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The objective of the present study is to analyze soot formation in diesel engine combustion by using multi-dimensional combustion simulations with a parallelized explicit ODE solver. Parallelized CHEMEQ2 was used to perform detailed chemical kinetics in KIVA-4 code. CHEMEQ2 is an explicit stiff ODE solver developed by Mott et al. which is known to be faster than traditional implicit ODE solvers, e.g., DVODE. In the present study, about eight times faster computation was achieved with CHEMEQ2 compared to DVODE when using a single thread. Further, by parallelizing CHEMEQ2 using OpenMP, the simulations could be run not only on calculation servers but also on desktop machines. The computation time decreases with the number of threads used. The parallelized CHEMEQ2 enabled combustion and emission characteristics, including detailed soot formation processes, to be predicted using KIVA-4 code with detailed chemical kinetics without the need for reducing the reaction mechanism.

The rotary engine provides high power density compared to piston engine, but one of its downside is higher oil consumption. In order to better understand oil transport, a laser induced fluorescence technique is used to visualize oil motion on the side of the rotor during engine operation. Oil transport from both metered oil and internal oil is observed. Starting from inside, oil accumulates in the rotor land during inward motion of the rotor created by its eccentric motion. Oil seals are then scraping the oil outward due to seal-housing clearance asymmetry between inward and outward motion. Cut-off seal does not provide an additional barrier to internal oil consumption. Internal oil then mixes with metered oil brought to the side of the rotor by gas leakage. Oil is finally pushed outward by centrifugal force, passes the side seals, and is thrown off in the combustion chamber.

This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle.

In order to study alternate methods of Air Fuel ratio (A/F) perturbation for maximizing three-way catalyst conversion efficiency, two methods for measuring the Oxygen Storage Capacity (OSC) of Catalyst were developed on an engine test bench. The first is to measure just the break-through Perturbing Oxygen Quantity (POQ, which is defined as the product of A/F amplitude, perturbation period and gas flow), and the second is to measure the response delay of the rear A/F sensor, which has been improved to be very similar to the former. Then, the OSC values of many catalysts were investigated with different perturbation parameters. The results show that OSC would not be affected by amplitude, period of perturbation and gas flow, and that the best conversion efficiency is obtained when the value of POQ is about 1/2 of the value for OSC. These results suggest that the best way to control perturbation is to keep POQ at 1/2 of OSC by setting perturbation parameters.

Aldehydes are the cause of sick house syndrome or chemical sensitivity and have harmful influences for human beings. In the cabin of vehicle, aldehydes which are included in the volatilization gas from the interior materials, DE emission gas in intake air, cigarette smoke and so on spoil the comfortableness. Active carbon, which has been used as an adsorbent, shows an excellent removal efficiency for most of the gas components by physical adsorption. But for aldehydes, it has difficulty because aldehydes are hard to be adsorbed physically. We have developed new aldehydes adsorbent undergoing addition reaction with gaseous aldehydes on its surface. Aldehydes capture material (ACM) make use of the chemical reaction using a resorcin as a reagent and an H-type zeolite as a water-containing support, and active hydrogen is used as a catalyst to promote the reaction. In addition, we have applied ACM to cabin air filter (CAF) of vehicle.

A pancake-type constant-volume combustion chamber was used to investigate the combustion and NOx emission characteristics of propane-air and hydrogen-air mixtures under various charge stratification patterns, which were obtained by variations of the initial charge and injected mixture concentrations and the ignition spark timing. A planar laser-induced fluorescence from nitrogen dioxide as gas fuel tracer was applied to measure the mixture distribution in the test chamber. The second harmonic output of pulsed Nd; YAG laser was used as a light source for fluorescence excitation. The fluorescence images were corrected by a gated image-intensified CCD camera. The quantitative analysis of fuel concentration was made possible by the application of linearity between fluorescence intensity and NO2 concentration at low trace level.

In order to control the mixture formation, a mixture injected 4-valve SI engine was developed with a small mixture chamber and mechanically driven mixture injection valve installed into the cylinder head. The mixture injection valve was located at the center of the combustion chamber. The mixture was injected from the final stage of the intake stroke to the beginning of the compression stroke. The mixture distribution and in-cylinder flow field inside the combustion chamber were measured by a pair of laser two-dimensional visualization techniques. A planar-laser-induced exciplex fluorescence technique was used to visualize the in-cylinder mixture formation by obtaining spectrally separated fluorescence images of liquid and vapor phase fuel distribution. Particle image velocimetry (PIV) was used to obtain flow field images. In the case of the mixture injected SI engine, the mixture injected into the swirl center was retained during the compression stroke.

Recently, an audible clattering noise has been noticed in some vehicles during cold engine starts, mainly in the U.S. The clattering is referred to by various names, such as “carbon knock,” “carbon rap,” “mechanical knock” and “combustion chamber deposit interference (CCDI).” CCDI is believed to be caused by the deposit formation in the combustion chamber. In the research effort described here, CCDI was successfully reproduced in a 2.5-liter multipoint injection engine with a polyolefin amine gasoline additive. It was determined that the CCDI was caused by mechanical contact between the piston top and the cylinder head deposits. The vibration due to CCDI originated mainly at the thrust side of the piston right after top-dead-center on compression stroke and was characterized by a high frequency response. Combustion chamber deposit (CCD) formation depends on many factors, including gasoline additives.

A new type of three way catalyst for lean engine was developed in order to reduce hydrocarbon (HC), carbon-monoxide (CO) and nitrogen-oxides (NOx) in lean exhaust gas. This catalyst has a base support material of MFI zeolite loaded with active metals including platinum (Pt), iridium (Ir) and rhodium (Rh). It showed good catalytic activity and thermal durability on a lean engine. This catalyst made it possible to enlarge the lean operating region of the lean burn engine. It showed the NOx reduction of 51% in Japanese 10-15 mode emission test and the emissions were found low enough to satisfy the new Japanese emission standards. Consequently, fuel economy of the lean vehicle with this catalyst has been improved about 16% in comparison with a comparable current stoichiometric combustion vehicle. This catalyst has been mass-produced for Mazda 323 lean burn vehicle (Z-Lean) for the Japanese domestic market.

A large quantity of recirculated exhaust gas is used to reduce NOx emissions and improve fuel economy at the same time. The effect of exhaust gas recirculation (EGR) was investigated under the stoichiometric and lean operating conditions and compared with the effect of lean operation without EGR. A mixture injected SI engine that has a mechanically driven mixture injection valve installed was prepared. In this engine, it is possible to charge combustible mixture independently from combustion air and recirculated exhaust gas introduced from intake port in order to stratify the mixture. The effect of the EGR ratio on NOx emissions and fuel consumption was measured under the stoichiometric and lean operating conditions. Due to the mixture distribution controlled by the mixture injection, a large quantity of recirculated exhaust gas could be introduced into the combustion chamber under the stoichiometric air/fuel ratio. The limit of EGR ratio was 48 %.

The new combustion method in DISC engine has been developed. It has a double structure combustion chamber characterized as ‘Caldera’. The chamber is constructed by a center cavity for the purpose of forming a stable mixture around a spark plug electrode, and by an outer cavity which has a role of a main chamber. This method makes possible a perfect un-throttling operation, and a fuel consumption equal to a diesel engine is achieved. With regard to an out-put of DISC engine, a stoichmetric combustion and a high torque are achieved by controling a fuel injection timing with an electro-magnetic injection system device. With regard to emission regulations, a heavy EGR include residual gas decreases greatly NOx and HC emissions simultaneously, and which suggests a possibility to achieve LEV/ULEV regulations.

Mazda has been pursuing the research of side exhaust porting for its rotary engine in an effort to improve the engine's fuel efficiency and exhaust emissions characteristics. The side exhaust porting configuration provides greater flexibility in setting port timing and shape, as compared to the peripheral exhaust porting configuration, which is in use in the current-generation rotary engines; the side exhaust porting configuration enables the selection of a port timing more favorable to reduced fuel consumption and exhaust emissions. The side exhaust port rotary engine used in this research has its exhaust port closure timing around the top dead center (TDC) and has no intake-exhaust timing overlap. As a result, burnt gasses entering the next cycle of combustion are reduced, thus enhancing combustion stability; also, the air-fuel ratio can be set leaner for improved fuel consumption.

The planar laser induced fluorescence (PLIF) technique was applied to two dimensional visualization of OH radicals in a combustion flame. A frequency doubled Nd:YAG laser pumped dye laser was used to form a laser light sheet which excited the OH X2Π-A2Σ transition. A fluorescence image of the OH radical and a visible image of a combustion flame were simultaneously imaged by a pair of CCD cameras with image intensifiers. Measurement of the OH radical in the combustion flame could be carried out by using this PLIF technique without Mie scattering lights from soot particles and other optical disturbances. The PLIF technique was employed to study the OH radical in the combustion chamber of a spark ignition (S. I.) engine using gasoline as fuel. Measurements of the OH radical fluorescence were carried out under various operating conditions of mass burned fraction, swirl ratio and air-fuel ratio.

Stratified charge engines have been getting attention for the drastic improvement in thermal efficiency at low-load region. There have been researchers on the two types of engines-the high pressure direct injection stratified charge type in which fuel is supplied directly at high pressure into its combustion chamber right before ignition timings, and the low pressure direct injection stratified charge type in which fuel is injected directly into its cylinder while the cylinder pressure is comparatively low[ 1- 3]. Rotary engines have higher freedom than reciprocating engines in terms of equipping direct fuel injection devices, since their combustion chambers rotate along the rotor housing. The fuel supply units, therefore, need not be exposed to high temperature combustion gas.

Lean-burn technology is now being reviewed again in view of demands for higher efficiency and cleanness in internal combustion engines. The improvement of combustion using in-cylinder gas flow control is the fundamental technology for establishing lean-burn technology, but the great increase in main combustion velocity due to intensifying of turbulence causes a deterioration in performance such as increase in heat loss and N0x. Thus, it is desirable to improve combustion stability while suppressing the increase in main burn velocity as much as possible (1). It is expected that the fluid characteristics of the in-cylinder tumbling motion that the generated vortices during intake stroke breake down in end-half of compression stroke will satisfy the above requisition. This study is concerned with the effects of enhancing of tumble intensity on combustion in 4-valve S. I. engines.

Both NOx and unburned HC were reduced by changing the direction of the flame propagation. It is generally said that the optimum ignition position of spark ignition engine is in the center of combustion chamber. However by igniting arround the chamber and propagating the flame toward the center, a smooth heat release pattern due to the decrease in the flame area and a decrease in the unburned gas entering the ring crevise can be anticipated. These effects of this combustion process, which was named the surrounding combustion process (SCP), were experimntally confirmed using the constant volume combustion vessels and the spark ignition engine equipped with six spark plugs per cylinder. Next, the steps for decreasing the number of ignitions TCre considered, and additional three spark plugs for SCP were installed in the four valve pentroof combustion chamber. With this engine, the NOx reduction and the capability of SCP to further improve the lean burn engine fuel economy were confirmed.

An all-ceramic swirl chamber has been developed which meets the 1987 U.S. particulate emission standard for LDV. The all ceramic construction raises combustion temperature to reduce particulate emission to the necessary level. But particulate reduction led to two-fold increase in NOx. This problem was coped with by applying EGR and fuel injection timing control. As a result NOx has been cut to the same level as with a base engine and particulate has been further reduced.

The present trend of internal combustion engines toward higher-speed and higher-output capacity is pressing the need for improved lubrication of sliding parts in the combustion chamber to secure reliability. To meet this need, investigation into frictional phenomena was made with a rotary engine, which led to the development of a method of coating the inner surface of the rotor housing with fluorocarbon resin superior in self-lubrication and friction resistance. Rotary engines given this surface finishing showed no trace of irregular wear of the sliding surfaces even when subjected, prior to completion of run-in firing (in green condition), to high-speed and high-load tests, indicating this method's noteworthy benefit of improving comformability. This method offers an excellent surface finish for sliding parts of internal combustion engines (rotary and reciprocating) which will gain increasingly higher output in the future.