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The introduction of real driving emissions cycles and increasingly restrictive emissions regulations force the automotive industry to develop new and more efficient solutions for emission reductions. In particular, the cold start and catalyst heating conditions are crucial for modern cars because is when most of the emissions are produced. One interesting strategy to reduce the time required for catalyst heating is post-oxidation. It consists in operating the engine with a rich in-cylinder mixture and completing the oxidation of fuel inside the exhaust manifold. The result is an increase in temperature and enthalpy of the gases in the exhaust, therefore heating the three-way-catalyst. The following investigation focuses on the implementation of post-oxidation by means of scavenging in a four-cylinder, turbocharged, direct injection spark ignition engine. The investigation is based on detailed measurements that are carried out at the test-bench.

Intensified emission regulations as well as consumption demands lead to an increasing significance of carbon monoxide (CO) emissions for diesel engines. On the one hand, the quantity of CO raw emissions is important for emission predictions as well as for the exhaust gas after treatment. On the other hand, CO emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the CO molecules. Due to these reasons, a simulation model for predicting CO raw emissions was developed for diesel engines based on a phenomenological two-zone model. The CO model takes three main sources of CO emissions of diesel engines into account: Firstly, it contains a sub model that describes CO from local understoichiometric areas. Secondly, CO emissions from overmixed regions are considered.

Intensified emission regulations as well as consumption demands lead to an increasing significance of unburned hydrocarbon (UHC) emissions for diesel engines. On the one hand, the quantity of hydrocarbon (HC) raw emissions is important for emission predictions as well as for the exhaust after treatment. On the other hand, HC emissions are also important for predicting combustion efficiency and thus fuel consumption, since a part of unreleased chemical energy of the fuel is still bound in the HC molecules. Due to these reasons, a simulation model for predicting HC raw emissions was developed for diesel engines based on a phenomenological two-zone model. The HC model takes three main sources of HC emissions of diesel engines into account: Firstly, it contains a sub-model that describes the fuel dribble out of the injector after the end of injection. Secondly, HC emissions from cold peripheral zones near cylinder walls are determined in another sub-model.

In order to optimize spray layouts of commonly used high-pressure injectors for gasoline direct injection (GDI) engines featuring multi-hole valve seats, a detailed understanding of the cause-effect relation between inner spray hole geometries and inner flow conditions, initializing the process of internal mixture formation, is needed. Therefore, a novel measurement setup, capable of determining spray hole individual mass flow rates, is introduced and discussed. To prove its feasibility, a 2-hole configuration is chosen. The injected fuel quantities are separated mechanically and guided to separate pressure tight measurement chambers. Each measurement chamber allows for time resolved mass flow rate measurements based on the HDA measurement principle (German: “Hydraulisches Druck-Anstiegsverfahren”).

Further improvements of internal combustion engines to reduce fuel consumption and to face future legislation constraints are strictly related to the study of mixture formation. The reason for that is the desire to supply the engine with homogeneous charge, towards the direction of a global stoichiometric blend in the combustion chamber. Fuel evaporation and thus mixture quality mostly depend on injector atomization features and charge motion within the cylinder. 3D-CFD simulations offer great potential to study not only injector atomization quality but also the evaporation behavior. Nevertheless coupling optical measurements and simulations for injector analysis is an open discussion because of the large number of influencing parameters and interactions affecting the fuel injection’s reproducibility. For this purpose, detailed numerical investigations are used to describe the injection phenomena.

As a consequence of reduced fuel consumption, direct injection gasoline engines have already prevailed against port fuel injection. However, in-cylinder fuel homogenization strongly depends on charge motion and injection strategies and can be challenging due to the reduced available time for mixture formation. An insufficient homogenization has generally a negative impact on the combustion and therefore also on efficiency and emissions. In order to reach the targets of the intensified CO2 emission reduction, further increase in efficiency of SI engines is essential. In this connection, 0D/1D simulation is a fundamental tool due to its application area in an early stage of development and its relatively low computational costs. Certainly, inhomogeneities are still not considered in quasi dimensional combustion models because the prediction of mixture formation is not included in the state of the art 0D/1D simulation.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

High-speed video imaging in a swirl-supported (Rs = 1.7), direct-injection heavy-duty diesel engine operated with moderate-to-high EGR rates reveals a distinct correlation between the spatial distribution of luminous soot and mean flow vorticity in the horizontal plane. The temporal behavior of the experimental images, as well as the results of multi-dimensional numerical simulations, show that this soot-vorticity correlation is caused by the presence of a greater amount of soot on the windward side of the jet. The simulations indicate that while flow swirl can influence pre-ignition mixing processes as well as post-combustion soot oxidation processes, interactions between the swirl and the heat release can also influence mixing processes. Without swirl, combustion-generated gas flows influence mixing on both sides of the jet equally. In the presence of swirl, the heat release occurs on the leeward side of the fuel sprays.

Emissions standards are becoming increasingly harder to reach without the use of exhaust aftertreatment systems such as Selective Catalytic Reduction and particulate filters. In order to make efficient use of these systems it is important to have accurate models of engine-out emissions. Such models are also useful for optimizing and controlling next-generation engines without aftertreatment using for example exhaust gas recirculation (EGR). Engines are getting more advanced using systems such as common rail fuel injection, variable geometry turbochargers (VGT) and EGR. With these new technologies and active control of the injection timing, more sophisticated models than simple stationary emission maps must be used to get adequate results. This paper is focused on the calculation of engine-out NOx and engine parameters such as cylinder pressure, temperature and gas flows.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. It is important to gain knowledge of the constraints and limits on the possible operating region. In this work, the emphasis is on investigating how cycle-to-cycle and cylinder-to-cylinder deviations limit the operating region, how these effects change in different parts of the operating region and how they can be controlled. At low load the cycle-to-cycle phenomena cause periodic behavior in combustion timing; together with cylinder deviations this is found responsible for decreasing the operating regime.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. This implementation requires only minor modifications of the standard SI engine and allows SI operation outside the operating range of HCCI. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. A heat exchanger is utilized to heat or cool the intake air, not as a means of combustion control but in order to simulate realistic variations in ambient temperature. The combustion is monitored in real time using cylinder pressure sensors. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. However, for a practical application the intake temperature will vary both geographically and from time to time.

Although there seems to be a consensus regarding the low emission potential of DME, there are still different opinions about why the low NOx emissions can be obtained without negative effects on thermal efficiency. Possible explanations are: The physical properties of DME affecting the spray and the mixture formation Different shape and duration of the heat release in combination with reduced heat losses In this paper an attempt is made to increase the knowledge of DME in relation to diesel fuel with respect to heat release and NOx formation. The emphasis has been to create injection conditions as similar as possible for both fuels. For that purpose the same injection system (CR), injection pressure (270 bar), injection timing and duration have been used for the two fuels. The only differences were the diameters of the nozzle holes, which were chosen to give the same fuel energy supply, and the physical properties of the fuels.

Methane and nitric oxide conversion was studied over a Pd-based catalyst at steady state conditions. The gas mixture contained methane (0.125 %), Nitric oxide (0.125 %), carbon monoxide (0.7 %), oxygen and argon as carrier gas. The experiments were performed in a well-stirred reactor (Berty reactor) which provided constant gas composition over the catalyst. Lambda scans from λ=1.01 to 0.99 and back performed by varying the oxygen content, revealed a hysteresis in both the methane conversion and the nitric oxide conversion. The temperature and presence of nitric oxide affected the hysteresis. Complementary experiments in a synthetic exhaust gas rig revealed a more pronounced hysteresis in the presence of carbon dioxide and water. An attempt to model the hysteresis effect as a function of the palladium and palladium-oxide transformations was made.

A FeCrAlloy mesh-type catalyst has been used to reduce hydrocarbons (HC) and carbon monoxide (CO) emissions from a 4-stroke HCCI engine. Significant for the HCCI engine is a high compression ratio and lean mixtures, which leads to a high efficiency, low combustion temperatures and thereby low NOx emissions, <5 pmm, but also low exhaust temperatures, around 300°C. It becomes critical to: 1. Ensure that the HCCI-combustion generates as low HC emissions as possible, this can be done by very precise control of engine inlet conditions and, if possible, compression ratio. 2. Ensure that the exhaust temperature is high enough, without loosing efficiency or producing NOx; in order to get an oxidizing catalyst to work. 3. Select proper catalyst material for the catalyst so that the exhaust temperature can be as low as possible.

The cylinder to cylinder and cycle to cycle variations were measured in a production type Volvo natural gas engine. Cylinder pressure was measured in all six cylinders. Emission measurements were performed individually after all cylinders, and commonly after the turbocharger. Measurements (ECE R49 13-mode) were performed with different spark gap and two different locations for fuel injection, one before the throttle and one before the turbocharger. Heat-release and lambda calculations show substantial cylinder to cylinder variations, due to lambda variations between the cylinders. The slow burn combustion chamber, with low turbulence, results in high cycle to cycle variations (> 100% COV imep) for some of the load cases.

Homogeneous Charge Compression Ignition (HCCI) combustion is a process dominated by chemical kinetics of the fuel-air mixture. The hottest part of the mixture ignites first, and compresses the rest of the charge, which then ignites after a short time lag. Crevices and boundary layers generally remain too cold to react, and result in substantial hydrocarbon and carbon monoxide emissions. Turbulence has little effect on HCCI combustion, and may be most important as a factor in determining temperature gradients and boundary layer thickness inside the cylinder. The importance of thermal gradients inside the cylinder makes it necessary to use an integrated fluid mechanics-chemical kinetics code for accurate predictions of HCCI combustion. However, the use of a fluid mechanics code with detailed chemical kinetics is too computationally intensive for today's computers.

Quantitative Laser-Induced Incandescence (LII) has been applied to investigate the soot formation in a combusting Diesel jet for various conditions. For the quantification of the LII signal the local soot volume fraction of a diffusion flame burner was measured using laser beam extinction. These data were used for the calibration of the LII signal. The investigation of the soot formation in a combusting Diesel jet was performed in a high pressure, high temperature combustion chamber with optical access. A wide range of pressure (up to 10 MPa) and temperature (up to 1,500 K) conditions could be covered using a hydrogen precombustion, which is initiated inside the chamber before fuel injection. The influence of different gas atmospheres have been investigated by varying the gas composition (H2, O2 and N2) inside the chamber.

The reactions over a commercially available double layer tri-metal type (Pt, Pd, Rh) passenger car catalyst were analysed. A parameter study was performed in synthetic exhaust gases at: steady state conversion, periodic oscillations, and controlled transients. The influences of gas phase composition, temperature, adiabatic heat of reaction and lambda oscillations were investigated. The reactions of nitrogen oxides, propene and carbon monoxide were simultaneously analysed. Fast response emission analysers were used to record the dynamic properties of the catalysts. The catalyst was found to have high conversion rates and high oxygen storage capacity at relatively low temperatures. The presence of sulphur dioxide was found to reduce the conversion of CO and NOx substantially. An emission increase of 40-70 % was observed for steady state conditions and at oscillating conditions the increase was more than 100%.

The formation of Nitrous Oxide (N2O) over an aged three way catalyst was analysed in a laboratory reactor for a variety of simulated Otto engine exhaust gas conditions. Nitrous Oxide formation was further analysed during FTP75 dynamometer test with a car. The car was equipped with either an aged catalyst or a fresh one. A fast response diode laser system was modified to enable detection of Nitrous Oxide and Carbon Monoxide simultaneously. From laboratory data the kinetics of Nitrous Oxide formation were evaluated with mathematical simulations and a mechanism was suggested. The results were compared to data from vehicle tests and the results were discussed in the light of the laboratory study. Two general trends were confirmed, i) N2O formation increases at slightly lean conditions: ii) catalysts with a low degree of deterioration gave lower N2O emissions, iii) the extent of N2O formation goes though a maximum with respect to dissociation rate of NO.