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Technical Paper

Monoglyceride Content in Marine Diesel Fuel-A Guide

2014-10-13
2014-01-2775
Problems with the low-temperature operability performance of biodiesel in blends with petroleum diesel are infrequent, but continue to limit the use of biodiesel during winter months. A troubling aspect of this problem is that in some cases precipitates above the blend Cloud Point (CP) have been detected and have led to plugging of fuel filters and subsequent engine stalling, as well as plugging of fuel dispenser filters. Many researchers found that the saturated monoglyceride content was a main component of the material that was found on plugged fuel filters, as well as traces of Saturated DiGlycerides (SDG), were also present on the plugged fuel filters. This is the reason which forced the organization of standardization to suggest a procedure in order to predict the content of the Saturated MonoGlycerides (SMG) even with uncertainty which can vary from −50% to +50%. The model which was used will be the same as that which was introduced in the Annex C of EN 14214+A1:2013.
Technical Paper

Production of Biobased Lubricant Basestocks with Improved Performance

2012-09-10
2012-01-1620
The ability of a catalyst to enhance the performance of synthesized biobased lubricant basestock was investigated in this study. Pomace olive oil, cottonseed oil, used frying oil and methyl oleate were utilized as starting materials for the production of the biobased lubricants and a two stages transesterification methodology was followed. Initially the oils were converted to their corresponding fatty acid methyl esters via methanolysis. The resulting methylesters were subsequently transesterified with TMP producing the desired oleochemical ester. These syntheses were carried out in the presence of either sodium methoxide or Ca/TEA alkoxide as catalysts. Following the purification phase, the synthesized esters were evaluated as potential biolubricants regarding their physicochemical properties such as viscosity index, pour point and acid value.
Journal Article

Impact of Simultaneous ETBE and Ethanol Addition on Motor Gasoline Properties

2008-10-06
2008-01-2503
This study examines the impact of ETBE and ethanol addition on the main properties of motor gasoline. European Union mandates the use of biofuels in all transport fuels, according to the 2003/30/EC Directive. The addition of ethanol, a known octane enhancing component, in small proportions significantly increases the vapor pressure of the final gasoline, exceeding the maximum specification limits. ETBE (ethyl tert-butyl ether) is on the other hand an excellent but expensive octane enhancing component with beneficial impact on vapor pressure of the final gasoline. This paper examines the ability of ETBE to act as a stabilizer in gasoline - ethanol blends. Two gasoline samples with different chemical compositions and characteristics were prepared by blending basic refinery components. In each sample, ETBE was added in concentrations of 2, 4, and 6 % V/V respectively. In each of these ETBE - gasoline blends, ethanol was added in concentrations from 1 to 6 % V/V in 1% steps.
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