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Technical Paper

The Formation of Ammonia in Three-Way Catalysts Fitted to Spark Ignition Engines - Mechanisms and Magnitudes

2022-08-30
2022-01-1026
Exhaust gas aftertreatment systems can, under certain conditions, create undesired chemical species as a result of their elimination reactions. A prime example of this is ammonia (NH3), which is not formed in the combustion reaction, but which can be formed within a three-way catalyst (TWC) when physicochemical conditions permit. The elimination of NOx in the TWC thus sometimes comes at the cost of significant emissions of NH3. Ammonia is a pollutant and a reactive nitrogen compound (RNC) and NH3 emissions should be analyzed in this context, alongside other RNC species. Examination of the literature on the subject published over the past two decades shows that ammonia, a species which is currently not subject to systematic emissions requirements for road vehicles in any market, is often identified as forming the majority of the RNC emissions under a range of operating conditions.
Technical Paper

Exhaust Emissions from Two Euro 6d-Compliant Plug-In Hybrid Vehicles: Laboratory and On-Road Testing

2021-04-06
2021-01-0605
This paper discusses the legislative situation regarding type approval of plug-in hybrid vehicles (also known as off-vehicle charging hybrid-electric vehicles, OVC-HEV) in the range of exhaust emissions and fuel consumption. A range of tests were conducted on two Euro 6d-complaint OVC-HEVs to quantify emissions. Procedures were based on EU legislative requirements. For laboratory (chassis dyno) testing, two different test cycles and three different ambient temperatures were used for testing. Furthermore, in some cases additional measurements were performed, including measurement of emissions of particulate matter and continuous analysis of regulated and unregulated pollutants in undiluted exhaust. Consumption of electrical energy was also monitored. On-road testing was conducted on the test vehicle tested on the chassis dyno in the tests mentioned above, as well as on a second OVC-HEV test vehicle.
Technical Paper

A Comparison of Tailpipe Gaseous Emissions from the RDE and WLTP Test Procedures on a Hybrid Passenger Car

2020-09-15
2020-01-2217
Non-plugin hybrids represent a technology with the capability to significantly reduce fuel consumption (FC), without any changes to refuelling infrastructure. The EU market share for this vehicle type in the passenger car segment was 3% in 2018 and this powertrain type remains of interest as an option to meet the European Union (EU) fleet average CO2 limits. EU legislative procedures require emissions limits to be met during the chassis dynamometer test and in the on-road real driving emissions (RDE) test, while official CO2/FC figures are quantified via the laboratory chassis dynamometer test only. This study employed both legislative test procedures and compared the results. Laboratory (chassis) dynamometer testing was conducted using the Worldwide Harmonised Light Vehicles Test Procedure (WLTP). On-road testing was carried out in accordance with RDE requirements, measuring the concentration of regulated gaseous emissions and the number of solid particles (PN).
Technical Paper

RDE-Compliant PEMS Testing of a Gasoline Euro 6d-TEMP Passenger Car at Two Ambient Temperatures with a Focus on the Cold Start Effect

2020-04-14
2020-01-0379
European Union RDE (real driving emissions) legislation requires that new vehicles be subjected to emissions tests on public roads. Performing emissions testing outside a laboratory setting immediately raises the question of the impact of ambient conditions - especially temperature - on the results. In the spirit of RDE legislation, a wide range of ambient temperatures are permissible, with mathematical moderation (correction) of the results only permissible for ambient temperatures <0°C and >+30°C. Within the standard range of temperatures (0°C to +30°C), no correction for temperature is applied to emissions results and the applicable emissions limits have to be met. Given the well-known link between the thermal state of an engine and its emissions following cold start, ambient temperature can be of great importance in determining whether a vehicle meets emissions requirements during an RDE test.
Technical Paper

RDE Testing of Passenger Cars: The Effect of the Cold Start on the Emissions Results

2019-04-02
2019-01-0747
This paper discusses the importance of the inclusion of emissions from the cold start event during legislative on-road tests on passenger cars (RDE - real driving emissions tests conducted under real-world driving conditions, as defined by EU legislation). Results from a recently-registered gasoline-powered vehicle are presented, with the main focus on the comparison of exhaust emission results: excluding/including the cold start during the initial phase of the RDE test. Cold start is the most challenging aspect of emissions control for vehicles with spark ignition engines and the inclusion of the cold start event in RDE test procedure has wide-ranging implications both for the testing process and compliance with RDE legislation via optimisation of aftertreatment systems and the engine calibration. In addition to some theoretical arguments, the results of an RDE-compliant test performed using the aforementioned procedures are presented.
Technical Paper

A Comparison of Gaseous Emissions from a Hybrid Vehicle and a Non-Hybrid Vehicle under Real Driving Conditions

2018-04-03
2018-01-1272
In this study, two vehicles were tested under real driving conditions with gaseous exhaust emissions measured using a portable emissions measurement system (PEMS). One of the vehicles featured a hybrid powertrain with a spark ignition internal combustion engine, while the other vehicle featured a non-hybrid (conventional) spark ignition internal combustion engine. Aside from differences in the powertrain, the two test vehicles were of very similar size, weight and aerodynamic profile, meaning that the power demand for a given driving trace was very similar for both vehicles. The test route covered urban conditions (but did include driving on a road with speed limit 90 km/h). The approximate test route distance was 12 km and the average speed was very close to 40 km/h.
Technical Paper

Analysis of Emission Factors in RDE Tests As Well as in NEDC and WLTC Chassis Dynamometer Tests

2016-04-05
2016-01-0980
This paper presents a study of passenger cars in terms of emissions measurements in tests conducted under real driving conditions (RDE - Real Driving Emissions) by means of PEMS (Portable Emission Measurement System) equipment. A special feature of the RDE tests presented in this paper is that they were performed under Polish conditions and the specified parameters may differ from those in most other European Union countries. Emission correction coefficients have been defined, based on the test results, equal to the increase (or decrease) of driving emissions during the laboratory (‘chassis dyno’) test or during normal usage in relation to the EU emission standards (emission class) of the vehicle.
Technical Paper

The Influence of Oxygenated Diesel Fuels on a Diesel Vehicle PM/NOx Emission Trade-Off

2009-11-02
2009-01-2696
Research on the influence of oxygenated diesel fuels on the PM/NOx emission trade-off was carried out with use of 11 different synthetic oxygenated compounds, representing 3 chemical groups (glycol ethers, maleates, carbonates). Each of oxygenates were evaluated as a fuel additive at a concentration of 5% v/v in the same base diesel fuel. The tests were conducted on a passenger car equipped with a common rail turbocharged diesel engine over the European cycle NEDC and US FTP-75 cycle. All the tested oxygenates caused a reduction in PM emissions and most of them caused a certain increase in NOx emissions. The changes in emissions depended on the oxygenate type and cycle. In general, the favorable and unfavorable influence of oxygenated compounds was more intensive during the NEDC, which is a softer and less transient cycle than the FTP-75. The most favorable changes in the PM/NOx emission trade-off were obtained for maleates and carbonates.
Technical Paper

The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions - Part 3

2008-10-06
2008-01-2387
The paper presents the test results relating to the influence of carbonate oxygenated additives to diesel fuel on exhaust emissions. Following the previous tests of glycol ethers (SAE Paper 2007-01-0069) and maleates (SAE Paper 2008-01-1813), the authors decided to use carbonates to obtain an even greater reduction in PM emissions. The significant effectiveness of carbonates on PM emission reduction was confirmed in tests performed by the authors. Diethyl carbonate was the most effective oxygenated compound with regard to PM emission reduction among all the 11 oxygenates which have been tested so far. Moreover, it is important to note that diethyl carbonate caused only a small increase in NOx emissions, thus it allowed for an essential improvement in the PM/NOx trade-off. A significant increase in the CO and HC emissions was, however, a negative effect of the use of carbonates.
Technical Paper

The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions - Part 2

2008-06-23
2008-01-1813
The paper presents the test results of the influence of maleate oxygenated additives to diesel fuel on exhaust emissions. Following the previous tests of glycol ethers (SAE Paper 2007-01-0069), the authors decided to use maleates as oxygenates to obtain greater changes in PM/NOx trade-off than the changes obtained as a result of the use of glycol ethers. It was found that in the NEDC maleates at the same concentration as in the case of glycol ethers ensure more favourable changes of PM/NOx trade-off and, as a matter of fact, caused greater reduction in PM emissions without the growth of NOx emissions, however, at the cost of CO and HC emissions. The tests performed in the FTP-75 confirmed a significantly weaker influence of maleates, both positive (PM) and negative (CO, HC) than in the NEDC. They did not find in both cycles any influence of maleates at the tested concentration upon fuel consumption and CO2 emissions.
Technical Paper

Effects of Fuel Properties on Exhaust Emissions from the Latest Light-Duty DI Diesel Engine

2003-05-19
2003-01-1882
The great reduction in future diesel engine emission limits, especially PM and NOx, forces one to develop means to comply with stringent legislation. Environmentally friendly fuels are regarded as a very effective means to decrease emissions. Although the emission reduction is less than could be achieved by the most modern engine technology or alternative fuels, the immediate net effect of reformulated diesel fuel on emissions is significant, as it takes place over the whole vehicle population. The experimental results presented in this paper were obtained within a research program investigating the effect of different fuels upon emissions from compression-ignition automotive engines. The research were carried out in the laboratories of the BOSMAL Automotive R & D Centre in co-operation to Institute of Internal Combustion Engines at Poznan University of Technology. The partial results of this research program were presented in SAE Paper 2002-01-2219.
Technical Paper

Analysis of the Influence of Fuel Sulphur Content on Diesel Engine Particulate Emissions

2002-07-09
2002-01-2219
The motor vehicle is one of the main sources of pollutant emissions, especially in urban areas. Environmentally friendly fuels are regarded as very effective means to decrease emissions. With regard to diesel engines, the reduction in nitrogen oxides and particulates are major problem areas. Although the fuel influence on NOx is comparatively low, the composition and parameters of diesel fuel have a big influence on particulate emissions and composition. Sulphur content is one of fuel proprieties, which has the most considerable influence on particulates. This paper describes results of the research on particulate emissions from diesel engines fuelled with research fuels of differing sulphur content. The sulphur content of the research fuels varied from 2000 ppm through 350 ppm (EURO III) and 50 ppm (EURO IV limit, which will be in force in the European Community from 1 January 2005) up to less than 5 ppm.
Technical Paper

A Method of Reducing the Exhaust Emissions from DI Diesel Engines by the Introduction of a Fuel Cut Off System During Cold Start

2001-10-01
2001-01-3283
This paper reviews the exhaust emissions from direct injection (DI) diesel engines in the initial period following start-up. The tests were undertake in “cold start” mode (the temperature of the cooling water and lube oil being equal to the ambient temperature) and “warm start” modes (after achieving a state of equilibrium). The results from both states are compared. Exhaust emissions in the period from cold start is very important and must be improved in order to satisfy present day standards worldwide. A significant emission decrease during cold start can be achieved by incorporating selective fuel cut-off during the few seconds directly after beginning of engine crank. Compared to the acceptable gaseous pollutant concentrations, it was observed that an almost 50% reduction in hydrocarbon emission and a 30% reduction in carbon monoxide emissions were obtained (3 minutes of idle run).
Technical Paper

Investigation of Exhaust Emissions from DI Diesel Engine During Cold and Warm Start

2001-03-05
2001-01-1260
This paper reviews the emissions from direct injection (DI) diesel engine in the initial period of controlled engine operation following start-up. The tests were undertaken in „cold start” mode (temperature of cooling water and lube oil equal to ambient temperature) and „warm start” mode* (after attaining a state of equilibrium). Both results were compared.
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