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Pre-ignition in a boosted spark-ignition engine can be triggered by several mechanisms, including oil-fuel droplets, deposits, overheated engine components and gas-phase autoignition of the fuel-air mixture. A high pre-ignition resistance of the fuel used mitigates the risk of engine damage, since pre-ignition can evolve into super-knock. This paper presents the pre-ignition propensities of 11 RON 89-100+ gasoline fuel blends in a single-cylinder research engine. Albeit the addition of two high-octane components (methanol and reformate) to a toluene primary reference fuel improved the pre-ignition resistance, one high-RON fuel experienced runaway pre-ignition at relatively low boost pressure levels. A comparison of RON 96 blends showed that the fuel composition can affect pre-ignition resistance at constant RON.