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Diamond-Like Carbon (DLC) is a promising engine material for reducing friction and wear on sliding parts. By contrast, MoDTC lubricant additives are known to promote the wear of a-C:H films. However, the mechanism that promotes wear and the formation of tribofilms on DLC parts when in contact with molybdenum-based lubricant additives has not been sufficiently studied. The purpose of this research is to determine the wear promotion mechanism and formation of tribofilm on DLC by lubricant additives by comparing friction and wear properties. We conducted friction and wear tests using a tribometer with DLC (ta-C, ta-C:H, a-C, and a-C:H) blocks, FC250 (cast iron) rings, and oils containing lubricant additives (MoDTC, MoDTP, and Mo without DTC ligand) by observing and analyzing the sliding surfaces of specimens. No wear was observed for any of the DLCs (ta-C, ta-C:H, a-C:H, and a-C) in combination with oils containing MoDTP or Mo without DTC ligands.

A mean value turbocharged engine model is useful in terms of accuracy and convenience for fuel economy strategies or engine controller development. Turbocharging process is a feedback system with a positive gain, i.e. increasing exhaust work leads to increasing a cycle work. The gain of the feedback system is determined mainly by exhaust work ratio in a cycle and inertia of the turbine. The work ratio was investigated based on engine test with EGR. A turbocharging process model was obtained using the work ratio in a cycle and theoretical equations. The model is applied to investigate manifold absolute pressure response with EGR.

Gasoline engines have the trace-knock phenomena induced by the fast combustion which happens a few times during 100 cycles. And that constrains the thermal efficiency improvement due to limiting the ignition timing advance. So the authors have been dedicating a trace-knock simulation so that we could obtain any pieces of information associated with trace-knock characteristics. This simulation consists of a turbulent combustion model, a cycle-by-cycle variation model and a chemical calculation subprogram. In the combustion model, a combustion zone is considered in order to obtain proper turbulent combustion speed through wide range of engine speed. From a cycle-by-cycle variation analysis of an actual gasoline engine, some trace-knock features were detected, and they were involved in the cycle-by-cycle variation model. And a reduced elementary reaction model of gasoline PRF (primary reference fuel) was customized to the knocking prediction, and it was used in the chemical calculation.

n-Tridecane is a low boiling point component of gas oil, and has been used as a single-component fuel for diesel spray and combustion experiments. However, no reduced chemical kinetic mechanisms for n-tridecane have been presented for three-dimensional modeling. A detailed mechanism developed by KUCRS (Knowledge-basing Utilities for Complex Reaction Systems), contains 1493 chemical species and 3641 reactions. Reaction paths during ignition process for n-tridecane in air computed using the detailed mechanism, were analyzed with the equivalence ratio of 0.75 and the initial temperatures of 650 K, 850 K, and 1100 K, which are located in the cool-flame dominant, negative-temperature coefficient, and blue-flame dominant regions, respectively.

The purpose of this study is to elucidate flame propagation behavior of homogeneous propane-air mixture under application of non-uniform electric field. A needle-shaped electrode was attached to the ceiling and a plate electrode was set at bottom of combustion chamber, so that the electric field was applied in the direction of the chamber's vertical axis. A homogeneous propane-air mixture was supplied at equivalence ratio of 1.0 and was ignited by leaser induced breakdown under atmospheric pressure and room temperature. It was found that the flame front and plate electrode were repelled each other and a thin air layer was formed between the flame and plate electrode when a relatively low positive DC non-uniform electric field was applied to the needle-shaped electrode. It might be thought that the induced current was generated in the flame front, so that the flame front and plate electrode repelled each other.

Downsizing engines with a turbocharging system have been widely applied to passenger cars to improve fuel economy. Engine torque response to accelerator operation is one of important features in addition to steady state performance of the system. Torque profile management for turbocharged internal combustion engines is one of required technologies. A turbocharging system for a car is a system with a positive feedback loop in which compressed air drives the compressor after the combustion process. A reduced order model was derived for the charging system. Pressure ratio of a compressor is proportional to square of turbine speed and the turbine speed is a first order delay system to throttle opening in the model. Model structure was designed from mathematical equations that describe turbine and compressor works. Model parameters were identified from measured data. An output torque profile control strategy based on the derived model is investigated.

To execute the computational fluid dynamics coupling with fuel chemistry in internal combustion engines, simplified chemical kinetic models which capture the low-temperature oxidation kinetics would be required. A steady-state analysis was applied to see the complicated reaction mechanism of alkylperoxy radicals by assuming the steady state for hydroperoxyalkyl (QOOH) and hydroperoxyalkylperoxy (OOQOOH) radicals. This analysis clearly shows the systematic trend of the reaction rate for the chain-branching and non-branching process of alkylperoxy (ROO) radicals as a function of the chain length and the carbon class. These trends make it possible to classify alkylperoxy radicals by their chemical structures, and suggest a reduced low-temperature oxidation chemistry.

One of the authors has proposed to use the decay rate of EHRR, the effective heat release rate, d2Q/dθ2 as an index for the rapid local combustion [1]. In this study, EHRR profiles and the cylinder gas pressure oscillations of the low and high speed knock are analyzed by using this index. A delayed rapid local combustion, such as an autoignition with small burned mass fraction can be detected. In the cases of the low speed knock, it has been agreed that a rapid local combustion is an autoignition. Although whether the cylinder gas oscillation is provoked by an auto ignition in a certain cycle or not is an irregular phenomenon, the auto ignition takes place in almost all of the cycles in the knocking condition. Mixture mass fraction burned by an auto ignition is large. A small auto ignition may induce a secondary auto ignition, in many cases, mass burned by the secondary auto ignition is extremely large.

A KIVA code which is customized for passenger car's diesel engines is linked with an engine performance simulator and demonstrated with our optimizing calculation system. Aiming to fulfill our target calculation speed, the combustion model of the KIVA code is changed from a chemical reaction calculation method to a chemical equilibrium calculation method which is introduced a unique technique handling chemical species maps. Those maps contain equilibrium mole fraction data of chemical species according to equivalence ratio and temperature. Linking the KIVA code to the engine simulator helps to evaluate engine performance by indicated mean effective pressure (IMEP). The optimizing calculation system enables to obtain response surfaces. Observing the response surfaces, clear views of engine performance characteristics can be seen. The overview of this calculation system and some examples of the calculation are shown in this paper.

The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

Knocking combustion experiments were conducted in this study using a test engine that allowed the entire bore area to be visualized. The purpose was to make clear the detailed characteristics of knocking combustion that occurs accompanied by cylinder pressure oscillations when a Homogeneous Charge Compression Ignition (HCCI) engine is operated at high loads. Knocking combustion was intentionally induced by varying the main combustion period and engine speed. Under such conditions, knocking in HCCI combustion was investigated in detail on the basis of cylinder pressure analysis, high-speed photography of the combustion flame and spectroscopic measurement of flame light emissions. The results revealed that locally occurring autoignition took place rapidly at multiple locations in the cylinder when knocking combustion occurred. In that process, the unburned end gas subsequently underwent even more rapid autoignition, giving rise to cylinder pressure oscillations.

The ignition delay times and heat release profiles of CH4, C2H6, C3H8, i-C4H10, and n-C4H10 and dual-component CH4-based blends with these alkanes in air were determined using a detailed chemical kinetic model. The apparent activation energy of C2H6 in the relationship between initial temperature and ignition delay time is higher than those of the other alkanes because OH formation is dominated by H2O2(+M)=OH+OH(+M) from the beginning over a wide range of initial temperatures. The heat release rate of C2H6 is higher than those of the other alkanes in the late stage of ignition delay time because H2O2 is accumulated with a higher concentration and promotes the OH formation rate of H2O2(+M)=OH+OH(+M). These ignition characteristics are reflected in those of CH4/C2H6.

The relationships between the octane number and the carbon atom number and the molecular structure of alkanes were comprehensively analyzed by using the detailed kinetic model generated by there automatic reaction scheme generation tool, KUCRS [1, 2]. The octane number is an index showing the ignition delay in the engine temperature regime, that is, the engine ignition temperature range. The high octane number is observed in the following two cases; 1 The ignition delay of the low temperature region is large. 2 The ignition delay of the low temperature region is the same, but the transition temperature for NTC (Negative Temperature Coefficient) region is low.

A great deal of interest is focused on Homogeneous Charge Compression Ignition (HCCI) combustion today as a combustion system enabling internal combustion engines to attain higher efficiency and cleaner exhaust emissions. Because the air-fuel mixture is compression-ignited in an HCCI engine, control of the ignition timing is a key issue. Additionally, because the mixture ignites simultaneously at multiple locations in the combustion chamber, it is necessary to control the resultant rapid combustion, especially in the high-load region. Supercharging can be cited as one approach that is effective in facilitating high-load operation of HCCI engines. Supercharging increases the intake air quantity to increase the heat capacity of the working gas, thereby lowering the combustion temperature for injection of the same quantity of fuel. In this study, experiments were conducted to investigate the effects of supercharging on combustion characteristics in an HCCI engine.

Combustion experiments were conducted with an optically accessible engine that allowed the entire bore area to be visualized for the purpose of making clear the characteristics that induce extremely rapid HCCI combustion and knocking accompanied by cylinder pressure oscillations. The HCCI combustion regime was investigated in detail by high-speed in-cylinder visualization of autoignition and combustion and emission spectroscopic measurements. The results revealed that increasing the equivalence ratio and advancing the ignition timing caused the maximum pressure rise rate and knocking intensity to increase. In moderate HCCI combustion, the autoignited flame was initially dispersed temporally and spatially in the cylinder and then gradually spread throughout the entire cylinder.

There are few investigations to change wood biomasses to the industrially available energy, so that a new conversion technology of biomass to liquid fuel has been established by the direct liquefaction process. However, cellulosic liquefaction fuel (for short CLF) cold not mixed with diesel fuel. In this study, the plastic was mixed with wood to improve the solubility of CLF to diesel fuel. CLF made by the direct co-liquefaction process could be stably and completely mixed with diesel fuel in any mixing ratio and CLF included 2 wt.% of oxygen. The test engine was an air-cooled, four-stroke, single cylinder, direct fuel injection diesel engine. In the engine starting condition test, the ignition timing of 5 wt.% CLF mixed diesel fuel was slightly delayed at immediately after the engine started, however the ignition timing was almost the same as diesel fuel after the engine was warmed-up.

Engine downsizing with a turbocharger / supercharger has attracted attention as a way of improving the fuel economy of automotive gasoline engines, but this approach can be frustrated by the occurrence of abnormal combustion. In this study, the factors causing abnormal combustion were investigated using a supercharged, downsized engine that was built by adding a mechanical supercharger. Combustion experiments were conducted in which the fuel octane number and supercharging pressure were varied while keeping the engine speed, equivalence ratio and intake air temperature constant. In the experiments, a visualization technique was applied to photograph combustion in the combustion chamber, absorption spectroscopy was used to investigate the intermediate products of combustion, and the cylinder pressure was measured. The experimental data obtained simultaneously were then analyzed to examine the effects on combustion.

A Homogeneous Charge Compression Ignition (HCCI) engine was operated under a continuous firing condition in this study to visualize combustion in order to obtain fundamental knowledge for suppressing the rapidity of combustion in HCCI engines. Experiments were conducted with a two-stroke engine fitted with a quartz observation window that allowed the entire bore area to be visualized. The effect of varying the compression ratio and fuel octane number on HCCI combustion was investigated. In-cylinder spectroscopic measurements were made at compression ratios of 11:1 and 15:1 using primary reference fuel blends having different octane numbers of 0 RON and 50 RON. The results showed that varying the compression ratio and fuel octane number presumably has little effect on the rapidity of HCCI combustion at the same ignition timing when the quantity of heat produced per cycle by the injected fuel is kept constant.

Some experimental data indicate that an HCCI process of a highly diluted mixture is characterized with a two-stage profile of heat release after the heat release by low-temperature oxidation, and with slow CO oxidation into CO₂ at a low temperature. In the present paper, these characteristics are discussed using a detailed chemical kinetic model of normal heptane, and based on an authors' idea that an ignition process can be divided into five phases. The H₂O₂ loop reactions mainly contribute to heat release in a low-temperature region of the TI (thermal ignition) preparation phase. However, H+O₂+M=HO₂+M becomes the main contributor to heat release in a high-temperature region of the TI preparation phase. H₂O₂ is accumulated during the LTO (low-temperature oxidation) and NTC (negative temperature oxidation) phases, and drives the H₂O₂ loop reactions to increase the temperature during the TI preparation phase.

Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.