Search Results

Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).

A new stratified charge system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle and a shell-shaped piston cavity. This system, basically classified into the wall-guided mixture preparation concept that leads air/fuel mixture to the spark plug periphery by means of spray penetration and piston cavity configuration without an extra intake air flow controlling system, obtained wide engine operating area with stratified combustion and high output performance. This report presents the characteristics of stratified mixture formation and combustion, especially the important factor for achieving stable stratified combustion in the high-speed region, which have been clarified through analytical studies.

Two effects of rich-spike duration on NOx-storing have been analyzed. The first one, that NOx-storing speed decreases as rich-spike duration increases, is explained as the influence of NOx diffusion in wash-coat layer, which is quantified by a simple mathematical expression for NOx-storing rate. The second one, a peculiar behavior of NOx-storing in appearance of the outlet NOx concentration, is clarified: Heat produced directly or indirectly (via oxygen storage in ceria) by rich-spike warms up the downstream part, which releases excess NOx at the raised temperature. Contributions of the oxygen storage and the carbonate of NOx-storage material are also discussed.

An all aluminum cylinder block with a Metal Matrix Composite (MMC) cylinder bore was developed which made it possible to re-design the base engine for high performance with a bore-to-bore distance as narrow as 5.5mm. The cylinder block is an open deck type and the MMC preform consists of alumina-silica fibers and mulite particles. A laminar flow die cast process was selected to ensure defect-free MMC bore quality. To insure good lubrication, electrochemical machining was applied to the bore surface. By use of radioisotope(RI) measurements, MMC reinforcement was optimized for wear characteristics. Particular attention was paid to use of fuels with high sulfur levels.

This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.

Recently, in the automobile industry, developing a plastic material type distinction system has been highly demanded for plastic recycling. We have developed a handy plastic distinction device which distinguishes between polypropylene (PP) and polyurethane (PU) and also distinguishes between 3 types of plastic wheel caps according to the electrostatic capacity and the light reflection pattern of the plastic. The device is operated by a dry battery (9V), so that it can be easily placed in the recovery field of waste automobile plastic parts.

New ductile cast iron flywheel integrated with gear and its manufacturing process were developed to reduce the manufacturing steps and cost compared with conventional flywheel around which a steel ring gear is fit. In this process, the ring gear teeth around a cast iron flywheel are formed directly in net shape and free from any defect by the hot form-rolling method, followed by the thermomechanical treatment in a short time. The gear is superior to that made by the conventional hobbing and heat treatment in accuracy, strength and anti-wear property.

A precise control system for a molten ferrous alloy temperature above 1700 K after the completion of induction melting has been developed in order to produce high quality casting parts for automobiles. In this system, the molten ferrous alloy temperature is measured just one time by a disposable thermocouple after the melting. The system predicts the temperature transition after the measurement using an original thermal model, and adjusts the supplied electric power to the furnace automatically according to the predicted temperature. Using this thermal model, the system has attained control deviations within ±5K under the following temperature controls, and contributed to the quality control of casting parts and the energy-saving during furnace operations. Casting temperature for a cast-steel of 1813 K in a 300 kg capacity high-frequency induction furnace on the “Toyota Vacuum Casting Process”.

Transient temperature and concentration distribution inside a catalytic converter during warm-up have been analyzed by experiments and numerical simulation. There is great maldistribution of species concentrations inside a converter during warm-up. Carbon monoxide (CO) and hydrocarbons (HC) have high concentrations in the exhaust gas passing through outer region cells because they are not converted due to low wall temperature. The effects of the noble metal loading pattern on conversion characteristics during warm-up have been investigated by numerical simulation. The effects of high-loading on improving conversion characteristics are saturated with the loading quantity of six times that of the base-loading. High-loading of the noble metal only on the frontal region (20 or 30mm. from the front face) has almost the same warming-up conversion performance as the uniform high-loading.

A reduced chemical kinetic model has been developed using temperature history measured by Coherent Anti-Stokes Raman Spectroscopy (CARS) and sensitivity analysis. Predictions of knock occurrence by this model show that the chemical role of residual gas and the intake flow have little effect on the knock occurrence crank angle. Furthermore, the effectiveness of the combustion period and the unburned gas temperature before spark ignition on the torque at trace knock limit (TTKL) has been clarified Under certain conditions, it is shown that the increase in torque, caused by the combustion duration shortened by ∼25%, is negated by the temperature rise of ∼15K before spark ignition.