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Journal Article

Sulfur Poisoning of a Cu-SSZ-13 SCR Catalyst under Simulated Diesel Engine Operating Conditions

2021-04-06
2021-01-0576
Cu-SSZ-13 catalysts are widely used for diesel aftertreatment applications for NOx (NO and NO2) abatement via selective catalytic reaction (SCR) due to their high conversion efficiency and excellent hydrothermal stability. Diesel engine exhaust contains small amounts of SOx due to the combustion of sulfur compounds in diesel fuel. The engine out SOx level mainly depends on the sulfur content in the diesel fuel. The presence of SOx from engine exhaust can deteriorate the SCR performance of Cu-SSZ-13 catalysts in real-world applications. This work is focused on the sulfur-induced deactivation process of a Cu-SSZ-13 catalyst under a range of simulated diesel engine operating conditions. Two catalyst deactivation modes, namely chemical poisoning and physical poisoning, are identified, primarily depending on the operating temperature. Chemical poisoning mainly results from the interaction between SOx and Cu species within the zeolite framework.
Technical Paper

Reliable Processes of Simulating Liner Roughness and Its Lubrication Properties

2019-04-02
2019-01-0178
Topology of liner finish is critical to the performance of internal combustion engines. Proper liner finish simulation processes lead to efficient engine design and research. Fourier methods have been well studied to numerically generate liner topology. However, three major issues wait to be addressed to make the generation processes feasible and reliable. First, in order to simulate real plateau honed liners, approaches should be developed to calculate accurate liner geometric parameters. These parameters are served as the input of the generation algorithm. Material ratio curve, the common geometry calculation method, should be modified so that accurate root mean square of plateau height distribution could be obtained. Second, the set of geometric parameters used in generating liner finish (ISO 13565-2) is different from the set of parameters used in manufacturing industry (ISO 13565-3). Quantitative relations between these two sets should be studied.
Technical Paper

Design and Durability of Vanadium-SCR Catalytic Aftertreatment System to Meet Tier 4 Emission Regulations in a Locomotive Application

2019-02-21
2019-01-5015
An advanced exhaust aftertreatment system (ATS) for Tier 4 compliant locomotive applications was successfully designed and developed for use on Cummins QSK95 engines. The engine and ATS were introduced in late 2016. This system provided nitrogen oxides (NOx) reduction capability in excess of 95%. Vanadia-based selective catalytic reduction (V-SCR) extruded catalyst technology was chosen over other readily available component technologies such as diesel oxidation catalyst (DOC) or a combination of DOC and SCR systems to address the stringent Tier 4 standards. In addition to NOx reduction, substantial oxidation of gaseous hydrocarbons (HCs) from unburnt fuel and lubricating oil soluble organic fraction (SOF) was also achieved. This dual functionality (oxidation and reduction capability) was one of the key factors in adopting this technology as the prime path and rendering it suitable for the harsh locomotive application environment.
Journal Article

NOx Reduction Using a Dual-Stage Catalyst System with Intercooling in Vehicle Gasoline Engines under Real Driving Conditions

2018-04-03
2018-01-0335
Selective catalytic reduction (SCR) of nitrogen oxides (NOx) is used in diesel-fueled mobile applications where urea is an added reducing agent. We show that the Ultera® dual-stage catalyst, with intercooling aftertreatment system, intrinsically performs the function of the SCR method in nominally stoichiometric gasoline vehicle engines without the need for an added reductant. We present that NOx is reduced during the low-temperature operation of the dual-stage system, benefiting from the typically periodic transient operation (acceleration and decelerations) with the associated swing in the air/fuel ratio (AFR) inherent in mobile applications, as commonly expected and observed in real driving. The primary objective of the dual-stage aftertreatment system is to remove non-methane organic gases (NMOG) and carbon monoxide (CO) slip from the vehicle’s three-way catalyst (TWC) by oxidizing these constituents in the second stage catalyst.
Technical Paper

Sustained Low Temperature NOx Reduction

2018-04-03
2018-01-0341
Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.
Technical Paper

Curved Beam Based Model for Piston-Ring Designs in Internal Combustion Engines: Working Engine Conditions Study

2018-04-03
2018-01-1277
A new multi-scale curved beam based model was developed for piston-ring designs. This tool is able to characterize the behavior of a ring with any cross section design. This paper describes the conformability and ring static twist calculation. The conformability part model the static behavior of the ring in working engine conditions. The model employs the computation scheme that separates the meshing of the structure and local force generation. Additional to the conventional static ring-bore conformability analysis, the conformability model is designed to examine ring-bore and ring-groove interactions in a running engine under varying driving forces and localized lubrication conditions. We made Improvements on the way to handle the effects of the radial temperature gradient compared to the existing models. Examples are given on the effects of ring rotation on the interaction of the ring and a distorted bore as well as the change of local lubrication conditions.
Technical Paper

Curved Beam Based Model for Piston-Ring Designs in Internal Combustion Engines: Closed Shape Within a Flexible Band, Free-Shape and Force in Circular Bore Study

2018-04-03
2018-01-1279
A new multi-scale curved beam based model was developed for piston-ring designs. This paper describes the free-shape, force in circular bore and closed shape within a flexible band (ovality) related parts. Knowing any one of these distributions, this model determines the other two. This tool is useful in the sense that the characterization of the ring is carried out by measuring its closed shape within a flexible band which is more accurate than measuring its free shape or force distribution in circular bore. Thus, having a model that takes the closed shape within a flexible band as an input is more convenient and useful based on the experiments carried out to characterize the ring.
Journal Article

Development and Application of Ring-Pack Model Integrating Global and Local Processes. Part 1: Gas Pressure and Dynamic Behavior of Piston Ring Pack

2017-03-28
2017-01-1043
A new ring pack model has been developed based on the curved beam finite element method. This paper describes the first part of this model: simulating gas pressure in different regions above piston skirt and ring dynamic behavior of two compression rings and a twin-land oil control ring. The model allows separate grid divisions to resolve ring structure dynamics, local force/pressure generation, and gas pressure distribution. Doing so enables the model to capture both global and local processes at their proper length scales. The effects of bore distortion, piston secondary motion, and groove distortion are considered. Gas flows, gas pressure distribution in the ring pack, and ring structural dynamics are coupled with ring-groove and ring-liner interactions, and an implicit scheme is employed to ensure numerical stability. The model is applied to a passenger car engine to demonstrate its ability to predict global and local effects on ring dynamics and oil transport.
Technical Paper

Development, Validation and ECM Embedment of a Physics-Based SCR on Filter Model

2016-09-27
2016-01-8075
SCR on Filter (SCRoF) is an efficient and compact NOX and PM reduction technology already used in series production for light-duty applications. The technology is now finding its way into the medium duty and heavy duty market. One of the key challenges for successful application is the robustness to real world variations. The solution to this challenge can be found by using model-based control algorithms, utilizing state estimation by physics-based catalyst models. This paper focuses on the development, validation and real time implementation of a physics-based control oriented SCRoF model. An overview of the developed model will be presented, together with a brief description of the model parameter identification and validation process using engine test bench measurement data. The model parameters are identified following a streamlined approach, focusing on decoupling the effects of deNOx and soot phenomena.
Journal Article

Cycle-by-Cycle Analysis of Cold Crank-Start in a GDI Engine

2016-04-05
2016-01-0824
The first 3 cycles in the cold crank-start process at 20°C are studied in a GDI engine. The focus is on the dependence of the HC and PM/PN emissions of each cycle on the injection strategy and combustion phasing of the current and previous cycles. The PM/PN emissions per cycle decrease by more than an order of magnitude as the crank-start progresses from the 1st to the 3rd cycle, while the HC emissions stay relatively constant. The wall heat transfer, as controlled by the combustion phasing, during the previous cycles has a more significant influence on the mixture formation process for the current cycle than the amount of residual fuel. The results show that the rise in HC emissions caused by the injection spray interacting with the intake valves and piston crown is reduced as the cranking process progresses. Combustion phasing retard significantly reduces the PM emission. The HC emissions, however, are relatively not sensitive to combustion phasing in the range of interest.
Technical Paper

A Framework for Robust Driver Gaze Classification

2016-04-05
2016-01-1426
The challenge of developing a robust, real-time driver gaze classification system is that it has to handle difficult edge cases that arise in real-world driving conditions: extreme lighting variations, eyeglass reflections, sunglasses and other occlusions. We propose a single-camera end-toend framework for classifying driver gaze into a discrete set of regions. This framework includes data collection, semi-automated annotation, offline classifier training, and an online real-time image processing pipeline that classifies the gaze region of the driver. We evaluate an implementation of each component on various subsets of a large onroad dataset. The key insight of our work is that robust driver gaze classification in real-world conditions is best approached by leveraging the power of supervised learning to generalize over the edge cases present in large annotated on-road datasets.
Technical Paper

The Anatomy of Knock

2016-04-05
2016-01-0704
The combustion process after auto-ignition is investigated. Depending on the non-uniformity of the end gas, auto-ignition could initiate a flame, produce pressure waves that excite the engine structure (acoustic knock), or result in detonation (normal or developing). For the “acoustic knock” mode, a knock intensity (KI) is defined as the pressure oscillation amplitude. The KI values over different cycles under a fixed operating condition are observed to have a log-normal distribution. When the operating condition is changed (over different values of λ, EGR, and spark timing), the mean (μ) of log (KI/GIMEP) decreases linearly with the correlation-based ignition delay calculated using the knock-point end gas condition of the mean cycle. The standard deviation σ of log(KI/GIMEP) is approximately a constant, at 0.63. The values of μ and σ thus allow a statistical description of knock from the deterministic calculation of the ignition delay using the mean cycle properties
Technical Paper

Emissions of Organic Species from a Nonroad Vanadium-Based SCR Aftertreatment System

2015-09-29
2015-01-2904
U.S. and European nonroad diesel emissions regulations have led to the implementation of various exhaust aftertreatment solutions. One approved configuration, a vanadium-based selective catalytic reduction catalyst followed by an ammonia oxidation catalyst (V-SCR + AMOX), does not require the use of a diesel oxidation catalyst (DOC) or diesel particulate filter (DPF). While certification testing has shown the V-SCR + AMOX system to be capable of meeting the nitrogen oxides, carbon monoxide, and particulate matter requirements, open questions remain regarding the efficacy of this aftertreatment for volatile and nonvolatile organic emissions removal, especially since the removal of this class of compounds is generally attributed to both the DOC and DPF.
Technical Paper

Aircraft In Situ Validation of Hydrometeors and Icing Conditions Inferred by Ground-based NEXRAD Polarimetric Radar

2015-06-15
2015-01-2152
MIT Lincoln Laboratory is tasked by the U.S. Federal Aviation Administration to investigate the use of the NEXRAD polarimetric radars* for the remote sensing of icing conditions hazardous to aircraft. A critical aspect of the investigation concerns validation that has relied upon commercial airline icing pilot reports and a dedicated campaign of in situ flights in winter storms. During the month of February in 2012 and 2013, the Convair-580 aircraft operated by the National Research Council of Canada was used for in situ validation of snowstorm characteristics under simultaneous observation by NEXRAD radars in Cleveland, Ohio and Buffalo, New York. The most anisotropic and easily distinguished winter targets to dual pol radar are ice crystals.
Journal Article

Desulfation of Pd-based Oxidation Catalysts for Lean-burn Natural Gas and Dual-fuel Applications

2015-04-14
2015-01-0991
Lean-burn natural gas (NG) engines are used world-wide for both stationary power generation and mobile applications ranging from passenger cars to Class 8 line-haul trucks. With the recent introduction of hydraulic fracturing gas extraction technology and increasing availability of natural gas, these engines are receiving more attention. However, the reduction of unburned hydrocarbon emissions from lean-burn NG and dual-fuel (diesel and natural gas) engines is particularly challenging due to the stability of the predominant short-chain alkane species released (e.g., methane, ethane, and propane). Supported Pd-based oxidation catalysts are generally considered the most active materials for the complete oxidation of low molecular weight alkanes at temperatures typical of lean-burn NG exhaust. However, these catalysts rapidly degrade under realistic exhaust conditions with high water vapor concentrations and traces of sulfur.
Journal Article

Experimental and Modeling Study of Ash Impact on DPF Backpressure and Regeneration Behaviors

2015-04-14
2015-01-1063
One field-returned DPF loaded with a high amount of ash is examined using experimental and modeling approaches. The ash-related design factors are collected by coupling the inspection results from terahertz spectroscopy with a calibrated DPF model. The obtained ash packing density, ash layer permeability and ash distribution profile are then used in the simulation to assess the ash impact on DPF backpressure and regeneration behaviors. The following features have been observed during the simulation: 1 The ash packing density, ash layer permeability and ash distribution profile should be collected at the same time to ensure the accurate prediction of ash impact on DPF backpressure. Missing one ash property could mislead the measurement of the other two parameters and thus affects the DPF backpressure estimation. 2 The ash buildup would gradually increase the frequency for the backpressure-based active soot regeneration.
Technical Paper

An Integrated Approach to Requirements Development and Hazard Analysis

2015-04-14
2015-01-0274
The introduction of new safety critical features using software-intensive systems presents a growing challenge to hazard analysis and requirements development. These systems are rich in feature content and can interact with other vehicle systems in complex ways, making the early development of proper requirements critical. Catching potential problems as early as possible is essential because the cost increases exponentially the longer problems remain undetected. However, in practice these problems are often subtle and can remain undetected until integration, testing, production, or even later, when the cost of fixing them is the highest. In this paper, a new technique is demonstrated to perform a hazard analysis in parallel with system and requirements development. The proposed model-based technique begins during early development when design uncertainty is highest and is refined iteratively as development progresses to drive the requirements and necessary design features.
Journal Article

Impact of Hydrocarbons on the Dual (Oxidation and SCR) Functions of Ammonia Oxidation Catalysts

2014-04-01
2014-01-1536
Ammonia oxidation (AMOX) catalysts are critical parts of most diesel aftertreatment systems around the world. These catalysts are positioned downstream of selective catalytic reduction (SCR) catalysts and remove unreacted NH3 that passes through the SCR catalyst. In many configurations, the AMOX catalyst is situated after a diesel oxidation catalyst and catalyzed diesel particulate filter that oxidize CO and hydrocarbons. However, in Euro V and proposed Tier 4 final aftertreatment architectures there is no upstream oxidation catalyst. In this study, the impact of hydrocarbons is evaluated on two different types of AMOX catalysts. One has dual washcoat layers-SCR washcoat on top of PGM washcoat-and the other has only a PGM washcoat layer. Results are presented for NH3 and hydrocarbon oxidation, NOx and N2O selectivity, and hydrocarbon storage. The AMOX findings are rationalized in terms of their impact on the individual oxidation and SCR functions.
Journal Article

Estimation of Nonlinear Viscoelastic Parameters from Estimated Linear Models of Behavior around Multiple Settling Points of a Foam-Mass System

2014-04-01
2014-01-0851
Flexible polyurethane foam is the main cushioning element used in car seats. Optimization of an occupied seat's static and dynamic behavior requires models of foam that are accurate over a wide range of excitation and pre-compression conditions. In this research, a method is described to estimate the parameters of a global model of the foam behavior from data gathered in a series of impulse tests at different settling points. The estimated model is capable of describing the responses gathered from all the impulse tests using a unique set of parameters. The global model structure includes a nonlinear elastic term and a hereditary viscoelastic term. The model can be used to predict the settling point for each mass used and, by expanding the model about that settling point, local linear models of the response to impulsive excitation can be derived. From this analysis the relationship between the local linear model parameters and the global model parameters is defined.
Technical Paper

Development of a SIL, HIL and Vehicle Test-Bench for Model-Based Design and Validation of Hybrid Powertrain Control Strategies

2014-04-01
2014-01-1906
Hybrid powertrains with multiple sources of power have generated new control challenges in the automotive industry. Purdue University's participation in EcoCAR 2, an Advanced Vehicle Technology Competition managed by the Argonne National Laboratories and sponsored by GM and DOE, has provided an exciting opportunity to create a comprehensive test-bench for the development and validation of advanced hybrid powertrain control strategies. As one of 15 competing university teams, the Purdue EcoMakers are re-engineering a donated 2013 Chevrolet Malibu into a plug-in parallel- through-the-road hybrid-electric vehicle, to reduce its environmental impact without compromising performance, safety or consumer acceptability. This paper describes the Purdue team's control development process for the EcoCAR 2 competition.
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