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Spray-guided gasoline direct injection SI engines attract as one of new generation lean-burn engines to promise CO2 reduction. These typically adopt “narrow-spacing” concept in which an injector is centrally mounted close to a spark plug. Therefore, geometric targets of the fuel spray and a position of the spark plug have to be exactly limited to maintain a proper mixture in the spark gap. In addition, the stable combustion window is narrow because the spark ignition is limited in a short time during and immediately after the injection. These spatial and temporal restrictions involve some intractable problems concerning the combustion robustness due to the complicate phenomena around the spark plug. The local mixture preparation near the spark plug significantly depends on the spray-induced charge motion. The intense flow induced by the motion blows out and stretches the spark, thereby affecting the spark discharge performance.

A two-stage combustion is one of the Mitsubishi GDI™ technologies for a quick catalyst warm-up on a cold-start. However, when the combustion is continued for a long time, an increase in the fuel consumption is a considerable problem. To solve the problem, a stratified slight-lean combustion is newly introduced for utilization of catalysis. The stratified mixture with slightly lean overall air-fuel ratio is prepared by the late stage injection during the compression stroke. By optimizing an interval between the injection and the spark timing, the combustion simultaneously supplies substantial CO and surplus O2 to a catalyst while avoiding the soot generation and the fouling of a spark plug. The CO oxidation on the catalyst is utilized to reduce the cold-start emissions. Immediately after the cold-start, the catalyst is preheated for the minimum time to start the CO oxidation by using the two-stage combustion. Following that, the stratified slight-lean combustion is performed.

An extensive effort has been made, at Mitsubishi Motors, in the technology field of new catalysts and of the catalyst reaction control for the purpose of further improvement of the emission control with the GDI engines [1-2]. A new NOx-trap catalyst has been developed to satisfy the required higher catalyst performance under high-temperature condition. The new catalyst contains potassium (K) of excellent NOx-storage capacity under high-temperature region in the catalytic atmosphere, and to retain K stability zeolite is mixed in the catalyst layer as well as the substrate is coated with silica (SiO2). This new catalyst has been proven of the improved NOx conversion efficiency, and solved the long-pending problems particularly those experienced under high-temperature operation.

NOx adsorber has already been used for the after-treatment system of series production vehicle installed with a lean burn or direct injection engine [1,2,3]. In order to improve NOx adsorbability at high temperatures, many researchers have recently been trying an addition of potassium (K) as well as other conventional NOx adsorbents. Potassium, however, reacts easily with the cordierite honeycomb substrate at high temperatures, and not only causes a loss in NOx adsorbability but also damages the substrate. Three new technologies have been proposed in consideration of the above circumstances. First, a new concept of K-capture is applied in washcoat design, mixed with zeolite, to improve thermal stability of K and to keep high NOx conversion efficiency, under high temperatures, of NOx adsorber catalyst. Second, another new technology, pre-coating silica over the boundary of a substrate and washcoat, is proposed to prevent the reaction between potassium and cordierite.

GDI (Gasoline Direct Injection) engine adopting new combustion control technologies was developed and introduced into Japanese domestic market in August of 1996. In order to extend its application to the European market, various system modifications have been performed. Injectors are located with a smaller angle to the vertical line in order to improve the combustion stability in the higher speed range. A new combustion control method named “two-stage mixing” is adopted to suppress the knock in the low speed range. As a result of this new method, the compression ratio was increased up to 12.5 to 1 while increasing the low-end torque significantly. Taking the high sulfur gasoline in the European market into account, a selective reduction lean-NOx catalyst with improved NOx conversion efficiency was employed. A warm-up catalyst can not be used because the selective reduction lean NOx catalyst requires HC for the NOx reduction.

The major problems of the various mixture formation concepts for direct injection gasoline engines that have been proposed up to the present were caused by the difficulties of preparing the mixture with adequate strength at spark plug in wide range of engine operating conditions. Novel combustion control technologies proposed by Mitsubishi is one of the solution for these problems. By adopting upright straight intake ports to generate air tumble, an electromagnetic swirl injector to realize optimized spray dispersion and atomization and a compact piston cavity to maintain charge stratification, it has become possible to achieve super-lean stratified combustion for higher thermal efficiency under partial loads as well as homogeneous combustion to realize higher performance at full loads. GDI™ (Gasoline Direct Injection) engine adopting these technologies is developed. At partial loads, fuel economy improvement exceeding 30 % is realized.

Diesel emission control is being addressed worldwide to help preserve the global environment. In 1994, emission controls in the U.S. called for reduction of diesel particulate matter (PM) to 10 to 20% of 1986's initial limit. In the same year, we developed and marketed small and medium duty trucks which were equipped with PM reduction systems that oxidize soluble organic fraction (SOF) contained in the PM, in order to satisfy these new regulations. Prior to their marketing, a catalyst was selected from among several types of candidate catalysts. Durability tests were performed using a catalytic converter-equipped small duty truck to verify the durability of the chosen catalyst. The durability test course was set up combining urban areas and expressways in the southern part of California, U.S.A.. The cumulative total distance covered on the test course reached 200,000 km. During the durability test, the catalyst was evaluated by measurement of PM emission using a chassis dynamometer.

The relationship between MTBE-blended gasoline properties and warm-up driveability is investigated by focusing on the transient combustion air-fuel ratio that strongly relates to the combustion state of the engine. As a result, although warm-up driveability of MTBE-free gasoline has a high correlation with 50% distillation temperature (T50) and a high correlation with 100°C distillation volume (E100), the correlation is found to be low when blended with MTBE. Various formulas that improve correlation with peak excess air ratio (λ) by correcting T50 and E100 for the amount of MTBE blended are examined. The formula for which the highest determination coefficient is obtained is proposed as a new driveability index (DI) that can also be applied to MTBE-blended gasoline. In addition, the effect on driveability by gasoline base materials using this new DI also is investigated.

The authors used a mass spectrometer to determine an SOF reduction mechanism of a diesel oxidation catalyst. The results indicate that SOF reduction lies in the catalytic conversion of high molecular organic matter to low molecular organic matter. And unregulated emissions are also reduced through this conversion. It is also found that the SOF reduction performance is highly dependent up on the condition of the wash coat. There is some limitation to improving diesel oxidation catalyst performance because of the sulfur content found in diesel fuel. Finally, the authors have determined what we think are the specifications of the presently best catalytic converter.

A stratified-charge lean-burn engine is newly developed for the purpose of energy saving and carbon dioxide reduction to minimize the global warming. The engine, named MVV(Mitsubishi Vertical Vortex)engine, is based on the unique vertical vortex technology which realizes stable combustion even with lean mixture without any additional device. And it also has another feature of “all range air-to-fuel ratio feedback control system” utilizing linear air-to-fuel ratio sensor. This paper describes various technologies developed in this engine.

During next decade, automotive engineers will take up unprecedented challenges to meet a variety of technical demands on passenger cars. While performance, refinement and reliability will continue to be major technical goals of passenger cars, reducing their impact on the environment not only in urban areas but also on the global basis will become an increasingly urgent issue. In addition, the need for energy and resources saving will necessitate development of more fuel efficient cars, exploitation of alternative energy and recycled materials. In this paper, the authors will review various alternative engines as candidates to satisfy the above demands. The authors will also discuss various alternative transportation energy sources such as alcoholic fuels, natural gas, hydrogen and electricity. Finally the trends of future passenger car engine design will be discussed.

A fuel control method to reduce the harmful exhaust gas from SI engines is proposed. As is well known, both the amplitude and the frequency of the limit cycle in a conventional air-fuel ratio control system are determined uniquely by parameters in the system. And this limits our making full use of the oxygen storage effect of TWC. A simple model of TWC reaction revealed the relationship between maximum conversion efficiency and both the amplitude and the frequency in a air fuel control system. It also revealed that TWC conversion efficiency attained to maximum levels when both the amplitude and the frequency of the limit cycle are selected so as to make full use of the oxygen storage effect of TWC. In order to achieve this, it is necessary to vary both the amplitude and the frequency arbitrarily.

A new prototype oxygen storage componented oxygen sensor has been developed which shows significant emission reductions of a 3-way catalyst system. This sensor is composed of ceria, as an oxygen storage component and supported pellets as a buffer layer surrounding the protective coating of the sensor element. This sensor offers a more rapid response than conventional ones under lean and rich fuel mixture excursions, which is caused by CO or O2 electrode poisoning.

Methanol has a poor self-ignition property and thus requires some kind of ignition assist system. Our evaluation of two such systems, a spark-assisted type and a glow-assisted type, indicated that these systems had room for improvement in terms of combustion stability and thermal efficiency in the low-load range. Combustion improvements in the low-load range were therefore carried out by increasing the compression ratio, adopting an injection nozzle with multiple holes and providing an ignition chamber. This has resulted in the successful development of a glow-assisted methanol engine with full-load performance equivalent or superior to a base diesel engine and with lower NOx emission. For practical application of this engine, further improvements in durability and reliability are to be made.

The accuracy of real-time A/F measurement at engine test benches has been improved with a modified equation to calculate A/F from exhaust gas composition. In addition to CO, CO2, total hydrocarbon (THC) and O2, the proposed equation includes NO and NO2 concentration as variables. In an attempt to improve the accuracy of the assumed constants in the equation, experiments have been conducted using automotive exhaust H2O and H2 analyzers. The accuracy of the proposed equation was proven through experiments and it was also found useful for precise evaluation of three-way catalyst or oxygen sensor characteristics.

A particulate trap oxidizer system to reduce diesel particulate emissions has been developed. This system consists of a ceramic foam filter with an optimum volume, shape, and mesh number in terms of collection efficiency, pressure loss and particulate blow-off; a catalyst with a low activated-temperature for particulate incineration and with no sulfate formation during highway driving; and a regeneration system which prevents particulate overcollection during long-term continuous low-load/low-speed driving where it is difficult to achieve self-burning of particulates with a catalytic reaction. This paper describes the development of the particulate trap oxidizer system with these technologies and presents the results of practicability evaluations and 50,000-mile vehicle durability tests.