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Technical Paper

High-Porosity Honeycomb Substrate with Thin-Wall and High Cell Density Using for SCR Coating to Meet Worldwide Tighter Emission Regulations

2022-03-29
2022-01-0550
Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.
Technical Paper

Particle Number Emission Reduction for GDI Engines with Gasoline Particulate Filters

2017-10-08
2017-01-2378
In order to meet the challenging CO2 targets beyond 2020 despite keeping high performance engines, Gasoline Direct Injection (GDI) technology usually combined with charged aspiration is expanding in the automotive industry. While providing more efficient powertrains to reduce fuel consumption one side effect of GDI is the increased particle formation during the combustion process. For the first time for GDI from September 2014 there is a Particle Number (PN) limit in EU of 6x10 sup 12 #/km, which will be further reduced by one order of magnitude to 6x10 sup 11 #/km effective from September 2017 to be the same level as applied to Diesel engines. In addition to the PN limit of the certification cycle NEDC further certification of Real Driving Emissions (RDE) including portable PN measurements are under discussion by the European Commission. RDE test procedure requires stable and low emissions in a wide range of engine operations and durable over a distance of 160 000 km.
Technical Paper

Evaluation of Hydrothermally Aged Vanadia SCR on High-Porosity Substrate

2016-10-17
2016-01-2320
Ammonia Selective Catalytic Reduction (SCR) is adapted for a variety of applications to control nitrogen oxides (NOx) in diesel engine exhaust. The most commonly used catalyst for SCR in established markets is Cu-Zeolite (CuZ) due to excellent NOx conversion and thermal durability. However, most applications in emerging markets and certain applications in established markets utilize vanadia SCR. The operating temperature is typically maintained below 550°C to avoid vanadium sublimation due to active regeneration of the diesel particulate filter (DPF), or some OEMs may eliminate the DPF because they can achieve particulate matter (PM) standard with engine tuning. Further improvement of vanadia SCR durability and NOx conversion at low exhaust gas temperatures will be required in consideration of future emission standards.
Technical Paper

Development of New High Porosity Diesel Particulate Filter for Integrated SCR Technology/Catalyst

2015-09-01
2015-01-2018
Diesel engines are widely used to reduce CO2 emission due to its higher thermal efficiency over gasoline engines. Considering long term CO2 targets, as well as tighter gas emission, especially NOx, diesel engines must become cleaner and more efficient. However, there is a tradeoff between CO2 and NOx and, naturally, engine developers choose lower CO2 because NOx can be reduced by a catalytic converter, such as a SCR catalyst. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher engine out NOx emission and lower exhaust gas temperatures, close-coupled a diesel particulate filter (DPF) system with integration of SCR catalyst technology is preferred. For SCR catalyst activity, it is known that the catalyst loading amount has an influence on NOx performance, so a high SCR catalyst loading will be required.
Journal Article

Development of New High Porosity Diesel Particulate Filter for Integrated SCR Technology/Catalyst

2015-04-14
2015-01-1017
Since the implementation of Euro 6 in September 2014, diesel engines are facing another drastic reduction of NOx emission limits from 180 to only 80 mg/km during NEDC and real driving emissions (RDE) are going to be monitored until limit values are enforced from September 2017. Considering also long term CO2 targets of 95 g/km beyond 2020, diesel engines must become cleaner and more efficient. However, there is a tradeoff between NOx and CO2 and, naturally, engine developers choose lower CO2 because NOx can be reduced by additional devices such as EGR or a catalytic converter. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher NOx engine out emission and lower exhaust gas temperatures, new aftertreatment systems will incorporate close-coupled DeNOx systems.
Technical Paper

Next Generation of Ceramic Wall Flow Gasoline Particulate Filter with Integrated Three Way Catalyst

2015-04-14
2015-01-1073
A Particle Number (PN) limit for Gasoline Direct Injection (GDI) vehicles was introduced in Europe from September 2014 (Euro 6b). In addition, further certification to Real Driving Emissions (RDE) is planned [1] [2], which requires low and stable emissions in a wide range of engine operation, which must be durable for at least 160,000 km. To achieve such stringent targets, a ceramic wall-flow Gasoline Particulate Filter (GPF) is one potential emission control device. This paper focuses on a catalyzed GPF, combining particle trapping and catalytic conversion into a single device. The main parameters to be considered when introducing this technology are filtration efficiency, pressure drop and catalytic conversion. This paper portrays a detailed study starting from the choice of material recipe, design optimization, engine bench evaluation, and final validation inside a standard vehicle from the market during an extensive field test up to 160,000 km on public roads.
Technical Paper

High Porosity DPF Design for Integrated SCR Functions

2012-04-16
2012-01-0843
Diesel engines are more fuel efficient due to their high thermal efficiency, compared to gasoline engines and therefore, have a higher potential to reduce CO2 emissions. Since diesel engines emit higher amounts of Particulate Matter (PM), DPF systems have been introduced. Today, DPF systems have become a standard technology. Nevertheless, with more stringent NOx emission limits and CO2 targets, additional NOx emission control is needed. For high NOx conversion efficiency, SCR catalysts technology shows high potential. Due to higher temperature at the close coupled position and space restrictions, an integrated SCR concept on the DPFs is preferred. A high SCR catalyst loading will be required to have high conversion efficiency over a wide range of engine operations which causes high pressure for conventional DPF materials.
Technical Paper

Evaluation of Advanced Diesel Oxidation Catalyst Concepts: Part 2

2006-04-03
2006-01-0032
The development of diesel powered passenger cars is driven by the enhanced emission legislation. To fulfill the future emission limits there is a need for advanced aftertreatment devices. A comprehensive study was carried out focusing on the improvement of the DOC as one part of these systems, concerning high HC/CO conversion rates, low temperature light-off behaviour and high temperature aging stability, respectively. The first part of this study was published in [1]. Further evaluations using a high temperature DPF aging were carried out for the introduced systems. Again the substrate geometry and the catalytic coating were varied. The results from engine as well as vehicle tests show advantages in a highly systematic context by changing either geometrical or chemical factors. These results enable further improvement for the design of the exhaust system to pass the demanding emission legislation for high performance diesel powered passenger cars.
Technical Paper

Performance of Catalyzed Particulate Filters without Upstream Oxidation Catalyst

2005-04-11
2005-01-0952
The possibility to employ a single-brick system with a catalyzed filter (CDPF) for the after-treatment of diesel engines is potentially a promising and cost-effective solution. In the first part of this paper, the effectiveness of a single brick CDPF system towards reducing the gaseous CO and HC emissions is investigated experimentally and computationally. The second part of the paper deals with the behavior of single brick catalyzed filters compared with two brick systems comprising an upstream oxidation catalyst. The main differences of the two systems are highlighted in terms of regeneration efficiency and thermal loading, based on simulation results. The modeling work is based on a 3-dimensional model of the catalyzed filter and an axi-symmetric model of the oxidation catalyst. Model validations are presented based on engine bench testing.
Technical Paper

Vehicle Road Simulation Testing, Correlation and Variability

2005-04-11
2005-01-0856
In this paper, responses from a vehicle's suspension, chassis and body, are used to demonstrate a methodology to optimize physical test results. It is well known that there is a variability effect due to an increase of wheel unsprung mass (due to loads measurement fixturing), tire pressure, speed, etc. This paper quantifies loading variability due to Wheel Force Transducer (WFT) unsprung mass by using a rainflow cycle counting domain. Also, presents a proving ground-to-test correlation study and the data reduction techniques that are used in road simulation test development to identify the most nominal road load measurement. Fundamental technical information and analytical methodology useful in overall vehicle durability testing are discussed. Durability testing in a laboratory is designed to correlate fatigue damage rig to road. A Proving Ground (PG) loading history is often acquired by running an instrumented vehicle over one or more PG events with various drivers.
Technical Paper

Modeling and Experimental Study of Uncontrolled Regenerations in SiC Filters with Fuel Borne Catalyst

2004-03-08
2004-01-0697
The objective of this paper is to study the parameters affecting the evolution of “uncontrolled” regeneration in diesel particulate filters with fuel-borne catalyst (FBC) support with emphasis on the development of thermal stresses critical for filter durability. The study is based on experiments performed on engine dynamometer, corresponding to “worst-case” scenario, as well as on advanced, multi-dimensional mathematical modeling. A new 2-dimensional mathematical model is presented which introduces an additional dimension across the soot layer and wall. With this dimension it is possible to take into account the variability of catalyst/soot ratio in the layer and to compute intra-layer composition gradients. The latter are important since they induce interesting O2 diffusion phenomena, which affect the regeneration evolution.
Technical Paper

High Vacuum Purge and Vapor Canister Performance

2004-03-08
2004-01-1435
High vacuum purge enhances the performance of an automotive vapor canister by increasing working capacity and decreasing Diurnal Breathing Loss (DBL) emissions. These improvements are significant because high vacuum purge can potentially be adapted for use in an automotive evaporative emissions system. These benefits were demonstrated by conducting multiple aging cycles at ambient, low, medium, and high vacuum levels. Effects on gasoline working capacity, butane capacity, accumulated hydrocarbon heel, and DBL performance were then compared and discussed.
Technical Paper

Application of Secondary Air Injection for Simultaneously Reducing Converter-In Emissions and Improving Catalyst Light-Off Performance

2002-10-21
2002-01-2803
Improving catalyst light-off characteristics during cold start and reducing engine-out (more accurately converter-in) emissions prior to catalyst light-off have been regarded as the keys to meeting future stringent emissions regulations. Many technologies and control strategies have been proposed, and some of them have already been incorporated into production, to address these issues. Among these, secondary air injection received a lot of attention. This study was initiated to investigate the thermal and chemical processes associated with secondary air injection inside the exhaust system in order to maximize the simultaneous benefit of improving catalyst light-off performance and reducing converter-in emissions. The effects of several design and operating parameters such as secondary air injection location, exhaust manifold design, spark timing, engine enrichment level, and secondary air flow rate were carefully examined.
Technical Paper

Prediction of Draw Bead Coefficient of Friction Using Surface Temperature

2002-03-04
2002-01-1059
Sheet metal stamping involves a system of complex tribological (friction, lubrication, and wear), heat transfer, and material strain interactions. Accurate coefficient of friction, strain, and lubrication regime data is required to allow proper modeling of the various sheet stamping processes. In addition, non-intrusive means of monitoring the coefficient of friction in production stamping operations would be of assistance for efficiently maintaining proper stamping quality and to indicate when adjustments to the various stamping parameters, including maintenance, would be advantageous. One of the key sub-systems of the sheet metal stamping process is the draw bead. This paper presents an investigation of the tribology of the draw bead using a Draw Bead Simulator (DBS) Machine and automotive zinc-coated sheet steels. The investigation and findings include: 1) A new, non-intrusive method of measuring the surface temperature of the sheet steel as it passes through the draw bead.
Technical Paper

Semiconductor Gas Sensors as Control Monitors for NOx Storage Catalytic Converters

2002-03-04
2002-01-1095
Silicon Carbide (SiC) based high temperature semiconductor gas sensors were tested for potential applications in the closed-loop control of NOx storage catalytic converters. The exhaust gas composition behind a storage catalyst was simulated by synthetic gas mixtures supplied from a gas blending manifold. In lean oxidizing ambients the sensors produced signals opposite in sign upon the appearance of NOx on the one hand and mixtures of HC and CO on the other hand. Transient gas measurements revealed response times ranging between several milliseconds for HC and several seconds for NOx. These features render SiC based sensors potentially useful for the control of NOx storage catalytic converters.
Technical Paper

Utilization of Advanced Three-Way Catalyst Formulations on Ceramic Ultra Thin Wall Substrates for Future Legislation

2002-03-04
2002-01-0349
The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).
Technical Paper

Stamping and Crush Performance of Dual Phase Steel

2001-10-16
2001-01-3074
Traditionally, high-strength low-alloy (HSLA) steel is used for automotive vehicle weight reduction in the North American automotive industry. Dual phase (DP) high strength steel has gained great attention because it provides a combination of high strength and good formability. The main advantage of DP steel is the high ratio of tensile strength to yield strength, which provides more flexibility in stamping and higher energy absorption in a component crush event. This study compares the performances of DP and HSLA steel grades in stamping processes and component crush events, as shown in a typical automotive unibody inner rail. Simulation results show that DP steel offers more uniform strain distribution, improved formability, and better crush performance than conventional HSLA steel.
Technical Paper

Application of Advanced Three-Way Catalyst Technologies on High Cell Density Ultra Thin-Wall Ceramic Substrates for Future Emission Legislations

2001-03-05
2001-01-0924
The future emission limits for gasoline fuelled passenger cars require more and more efficient exhaust gas aftertreatment devices - the catalytic converter being one essential part of the complex system design. The present paper summarizes the results of several basic research programs putting major emphasis on the application of highly sophisticated three-way catalyst technologies being taylored for the utilization on ultra thin-wall ceramic substrates. In the first part of the investigation the following effects were examined in detail: Different washcoat loadings at constant PGM-loadings Different volumes of catalysts for constant amounts of PGM and washcoat Similar washcoat technologies at different ratios of WC-loading to precious metal concentration in the washcoat.
Technical Paper

Effect of Forming Strain on Fatigue Performance of a Mild Automotive Steel

2001-03-05
2001-01-0083
The effect of forming strains on the fatigue behavior of an automotive mild steel, interstitial free steel, was studied after being prestrained by balanced biaxial stretch and plane strain. In the long life region, higher than 5×105 reversals, prestrain improves fatigue resistance. In the short life region, prestrain reduces fatigue resistance. At even shorter fatigue lives, the detrimental effect of prestrain diminishes. For plane strains, the fatigue behavior is anisotropic. In the direction perpendicular to the major strain, the steel exhibits much better fatigue resistance than in the direction parallel to the major strain.
Technical Paper

Concepts Designed to Enhance the CustomerS Driving Experience

2000-11-01
2000-01-C031
Throughout its history, the automobile has served the utilitarian purpose of transportation quite well. However, until recently, vehicle occupants have had little else to do while proceeding from point "A'' to point "B.'' The phenomenal improvements in computing and communication technologies promise to evolve the driving experience. Like never before, new opportunities to make driving more efficient and engaging are becoming available. The challenge will be to develop the right combination of technology, safety, design and user interface that creates a product popular with customers.
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