Search Results

To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.

Turbine housings in car engine turbochargers, which use costly stainless steel castings, account for nearly 50% of the parts cost of a turbocharger. They are also the component which controls the competitiveness of the turbocharger, in terms of both function and cost. In this research, focusing on thermal fatigue resistance which is one of the main functions demanded of a turbine housing, achieving reduction in wall thickness while securing sufficient thermal fatigue resistance, it is possible to reduce the amount of material used in the turbine housing and aimed for cost reduction. Therefore, we built a method to quantitatively predict, using 3D FEM, the lifespan from the initiation of thermal fatigue cracking to the formation of a penetrating crack which leads to gas leakage.

In recent years, studies have been conducted on the relationship between the J factor, which indicates flow of molten aluminum at the time of injection, and the quality of HPDC products. The flow of molten metal at a high J factor is referred to as “Atomized Flow.” The authors and others conducted studies on the relationship between the J factor and the strength of HPDC products. An area exceeding 300MPa was found in the product produced at a high J factor corresponding to the “Atomized Flow.” The defect was less in the above-mentioned position because the gas porosity was finely dispersed. Considering that the fine dispersion of gas porosity is related to the “Atomized Flow”, pictures were taken to analyze “Atomized Flow.” The molten aluminum was ejected into an open space at a high speed and the splashed conditions were photographed. From the images taken by the pulse laser permeation, the conditions of microscopic atomized flow were observed precisely.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

Piston ring wear in gasoline engine induces deterioration of emissions performance due to leakage of blow-by gas, instability of idling caused by reduced compression in combustion chamber, and to generate early degeneration of engine oil. We examined anti-wear performance of DLC coating on piston ring, which had been recently reported as an effective method for improving the abrasion resistance. As a result, wear rate remained low under the condition of DLC existence on sliding surface, but once DLC was worn out completely, wear of the piston ring was accelerated and its life became shorter than piston ring without DLC. In this research, we designed reciprocating test apparatus that operates at much higher velocity range, and characterized the frictional materials of the piston ring and sleeve and the DLC as a protective film, a vapor phase epitaxy (VPE) was actively used as a means to form certain level of convex and concave shape on its surface.

1. On page 111, the authors have described a method to assess driver distraction. In this method, participants maintained a white square size on a forward display by using a game gas pedal of like in car-following situation. The size of the white square is determined by calculating the distance to a virtual lead vehicle. The formulas to correct are used to explain variation of acceleration of the virtual lead vehicle. The authors inadvertently incorporated old formulas they had used previously. In the experiments discussed in the article, the corrected formulas were used. Therefore, there is no change in the results. The following from the article:

A new nitriding technology and material technology have been developed to increase the strength of microalloyed gears. The developed nitriding technology makes it possible to freely select the phase composition of the nitride compound layer by controlling the treatment atmosphere. The treatment environment is controlled to exclude sources of supply of [C], and H2 is applied as the carrier gas. This has made it possible to control the forward reaction that decomposes NH3, helping to enable the stable precipitation of γ′-phase, which offers excellent peeling resistance. A material optimized for the new nitriding technology was also developed. The new material is a low-carbon alloy steel that makes it possible to minimize the difference in hardness between the compound layer and the substrate directly below it, and is resistant to decline in internal hardness due to aging precipitation in the temperature range used in the nitriding treatment.

Catalyst simulation, which can analyze the complicated reaction pathway of exhaust gas purifications and identify the rate-determining step, is an essential tool in the development of catalyst materials. This requires an elementary reaction model which describes the detailed processes, i.e. adsorption, decomposition, and others. In our previous work, the elementary reaction model on Pt/CeO2 catalyst was constructed. In this study, we focused on extending the Zeolite catalyst and including the gas diffusivity through the catalyst layer. The reaction rate of a Zeolite catalyst was expressed by an Arrhenius equation, and the elementary reaction model was composed of 17 reactions. Each Arrhenius parameter was optimized by the catalytic activity measurements. The constructed model was validated with NOx conversion in cyclic experiments which were repeated with Lean phase (NOx adsorption) and Rich phase (NOx reduction).

By increasing the percentage of highly dissociative strong acid components included in the neutralizing acid of the electrodeposition coating, it was possible to improve electrical conductivity and coulomb efficiency and achieve excellent throwing power. The GA cratering caused by the increase in the strong acid ratio was resolved by setting the strong acid ratio to 90% while reducing MEQ. By increasing coulomb efficiency, the quantity of hydrogen gas produced during electrodeposition was minimized, and as a result, gas pinholes remaining in the coating were reduced, increasing the smoothness of the coating beyond than that of the current materials. As a result of this study, the usage of e-coating per vehicle body was reduced by approximately 11%.

The reduction of NOx in exhaust gas has been a major challenge in diesel engine development. For the NOx reduction issues, a new Lean NOx Catalyst (LNC) aftertreatment system has been developed by Honda. A feature of the LNC system is the method that is used to reduce NOx through an NH₃-Selective Catalytic Reduction (NH₃-SCR). In an LNC system NOx is adsorbed at lean conditions, then converted to NH₃ at rich conditions and subsequently reduced in the next lean phase. In recent years, as the efficiency of the diesel engine has improved, the exhaust gas temperatures have been reduced gradually. Therefore, the aftertreatment system needs to be able to purify NOx at lower temperatures. The development of a new LNC which has a high activity at low temperature has been carried out. For the improvement of the LNC three material improvements were developed. The first of these was the development of a NOx adsorbent which is matching the targeted exhaust gas temperatures.

Conventionally, the Ni-based superalloys NCF3015 (30Ni-15Cr) and the high nickel content NCF440 (70Ni-19Cr) (with its outstanding wear resistance and corrosion resistance), have been used as engine exhaust valve materials. In recent years, automobile exhaust gases have become hotter because of exhaust gas regulations and enhanced fuel consumption efficiency. Resource conservation and cost reductions also factor into global environmental challenges. To meet these requirements, NCF5015 (50Ni-15Cr), a new resource-conserving, low-cost Ni-based heat-resistant alloy with similar high-temperature strength and wear resistance as NCF440, has been developed. NCF5015's ability to simultaneously provide wear resistance, corrosion resistance and strength when NCF5015 is used with diesel engines was verified and the material was then used in exhaust valves.

The influence of elevated temperature forming on local mechanical properties of AZ31B magnesium (Mg) sheet material was investigated. The Mg sheet was formed into a closure component with high temperature gas pressure at 485°C. Miniature tensile testing specimens were cut from selected areas of the component where different levels of thinning occurred. The specimens were strained in tension to fracture using a miniature tensile stage. The two-dimensional strain distribution in the necking region along with true stress-true strain curves were computed using a digital image correlation technique to assess the influence of the forming-induced thinning on tensile strength and percent elongation at fracture.

Owing to its combustion characteristics and chemical composition, natural gas features cleaner emissions and lower CO2 compared to gasoline under equal thermal efficiency. Natural gas can be a promising alternative energy source to respond to crude oil exhaustion and global warming issues. Focusing on the utility of natural gas, a feasibility study on CNG (Compressed Natural Gas) -fueled two-wheeled vehicles has been conducted. A proto-type two-wheeled vehicle was made based on a 125 cm3 class gasoline-fueled scooter. To adapt the engine to the use of CNG fuel, an electronically controlled gas injection system was applied to the fuel supply system. To provide abrasion resistance of engine valves and valve seats, the specific matter of gas-fuel was improved. Furthermore, a lubricant circulation passage was added to maintain the temperature of the pressure reducing valve.

In most motorcycle engines, blow-by gas is introduced into the air intake system, including the air cleaner, for the purpose of reducing the blow-by gas emissions in the crankcase. In such a system, the water and gasoline components of the blow-by gas get mixed into the engine oil under some driving conditions. This oil contamination shortens the oil replacement intervals. In order to reduce this problem, we devised a system to ventilate the crankcase positively and installed it on the engine of a small motorcycle. The system had a construction to draw fresh air with a one way valve that is actuated by the change in pressure inside the crankcase. The inside of the crankcase is ventilated by the fresh air. In the case of small motorcycle engines, if the gas positively ventilated from the inside of the crankcase were guided to the downstream of the throttle valve, the engine performance under low -loads, including idling, is significantly changed by the inflow of the gas.

Using sand cores, the weld-able, hollow die-cast parts have been developed. For casting, the transition flow filling method is applied to reduce gas containment and to minimize damages to the core. In designing the products, the newly developed core stress prediction system by melt pressure distribution and the newly developed in-product gas containment prediction system have been applied. The hollow die-cast frame made by the new method attains a 30% increase in rigidity and 1kg reduction of weight.

The super-ultra-low-emission-vehicle (SULEV) non-methane organic gas (NMOG) hydrocarbon exhaust standard as legislated by the state of California LEV II regulations is 10 milligrams per mile. This requires that the associative instrumentation must be capable of accurately and precisely determining total hydrocarbons (THC) concentrations on the order of 10 parts per billion-carbon (ppbC) for vehicle tests run under optimum conditions on a bag mini-diluter (BMD) test site. The flame ionization detector (FID) is the standard instrument used in the measurement of THC. Currently, there are many instrument manufacturers that produce these types of analyzers. This paper studies the limit of detection and accuracy capabilities of one of these instruments, the Beckman 400A FID. In addition, the paper shows evidence that supports that this “state of technology” as described by this instrument, is sufficient to meet the demands of the today's most stringent, vehicle emission standards.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

As automotive exhaust emission levels reduce, there is a need for increased sensitivity of the NOx measurement. This paper documents work performed to increase the sensitivity of the existing Rosemount NGA 2000 CLD Analyzer. The effects of sample flow rate, ozone flow rate and ozone supply gas were explored. Limit of Detection (LOD) and Converter Efficiency were evaluated. The goal of this optimization has been to provide a cost effective and expeditious method to improve the low level NOx measurement. Changing the ozone generator supply gas from air to oxygen and increasing the sample and ozone flow rates resulted in a LOD improvement from 17 ppb to 8 ppb.

Copolymer materials have been used for the collection of vehicle exhaust gas samples since the inception of regulatory standards. Some of these copolymers contain N,N-dimethylacetamide (DMA), which is added to improve the physical properties of the copolymer and eliminate manufacturing problems. DMA is highly soluble in water, and in effect is rinsed from the emission bag surface by humid exhaust gas samples. This study shows that DMA can thus incorrectly add to test vehicle overall hydrocarbon emissions. The DMA contribution can be significant for lower level emission vehicles. This study introduces a new bag material, KYNAR®, which significantly reduces this interference.