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A fuel reforming technology using a low temperature oxidation was developed to improve a NOx reduction performance of HC-SCR (Hydrocarbons Selective Catalytic Reduction) system, which does not require urea. The low-temperature oxidization of a diesel fuel in gas phase produces NOx reduction agents with high NOx reduction ability such as aldehydes and ketones. A pre-evaporation-premixing-type reformer was adopted in order to generate a uniform temperature field and a uniform fuel/air premixed gas, and to promote the low temperature oxidation efficiently. As a fundamental study, elementary reaction analysis for n-hexadecane/air premixtures was carried out to investigate the suitable reformer temperature and fuel/air equivalence ratio for generation of oxygenated hydrocarbons. It was found that the reforming efficiency was highest at the reforming temperature around 623 to 673K, and aldehydes and ketones were produced.

The purpose of this study is to explore an effect of cooled-EGR on the diesel engine performance fueled with coconut-oil methyl ester (CME). The exhaust gas was cooled by the water at room temperature and was fed to the intake manifold, and the EGR rate was changed from 0 % to 30 % at every 10 %. The engine performances were measured at several EGR rates, fuel injection pressures and timings. Test fuels were CME and commercial diesel fuel. In the case of high EGR rate at which the compression ignition was deteriorated, the ignition timing of CME was always earlier than that of diesel fuel, therefore CME had good ignitability as compared with diesel fuel under EGR application. When the fuel injection pressure was increased at high EGR rate, the ignition delay was improved by the fuel atomization and air-fuel mixing effect.

Effects of measurement method, coolant temperature and fuel composition on soot emissions were examined by engine experiments. By reducing the pressure fluctuation in the sampling line, the measured soot emissions with better stability and reproducibility could be obtained. With lower coolant temperatures, larger soot emissions were yielded at much advanced fuel injection timings. Compared to gasoline, soot emissions with a blend fuel of normal heptane, isooctane and toluene were significantly decreased, suggesting the amounts of aromatic components (toluene or others) should be increased to obtain a representative fuel for the predictive model of particulate matter in SIDI engines.

In this study, the effect of autoignition behavior in the unburned end-gas region on pressure wave formation and knock intensity was investigated. A single-cylinder gasoline engine capable of high-speed observation of the end gas was used in the experiments. Visualization in the combustion chamber and spectroscopic measurement of light absorption by the end gas were carried out to analyze autoignition behavior in the unburned end-gas portion and the reaction history before autoignition. The process of autoignition and pressure wave growth was investigated by analyzing multipoint pressure histories. As a result, it was found that knocking intensity increases through interaction between autoignition and pressure waves.

This study investigated the influence of EGR and spark advance on knocking under high compression ratio, ultra-lean mixture and supercharged condition using premium gasoline as a test fuel. A high-compression ratio, supercharged single cylinder engine was used in this experiment. As a result, the period from ignition to autoignition was prolonged. In addition, knock intensity was drastically reduced. In other words, it is inferred that by combining an appropriate amount of EGR and spark advance, high efficiency operation avoiding knocking can be realized.

The purpose of this study was to investigate how autoignition leads to the occurrence of pressure oscillations. That was done on the basis of in-cylinder visualization and analysis of flame images captured with a high-speed camera using an optically accessible engine, in-cylinder pressure measurement and measurement of light emission from formaldehyde (HCHO). The results revealed that knocking intensity tended to be stronger with a faster localized growth speed of autoignition. An investigation was also made of the effect of exhaust gas recirculation (EGR) as a means of reducing knocking intensity. The results showed that the application of EGR advanced the ignition timing, thereby reducing knocking intensity under the conditions where knocking occurred.

Engine knock is the one of the main issues to be addressed in developing high-efficiency spark-ignition (SI) engines. In order to improve the thermal efficiency of SI engines, it is necessary to develop effective means of suppressing knock. For that purpose, it is necessary to clarify the mechanism generating pressure waves in the end-gas region. This study examined the mechanism producing pressure waves in the end-gas autoignition process during SI engine knock by using an optically accessible engine. Occurrence of local autoignition and its development process to the generation of pressures waves were analyzed under several levels of knock intensity. The results made the following points clear. It was observed that end-gas autoignition seemingly progressed in a manner resembling propagation due to the temperature distribution that naturally formed in the combustion chamber. Stronger knock tended to occur as the apparent propagation speed of autoignition increased.

Internal combustion engines have been required to achieve even higher efficiency in recent years in order to address environmental concerns. However, knock induced by abnormal combustion in spark-ignition engines has impeded efforts to attain higher efficiency. Knock characteristics during abnormal combustion were investigated in this study by in-cylinder visualization and spectroscopic measurements using a four-stroke air-cooled single-cylinder engine. The results revealed that knock intensity and the manner in which the autoignited flame propagated in the end gas differed depending on the engine speed.

The purpose of this study is to explore an effect of the coconut oil methyl ester (CME) and vegetable oil methyl ester (VME) on a low compression ratio diesel engine performance. CME and VME were produced from coconut oil and vegetable oil with methanol, respectively. Vegetable oil was assumed to contain 60 wt.% of soybean oil and 40 wt.% rapeseed oil. The engine performance was measured in the steady operating condition at 3600 rpm of engine speed. The ignition timings of CME and VME were advanced and the maximum cylinder pressures of CME and VME were higher as compared with the diesel fuel at low compression ratio, because CME and VME consisted of medium chain fatty acid methyl esters. The ignitability of CME was superior to VME, because CME consisted of saturated fatty acid. The brake thermal efficiency of diesel fuel was slightly higher than CME and VME at any compression ratios.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. However, because HCCI engines lack a physical means of initiating ignition, it is difficult to control the ignition timing. Another issue of HCCI engines is that the combustion process causes the cylinder pressure to rise rapidly. The time scale is also important in HCCI combustion because ignition depends on the chemical reactions of the mixture. Therefore, we investigated the influence of the engine speed on autoignition and combustion characteristics in an HCCI engine. A four-stroke single-cylinder engine equipped with a mechanically driven supercharger was used in this study to examine HCCI combustion characteristics under different engine speeds and boost pressures.

In-cylinder visualization of the entire bore area at an identical frame rate was used to investigate knocking conditions under spark ignition (SI) combustion and under Homogeneous Charge Compression Ignition (HCCI) combustion in the same test engine. A frequency analysis was also conducted on the measured pressure signals. The results revealed that a combustion regime accompanied by strong pressure oscillations occurred in both the SI and HCCI modes, which was presumably caused by rapid autoignition with attendant brilliant light emission that took place near the cylinder wall. It was found that the knocking timing was the dominant factor of this combustion regime accompanied by cylinder pressure oscillations in both the SI and HCCI combustion modes.

Improving the thermal efficiency of internal combustion engines requires operation under a lean combustion regime and a higher compression ratio, which means that the causes of autoignition and pressure oscillations in this operating region must be made clear. However, there is limited knowledge of autoignition behavior under lean combustion conditions. Therefore, in this study, experiments were conducted in which the ignition timing and intake air temperature (scavenging temperature) of a 2-stroke optically accessible test engine were varied to induce autoignition under a variety of conditions. The test fuel used was a primary reference fuel with an octane rating of 90. The results revealed that advancing the ignition timing under lean combustion conditions also advanced the autoignition timing, though strong pressure oscillations on the other hand tended not to occur.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Technologies for further improving vehicle fuel economy have attracted widespread attention in recent years. However, one problem with some approaches is the occurrence of abnormal combustion such as low-speed pre-ignition (LSPI) that occurs under low-speed, high-load operating conditions. One proposed cause of LSPI is that oil droplets diluted by the fuel enter the combustion chamber and become a source of ignition. Another proposed cause is that deposits peel off and become a source of ignition. A four-stroke air-cooled single-cylinder engine was used in this study to investigate the influence of Ca-based additives having different properties on abnormal combustion by means of in-cylinder visualization and absorption spectroscopic measurements. The results obtained for neutral and basic Ca-based additives revealed that the former had an effect on advancing the time of autoignition.

Suppression or reduction of soot emissions is an important goal in the development of automotive engines for environmental and human health purposes. A better understanding at the molecular level of the formation process of soot particles resulting from collision and aggregation of smaller particles made of Polycyclic Aromatic Hydrocarbon (PAH) is needed. In addition to experiments, computational methods are efficient and valuable tools for this purpose. As a first step in our detailed computational chemistry study, we applied Ultra-Accelerated Molecular Dynamics (UAQCMD) and Canonical Monte-Carlo (CMC) methods to investigate the nucleation process. The UA-QCMD can calculate chemical reaction dynamics 107 times faster than conventional first principle molecular dynamics methods, while CMC can calculate equilibrium properties at various temperatures, pressures, and chemical compositions.

One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.

Homogeneous Charge Compression Ignition (HCCI) engines have attracted much attention and are being widely researched as engines characterized by low emissions and high efficiency. However, one issue of HCCI engines is their limited operating range because of the occurrence of rapid combustion at high loads and misfiring at low loads. It is known that knocking accompanied by in-cylinder pressure oscillations also occurs in HCCI engines at high loads, similar to knocking seen in spark-ignition engines. In this study, HCCI combustion accompanied by in-cylinder pressure oscillations was visualized by taking high-speed photographs of the entire bore area. In addition, the influence of internal exhaust gas circulation (EGR) on HCCI knocking was also investigated. The visualized combustion images revealed that rapid autoignition occurred in the end-gas region during the latter half of the HCCI combustion process when accompanied by in-cylinder pressure oscillations.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

Internal combustion engines today are required to achieve even higher efficiency and cleaner exhaust emissions. Currently, research interest is focused on premixed compression ignition (Homogeneous Charge Compression Ignition, HCCI) combustion. However, HCCI engines have no physical means of initiating ignition such as a spark plug or the fuel injection timing and quantity. Therefore, it is difficult to control the ignition timing. In addition, combustion occurs simultaneously at multiple sites in the combustion chamber. As a result, combustion takes place extremely rapidly especially in the high load region. That makes it difficult for the engine to operate stably at high loads. This study focused on the fuel composition as a possible means to solve these problems. The effect of using fuel blends on the HCCI operating region and combustion characteristics was investigated using a single-cylinder test engine.

This study investigated the origin of knocking combustion accompanied by pressure wave and strong pressure oscillations in a Homogeneous Charge Compression Ignition (HCCI) engine. Experiments were conducted with a two-stroke single cylinder optically accessible engine that allowed the entire bore area to be visualized. The test fuel used was n-heptane. The equivalence ratio and intake temperature were varied to induce a transition from moderate HCCI combustion to extremely rapid HCCI combustion accompanied by in-cylinder pressure oscillations. Local autoignition and pressure wave behavior under each set of operating conditions were investigated in detail on the basis of high-speed in-cylinder visualization and in-cylinder pressure analysis. As a result, under conditions where strong knocking occurs, a brilliant flame originates from the burned gas side in the process where the locally occurring autoignition gradually spreads to multiple locations.