporation1,2, the MER mission requirements have necessitated new design features and an extensive qualification program. The design utilizes the work created by the expansion of a paraffin wax by bringing into contact two aluminum surfaces, thereby forming a heat conduction path. As the paraffin freezes and contracts, compression springs separate the surfaces to remove the conduction path. The flight qualification program involved extensive thermal performance, structural, and life testing.

The Trace Gas Analyzer (TGA, Figure 1) is a self-contained, battery-powered mass spectrometer that is designed for use by astronauts during extravehicular activities (EVA) on the International Space Station (ISS). The TGA contains a miniature quadrupole mass spectrometer array (QMSA) that determines the partial pressures of ammonia, hydrazines, nitrogen, and oxygen. The QMSA ionizes the ambient gas mixture and analyzes the component species according to their charge-to-mass ratio. The QMSA and its electronics were designed, developed, and tested by the Jet Propulsion Laboratory (1,2). Oceaneering Space Systems supported JPL in QMSA detector development by performing 3D computer for optimal volumetric integration, and by performing stress and thermal analyses to parameterize environmental performance.

As a result of the Viking missions in 1970s, the presence of a strong oxidant in Martian soil was suggested. Here we present a testable, by near-term missions, hypothesis that iron(VI) contributes to that oxidizing pool. Ferrate(VI) salts were studied for their spectral and oxidative properties and biological activities. Ferrate(VI) has distinctive spectroscopic features making it available for detection by remote sensing reflectance spectra and contact measurements via Mössbauer spectroscopy. The relevant miniaturized instrumentation has been developed or is underway, while XANES spectroscopy is shown to be a method of choice for the returned samples. Ferrate(VI) is capable of splitting water to yield oxygen, and oxidizing organic carbon to CO2. Organic oxidation was strongly abated after pre-heating ferrate, similar to the observations with Mars soil samples.

The development of tunable diode laser systems in the 2 - 5 μm spectral region will have numerous applications for trace gas detection. To date, the development of such systems has been hampered by the difficulties of epitaxial growth, and device processing in the case of the Sb-based materials system. One of the compounding factors in this materials system is the use of aluminum containing compounds in the laser diode cladding layers. This makes the regrowth steps used in traditional lasers very difficult. As an alternative approach we are developing laterally coupled antimonide based lasers structures that do not require the regrowth steps. In this paper, the materials growth, device processing and development of the necessary drive electronics for an antimony based tunable diode laser system are discussed.

The Jet Propulsion Laboratory Mars Exploration Program Office is currently planning a series of exciting missions to the Red Planet. During each launch opportunity, the missions to Mars will include a Rover mission. During the earlier Rover missions to Mars such as the Mars Pathfinder mission carrying the Sojourner Rover in 1997, the main rover power source was a solar array. The power subsystem of the Sojourner Rover included a solar panel for power during the day, a non-rechargeable lithium battery for power during the night, and a power electronics board for power conditioning and distribution. Starting with the year 2003 the rover missions to Mars will incorporate a rechargeable energy storage device rather than a non-rechargeable power source. Included in the power electronics board, will be a battery controller/charger. The battery controller/charger will be able to monitor and control three parallel 4-cell battery strings.

The power produced by an AMTEC is dependent on the porosity of the electrode layers deposited on the surface of the BASE tubes. The elevated temperatures at which these power generators operate result in a slow growth or coalescence of the grains that comprise the electrode layers thereby reducing porosity and effective surface area. The lifetime of AMTEC electrodes is therefore related to the rate of grain growth of the electrode material. A preliminary model has been developed to determine the rate of grain growth over the operational lifetime of an AMTEC. This model examines the conditions for continuous growth as a function of the relative sizes, boundary and activation energies and mobilities of the grains. An assumption of strain-free growth has been made in determining the factors for normal growth. Experimental measurements for titanium nitride alloy electrodes are compared with this model. Predictions are made for performance lifetimes out to 10 years.

The lifetime of an AMTEC electrode is predicted from the rate of grain growth in the electrode. The rate of growth depends on several physical characteristics of each material, including the rate of diffusion of the material on itself. Grain growth rates for rhodium-tungsten and titanium nitride electrodes have been determined, and have been used to predict operating lifetimes of AMTEC electrodes. For lifetimes of 10 years or more, RhxW electrodes may be used at any operating temperature supportable by the electrolyte. TiN electrodes may be used in AMTEC cells only at operating temperatures under 1150 K.

This paper reports several slow reversible and quasi-reversible processes which occur in the porous electrode/solid electrolyte combination at AMTEC operating temperatures. These processes help to elucidate the evolution of the electrode and electrolyte characteristics with time. They also demonstrate that the atomic constituents of the electrode/electrolyte engage in significant dynamic motion. We report the stability of the sodium beta“-alumina phase in low pressure sodium vapor at 1173K up to 3000 hours, and the decomposition of the sodium meta-aluminate (NaAlO2) phase present at about 1% in the BASE ceramic, which gives rise to transient local increases in the solid electrolyte resistivity due to local micro-cracking. We also report slow apparent morphological changes, possibly surface or grain boundary reconstruction, in TiN and RhW electrodes driven by changes in the local sodium activity.

We have elicited a reliable Raman spectral signature for glucose in rabbit aqueous humor across mammalian physiological ranges in a rabbit model stressed by recent myocardial infarction. The technique employs near infrared Raman laser excitation at 785 nm, multivariate analysis, non-linear artificial neural networks and an offset spectra subtraction strategy. Aqueous humor glucose levels ranged from 37 to 323 mg/dL. Data were obtained in 80 uL samples to anticipate the volume constraints imposed by the human and rabbit anterior chamber of the eye. Total sample collection time was 10 seconds with total power delivered to sample of 30 Mw. Spectra generated from the aqueous humor were compared qualitatively to artificial aqueous samples and an excitation offset technique was devised to counteract broadband background noise partially obscuring the glucose signature.