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The chief goal of engineers studying internal combustion engines is to improve energy efficiency in the face of the increasingly severe global warming and energy issues. Hence, there have been numerous studies focusing on the combustion reactions in order to develop clean and reliable combustion that is capable of operating using less fuel. And to improve the comprehension of engine performance and its combustion reactions, development of comprehensive measurement technique for engine performance, in-cylinder visualization technique, and numerical simulations, is essential and strongly demanded. There have hitherto been numerous studies about combustion diagnostics and analysis, including high-efficiency measurement techniques using response surface method the air-fuel mixture distribution and flame propagation measurement with optical visualization techniques, and numerical calculations of combustion reaction with elementary reactions.