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This work explores the effect of the particle matter index (PMI) and aromatic content on fuel wall impingement associated with stochastic pre-ignition (SPI). Statically significant measurements of SPI rates are directly coupled with laser induced florescence (LIF) measurements of fuel dilution from spray-linear impingement. Literature suggests that PMI is could be correlated with the number of SPI events, but the root cause(s) of PMI and SPI are directly causational or are a predicator of SPI. Three fuels have been used in this study with 3 different PMI and two different aromatic contents. The fuels are direct injected at two different injection timings, an earlier injection timing which initially targets the piston crown, 310°CA bTDC, and a later injection timing that the liner, 220°CA bTDC start of injection timings (SOI) respectively. The earlier 310 SOI injection increases soot, whereas the later 220°CA SOI targets the liner and increases wall-wetting.