Search Results

Heavy Duty Vehicle (HDV) Diesel emission regulations are set to be tightened in the future. The introduction of PN PEMS testing for Euro VI-e, and the expected tightening of PM/NOx targets set to be introduced by CARB in the US beyond 2024 are expected to create challenging tailpipe PN conditions for OEMs. Additionally, warranty and the useful life period will be extended from current levels. Improved fuel efficiency (reduction of CO2) also remains an important performance criteria. Furthermore, future non-road diesel emission regulations may follow tighten HDV diesel emission regulations contents, and non-road cycles evaluation needs to be considered as well for future. In response to the above tightened regulation, for Diesel Particulate Filter (DPF) technologies will require higher PN filtration performance, lower pressure drop, higher ash capacity and better pressure drop hysteresis for improved soot detectability.

Selective catalyst reduction (SCR) using cordierite honeycomb substrate is generally used as a DeNOx catalyst for diesel engines exhaust in both on-road and commercial off-highway vehicles to meet today’s worldwide emission regulations. Worldwide NOx emission regulations will become stricter, as represented by CARB2027 and EuroVII. Technologies which can achieve further lower NOx emissions are required. Recently, several technologies, like increased SCR catalyst loading amount on honeycomb substrates, and additional SCR catalyst volume in positions closer to the engine are being considered to achieve ultra-low NOx emissions. However, undesirable pressure drop increase and enlarging after treatment systems will be caused by adopting these technologies. Therefore, optimization of the material and honeycomb cell structure for SCR is inevitable to achieve ultra-low NOx emissions, while minimizing any system drawbacks.

In order to meet the challenging CO2 targets beyond 2020 without sacrificing performance, Gasoline Direct Injection (GDI) technology, in combination with turbo charging technology, is expanding in the automotive industry. However, while this technology does provide a significant CO2 reduction, one side effect is increased Particle Number (PN) emission. As a result, from September 2017, GDI vehicles in Europe are required to meet the stringent PN emission limits of 6x1011 #/km under the Worldwide harmonized Light vehicles Test Procedure (WLTP). In addition, it is required to meet PN emission of 9x1011 #/km under Real Driving Emission (RDE) testing, which includes a Conformity Factor (CF) of 1.5 to account for current measurement inaccuracies on the road. This introduction of RDE testing in Europe and China will especially provide a unique challenge for the design of exhaust after-treatment systems due to its wide boundary conditions.

With the push towards more stringent on-road US heavy duty diesel regulations (i.e. HD GHG Phase 2 and the proposed ARB 20 mg/bhp-hr NOx), emission system packaging has grown critical while improving fuel economy and NOx emissions. The ARB regulations are expected to be implemented post 2023 while regulation for EU off-road segment will begin from 2019. The regulation, called Stage V, will introduce particle number (PN) regulation requiring EU OEMs to introduce a diesel particulate filter (DPF) while customer demands will require the OEMs to maintain current emission system packaging. A viable market solution to meet these requirements, especially for EU Stage V being implemented first, is a DPF coated with a selective catalyst reduction (SCR) washcoat (i.e. SCRonDPF).

In order to meet the challenging CO2 targets beyond 2020 despite keeping high performance engines, Gasoline Direct Injection (GDI) technology usually combined with charged aspiration is expanding in the automotive industry. While providing more efficient powertrains to reduce fuel consumption one side effect of GDI is the increased particle formation during the combustion process. For the first time for GDI from September 2014 there is a Particle Number (PN) limit in EU of 6x10 sup 12 #/km, which will be further reduced by one order of magnitude to 6x10 sup 11 #/km effective from September 2017 to be the same level as applied to Diesel engines. In addition to the PN limit of the certification cycle NEDC further certification of Real Driving Emissions (RDE) including portable PN measurements are under discussion by the European Commission. RDE test procedure requires stable and low emissions in a wide range of engine operations and durable over a distance of 160 000 km.

Diesel engines are widely used to reduce CO2 emission due to its higher thermal efficiency over gasoline engines. Considering long term CO2 targets, as well as tighter gas emission, especially NOx, diesel engines must become cleaner and more efficient. However, there is a tradeoff between CO2 and NOx and, naturally, engine developers choose lower CO2 because NOx can be reduced by a catalytic converter, such as a SCR catalyst. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher engine out NOx emission and lower exhaust gas temperatures, close-coupled a diesel particulate filter (DPF) system with integration of SCR catalyst technology is preferred. For SCR catalyst activity, it is known that the catalyst loading amount has an influence on NOx performance, so a high SCR catalyst loading will be required.

Since the implementation of Euro 6 in September 2014, diesel engines are facing another drastic reduction of NOx emission limits from 180 to only 80 mg/km during NEDC and real driving emissions (RDE) are going to be monitored until limit values are enforced from September 2017. Considering also long term CO2 targets of 95 g/km beyond 2020, diesel engines must become cleaner and more efficient. However, there is a tradeoff between NOx and CO2 and, naturally, engine developers choose lower CO2 because NOx can be reduced by additional devices such as EGR or a catalytic converter. Lower CO2 engine calibration, unfortunately, leads to lower exhaust gas temperatures, which delays the activation of the catalytic converter. In order to overcome both problems, higher NOx engine out emission and lower exhaust gas temperatures, new aftertreatment systems will incorporate close-coupled DeNOx systems.

Diesel particulate filters (DPF) are a common component in emission-control systems of modern clean diesel vehicles. Several DPF materials have been used in various applications. Silicone Carbide (SiC) is common for passenger vehicles because of its thermal robustness derived from its high specific gravity and heat conductivity. However, a segmented structure is required to relieve thermal stress due to SiC's higher coefficient of thermal expansion (CTE). Cordierite (Cd) is a popular material for heavy-duty vehicles. Cordierite which has less mass per given volume, exhibits superior light-off performance, and is also adequate for use in larger monolith structures, due to its lower CTE. SiC and cordierite are recognized as the most prevalent DPF materials since the 2000's. The DPF traps not only combustible particles (soot) but also incombustible ash. Ash accumulates in the DPF and remains in the filter until being physically removed.

Diesel engines are more fuel efficient due to their high thermal efficiency, compared to gasoline engines and therefore, have a higher potential to reduce CO2 emissions. Since diesel engines emit higher amounts of Particulate Matter (PM), DPF systems have been introduced. Today, DPF systems have become a standard technology. Nevertheless, with more stringent NOx emission limits and CO2 targets, additional NOx emission control is needed. For high NOx conversion efficiency, SCR catalysts technology shows high potential. Due to higher temperature at the close coupled position and space restrictions, an integrated SCR concept on the DPFs is preferred. A high SCR catalyst loading will be required to have high conversion efficiency over a wide range of engine operations which causes high pressure for conventional DPF materials.

The Inlet-Membrane DPF, which has a small pore size membrane formed on the inlet side of the body wall, has been developed as a next generation diesel particulate filter (DPF). It simultaneously achieves low pressure drop, small pressure drop hysteresis, high robustness, and high filtration efficiency. Low pressure drop improves fuel economy. Small pressure drop hysteresis has the potential to extend the regeneration interval since the linear relationship between pressure drop and accumulated soot mass improves the accuracy of soot mass detection by means of the pressure drop values. The Inlet-membrane DPF's high robustness also extends the regeneration interval resulting in improved fuel economy and a lower risk of oil dilution while its high filtration efficiency reduces PM emissions. The concept of the Inlet-Membrane DPF was confirmed using disc type filters in 2008 and its performance was evaluated using full block samples in 2009.

Gasoline Direct Injection (GDI) engines achieve better fuel economy but have the drawback of increased Particulate Matter (PM) emissions. As known from diesel engine applications particulate filters are an effective PM reduction device which is expected to be effective for reduction of particulates emitted by GDI engines as well. For this investigation new filter concepts especially designed for GDI applications are proposed. Filtration efficiency, pressure drop and regeneration performance were verified by cold flow bench and engine and chassis dynamometer testing. The experimental data were used to discuss the validity of these new filter design concepts.

A wall flow diesel particulate filter (DPF) having a novel wall pore structure design for reducing backpressure, increasing robustness, and increasing filtration efficiency is presented. The filter offers a linear relationship between soot loading and backpressure, offering greater accuracy in estimating the amount of soot loading from backpressure. Basic experiments were performed on small plate test pieces having various pore structure designs. Soot generated by a Cast-2F propane burner having a controlled size distribution was used. Cold flow test equipment that was carefully designed for flow distribution and soot/air mixing was used for precise measurement of backpressure during soot loading. The upstream and downstream PM numbers were counted by Scanning Mobility Particle Sizer (SMPS) to determine soot concentration in the gas flow and filtration efficiency of the test pieces. Microscope observations of the soot trapped in the wall were also carried out.

Developing ultra thin wall ceramic substrates is necessary to meet stricter emissions regulations, in part because substrate cell walls need to be thinner in order to improve warm-up and light-off characteristics and lower exhaust system backpressure. However, the thinner the cell wall becomes, the poorer the mechanical and thermal characteristics of the substrate. Furthermore, the conditions under which the ultra thin wall substrates are used are becoming more severe. Therefore both the mechanical and thermal characteristics are becoming important parameters in the design of advanced converter systems. Whereas square cells are used world-wide in conjunction with oxidation and/or three-way catalysts, hexagonal cells, with features promoting a homogeneous catalyst coating layer, have found limited use as a NOx absorber due to its enhanced sulfur desorption capability.

Further stringent emission legislation requires advanced technologies, such as sophisticated engine management and advanced catalyst and substrate to achieve high catalytic performance, especially during the light-off phase. This paper presents the results of calculations and measurements of hydrocarbon and carbon monoxide light-off performance for substrates of different wall thickness, cell density and cell shapes. The experimental data from catalyst light-off testing on an engine dynamometer are compared with theoretical results of computer modeling under different temperature ramps and flow rates. The reaction kinetics in the computer modeling are derived from the best fit for the performance of conventional ceramic substrate (6mil/400cpsi), by comparing the theoretical and experimental results on both HC and CO emissions. The calibrated computer model predicts the effects of different wall thickness, cell density and cell shape.

New ultra-low vehicle emission legislation requires advanced catalyst systems to achieve high conversion requirements. Manufacturers have to improve both the washcoat formulations and the catalyst substrate technology to meet these new regulations. This paper will present the results of a computer modeling study on the effects of ultra-thinwall catalysts on hydrocarbon and carbon monoxide light-off performance improvement. The experimental data from catalyst light-off testing on an engine dynamometer are compared with theoretical results of advanced substrate modeling for ultra-thin wall ceramic substrates. Results show that thermal mass has the greatest effect on light-off performance. Decreases in wall thickness offer the greatest benefit to light-off performance by lowering the thermal mass of the substrate, thus allowing it to reach light-off temperature faster.

In this study, to satisfy increasingly strict emission regulations, the conversion efficiency of a 0.11 mm (4 mil) thin-wall catalyst is discussed. The effects of catalyst bulk density on reducing heat mass to improve catalyst emission conversion in the early cold transient mode (Bag 1 in the FTP-75 mode) is quantitatively discussed. To analyze the effects of low heat mass, catalyst's bed temperatures were measured. Effects of the geometric surface area (GSA) and volume of the catalyst were also analyzed. An early feedback control system with an HEGO oxygen sensor and a secondary air injection control system with an original oxygen sensor were compared with an original control system on THC, CO, and NOx emission amounts.

Ceramic honeycomb wall flow diesel particulate filters (DPF) have been investigated for use in exhaust gas control of diesel vehicles. However, before they can be used, prevention of thermal shock failure during combustion regeneration is necessary. Studies were conducted on thermal shock failures on 9-inch diameter large volume DPF during regeneration by finite element analyses (FEA). These studies reveal that, within safe limits, maximum thermal stress is almost constant even at different gas flow rates and oxygen concentrations. Regeneration tests were also conducted on large volume DPF of several materials having different pore size distributions. FEA thermal stress was compared with mechanical strength of the material at safe levels.

Application of ceramic honeycomb wall-flow type diesel particulate filters (DPF) to heavy duty vehicles requires a large volume filter. Heavy duty vehicles produce a large volume exhaust gas, and pressure drop in the exhaust system must be maintained to a certain level. In addition, the filters must be designed to resist fracture from thermal stresses during regeneration. This is particularly important in heavy duty vehicles because of these extended mileage requirements. These studies of the effects of DPF volume on thermal shock resistance during regeneration reveal that the maximum failure temperatures are lower as DPF volume is increased, still maintaining 950°C maximum temperature with 12 ℓ volume and 9″D × 12″L size large DPF. Some thermal stress analyses with temperature profiles and finite element analysis were conducted on four different volume DPF during regeneration.