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The increasing need to reduce greenhouse gas emissions and shift away from fossil fuels has raised an interest for methanol. Methanol can be produced from renewable sources and can drastically lower soot emissions from compression ignition engines (CI). As a result, research and development efforts have intensified focusing on the use of methanol as a replacement for diesel in CI engines. The issue with methanol lies in the fact that methanol is challenging to ignite through compression alone, particularly at low-load and cold starts conditions. This challenge arises from methanol's high octane number, low heating value, and high heat of vaporization, all of which collectively demand a substantial amount of heat for methanol to ignite through compression.

The growing demand to lower greenhouse gas emissions and transition from fossil fuels, has put methanol in the spotlight. Methanol can be produced from renewable sources and has the property of burning almost soot-free in compression ignition (CI) engines. Consequently, there has been a notable increase in research and development activities directed towards exploring methanol as a viable substitute for diesel fuel in CI engines. The challenge with methanol lies in the fact that it is difficult to ignite through compression alone, particularly in low-load and cold start conditions. This difficulty arises from methanol's high octane number, relatively low heating value, and high heat of vaporization, collectively demanding a considerable amount of heat for methanol to ignite through compression. Previous studies have addressed the use of a pilot injection in conjunction with a larger main injection to lower the required intake air temperature for methanol to combust at low loads.

The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines.

A modern diesel engine is a reliable and efficient mean of producing power. A way to reduce harmful exhaust and greenhouse gas (GHG) emissions and secure the sources of energy is to develop technology for an efficient diesel engine operation independent of fossil fuels. Renewable diesel fuels are compatible with diesel engines without any major modifications. Rapeseed oil methyl esters (RME) and other fatty acid methyl esters (FAME) are commonly used in low level blends with diesel. Lately, hydrotreated vegetable oil (HVO) produced from vegetable oil and waste fat has found its way into the automotive market, being approved for use in diesel engines by several leading vehicle manufacturers, either in its pure form or in a mixture with the fossil diesel to improve the overall environmental footprint. There is a lack of data on how renewable fuels change the semi-volatile organic fraction of exhaust emissions.

An increasing need to lower greenhouse gas emissions, and so move away from fossil fuels like diesel and gasoline, has greatly increased the interest for methanol. Methanol can be produced from renewable sources and eliminate soot emissions from combustion engines [1]. Since compression ignition (CI) engines are used for the majority of commercial applications, research is intensifying into the use of methanol, as a replacement for diesel fuel, in CI engines. This includes work on dual-fuel set-ups, different fuel blends with methanol, ignition enhancers mixed with methanol, and partially premixed combustion (PPC) strategies with methanol. However, methanol is difficult to ignite, using compression alone, at low load conditions. The problem comes from methanol’s high octane number, low lower heating value and high heat of vaporization, which add up to a lot of heat being needed from the start to combust methanol [2].

This study investigates particulate matter (PM) and regulated emissions from renewable rapeseed oil methyl ester (RME) biodiesel in pure and blended forms and contrasts that to conventional diesel fuel. Environmental and health concerns are the major motivation for combustion engines research, especially finding sustainable alternatives to fossil fuels and reducing diesel PM emissions. Fatty acid methyl esters (FAME), including RME, are renewable fuels commonly used from low level blends with diesel to full substitution. They strongly reduce the net carbon dioxide emissions. It is largely unknown how the emissions and characteristics of PM get altered by the combined effect of adding biodiesel to diesel and implementing modern engine concepts that reduce nitrogen oxides (NOx) emissions by exhaust gas recirculation (EGR).

The present work describes the numerical modeling of medium-speed marine engines, operating in a fumigated dual-fuel mode, i.e. with the second fuel injected in the ports. This engine technology allows reducing engine-out emissions while maintaining the engine efficiency and can be fairly easily retrofitted from current diesel engines. The main premixed fuel that is added can be a low-carbon one and can additionally be of a renewable nature, thereby reducing or even completely removing the global warming impact. To fully optimize the operational parameters of such a large marine engine, computational fluid dynamics can be very helpful. Accurately describing the combustion process in such an engine is key, as the prediction of the heat release and the pollutant formation is crucial. Auto-ignition of the diesel fuel needs to be captured, followed by the combustion and flame propagation of the premixed fuel.

In the search for low greenhouse gas propulsion, the dual fuel engine provides a solution to use low carbon fuel at diesel-like high efficiency. Also a lower emission of NOx and particles can be achieved by replacing a substantial part of the diesel fuel by for example natural gas. Limitations can be found in excessively high heat release rate (combustion-knock), and high methane emissions. These limitations are strongly influenced by operating parameters and properties of the used (bio)-gas. To find the dominant relations between fuel properties, operating parameters and the heat release rate and methane emissions, a combustion model is beneficial. Such a model can be used for optimizing the process, or can even be used in real time control. As precursor for such a model, the current state of art of dual fuel combustion modelling is investigated in this work. The focus is on high speed dual fuel engines for heavy duty and marine applications, with a varying gas/diesel ratio.

NOx pollution from diesel engines has been stated as causing over 10 000 pre-mature deaths annually and predictions are showing that this level will increase [1]. In order to decrease this growing global problem, exhaust after-treatment systems for diesel engines have to be improved, this is especially so for vehicles carrying freight as their use of diesel engines is expected to carry on into the future [2]. The most common way to reduce diesel engine NOx out emissions is to use SCR. SCR operates by injecting aqueous Urea solution, 32.5% by volume (AUS-32), that evaporates prior the catalytic surface of the SCR-catalyst. Due to a catalytic reaction within the catalyst, NOx is converted nominally into Nitrogen and Water. Currently, the evaporative process is enhanced by aggressive mixer plates and long flow paths.

Diesel engines are one of the most important power generating units these days. Increasing greenhouse gas emission level and the need for energy security has prompted increasing research into alternative fuels for diesel engines. Biodiesel is the most popular among the alternatives for diesel fuel as it is biodegradable and renewable and can be produced domestically from vegetable oils. In recent years, hydrotreated vegetable oil (HVO) has also gained popularity due to some of its advantages over biodiesel such as higher cetane number, lower deposit formation, storage stability, etc. HVO is a renewable, paraffinic biobased alternative fuel for diesel engines similar to biodiesel. Unlike biodiesel, the production process for HVO involves hydrogen as catalyst instead of methanol which removes oxygen content from vegetable oil.

The concept of Partially Premixed Combustion (PPC) in internal combustion engines has shown to yield high gross indicated efficiencies, but at the expense of gas exchange efficiencies. Most of the experimental research on partially premixed combustion has been conducted on compression ignition engines designed to operate on diesel fuel and relatively high exhaust temperatures. The partially premixed combustion concept on the other hand relies on dilution with high exhaust gas recirculation (EGR) rates to slow down the combustion which results in low exhaust temperatures, but also high mass flows over cylinder, valves, ports and manifolds. A careful design of the gas exchange system, EGR arrangement and heat exchangers is therefore of utter importance. Experiments were performed on a heavy-duty, compression ignition engine using a fuel consisting of 80 volume % 95 RON service station gasoline and 20 volume % n-heptane.

Factors influencing the effect of pilot-injection on main-injection combustion were investigated using heat release analysis in a heavy-duty diesel engine fuelled with standard diesel fuel, and included the effect of those factors on engine performance and emissions. Combinations of pilot injection parameters i.e. pilot start of injection, pilot mass, pilot-main injection separation, and rail pressure were studied for various operating conditions and combustion phases. It was concluded that the effect of pilot-injection combustion on main injection can be studied based on the phase of pilot combustion at the start of main injection. Four cases were identified: a) main injection during the mixing phase of pilot injection; b) main injection during the premixed phase of pilot combustion; c) main injection during the diffusive phase of pilot combustion and d) main injection after pilot combustion was completed.

Factors influencing pilot-injection combustion were investigated using heat release analysis in a heavy-duty diesel engine fuelled with standard diesel fuel. Combinations of pilot-injection parameters i.e. pilot start of injection, pilot mass, pilot-main injection separation, and rail pressure were studied for various operating conditions and combustion phases. An experiment was designed to investigate the factors influencing the combustion of the pilot. For improved injected fuel-mass accuracy, reference data for the injectors were measured in a spray rig prior to the engine experiments. Results show that cycle-to-cycle variations and cylinder-to-cylinder variations influence pilot autoignition and the amount of heat released. Rail pressure and injected pilot mass affect the obtained variance depending on the chamber conditions. The obtained combustion modes (premixed, diffusive) of pilot combustion were found to be a function of the injected mass and rail pressure.

Yearly 3.3 million premature deaths occur worldwide due to air pollution and NOx pollution counts for nearly one seventh of those [1]. This makes exhaust after-treatment a very important research and has caused the permitted emission levels for NOx to decrease to very low levels, for EURO 6 only 0.4 g/kWh. Recently new legislation on ammonia slip with a limit of 10 ppm NH3 has been added [2], which makes the SCR-technology more challenging. This technology injects small droplets of an aqueous Urea solution into the stream of exhaust gases and through a catalytic reaction within the SCR-catalyst, NOx is converted into Nitrogen and Water. To enable the catalytic reaction the water content in the Urea solution needs to be evaporated and the ammonia molecules need to have sufficient time to mix with the gases prior to the catalyst.

Methanol is today considered a viable green fuel for combustion engines because of its low soot emissions and the possibility of it being produced in a CO2-neutral manner. Methanol as a fuel for combustion engines have attracted interest throughout history and much research was conducted during the oil crisis in the seventies. In the beginning of the eighties the oil prices began to decrease and interest in methanol declined. This paper presents the emission potential of methanol. T-Φ maps were constructed using a 0-D reactor with constant pressure, temperature and equivalence ratio to show the emission characteristics of methanol. These maps were compared with equivalent maps for diesel fuel. The maps were then complemented with engine simulations using a stochastic reactor model (SRM), which predicts end-gas emissions. The SRM was validated using experimental results from a truck engine running in Partially Premixed Combustion (PPC) mode at medium loads.

Partially Premixed Combustion (PPC) has the potential of simultaneously providing high engine efficiency and low emissions. Previous research has shown that with proper combination of Exhaust-Gas Recirculation (EGR) and Air-Fuel equivalence ratio, it is possible to reduce engine-out emissions while still keeping the engine efficiency high. In this paper, the effect of changes in intake pressure (boost) and EGR fraction on PPC engine performance (e.g. ignition delay, burn duration, maximum pressure rise rate) and emissions (carbon monoxide (CO), unburned hydrocarbon (UHC), soot and NOX) was investigated in a single-cylinder, heavy-duty diesel engine. Swedish diesel fuel (MK1), RON 69 gasoline fuel and 99.5 vol% ethanol were tested. Fixed fueling rate and single injection strategy were employed.

Partially premixed combustion (PPC) is intended to improve fuel efficiency and minimize the engine-out emissions. PPC is known to have the potential to reduce emissions of nitrogen oxides (NOx) and soot, but often at the expense of increased emissions of unburned hydrocarbons (HC) and carbon monoxide (CO). PPC has demonstrated remarkable fuel flexibility and can be operated with a large variety of liquid fuels, ranging from low-octane, high-cetane diesel fuels to high-octane gasolines and alcohols. Several research groups have demonstrated that naphtha fuels provide a beneficial compromise between functional load range and low emissions. To increase the understanding of the influence of individual fuel components typically found in commercial fuels, such as alkenes, aromatics and alcohols, a systematic experimental study of 15 surrogate fuel mixtures of n-heptane, isooctane, toluene and ethanol was performed in a light-duty PPC engine using a design of experiment methodology.

Partially Premixed Combustion, PPC, with 50% Exhaust Gas Recirculation (EGR) at lean combustion conditions λ =1.5, has shown good efficiency and low emissions in a heavy-duty single-cylinder engine. To meet emission requirements in all loads and transient operation, aftertreatment devices are likely needed. Reducing λ to unity, when a three-way catalyst can be applied, extremely low emissions possibility exists for stoichiometric PPC. In this study, the possibility to operate clean PPC from lean condition to stoichiometric equivalence ratio with reasonable efficiency and non-excessive soot emission was investigated. Two EGR rates, 48% and 38% with two fuel rates were determined for 99.5 vol% ethanol in comparison with one gasoline fuel and Swedish diesel fuel (MK1). Engine was operated at 1250 rpm and 1600 bar injection pressure with single injection. Results revealed that efficiency was reduced and soot emission increased from lean PPC to stoichiometric PPC operation.

Partially premixed combustion (PPC) has the potential of high efficiency and simultaneous low soot and NOx emissions. Running the engine in PPC mode with high octane number fuels has the advantage of a longer premix period of fuel and air which reduces soot emissions, even at higher loads. The problem is the ignitability at low load and idle operating conditions. The objective of this study is investigation of the low load limitations with gasoline fuels with octane numbers RON 69 and 87. Measurements with diesel fuel were also taken as reference. The experimental engine is a light duty diesel engine equipped with a fully flexible valve train system. Trapped hot residual gases using negative valve overlap (NVO) is the main parameter of interest to potentially increase the attainable operating region of high octane number gasoline fuels.

A transparent HSDI CI engine was used together with a high speed camera to analyze the liquid phase spray geometry of the fuel types: Swedish environmental class 1 Diesel fuel (MK1), Soy Methyl Ester (B100), n-Heptane (PRF0) and a gas-to-liquid derivate (GTL) with a distillation range similar to B100. The study of the transient liquid-phase spray propagation was performed at gas temperatures and pressures typical for start of injection conditions of a conventional HSDI CI engine. Inert gas was supplied to the transparent engine in order to avoid self-ignition at these cylinder gas conditions. Observed differences in liquid phase spray geometry were correlated to relevant fuel properties. An empirical relation was derived for predicting liquid spray cone angle and length prior to ignition.