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Methanol is one of the most promising fuels for the decarbonization of the off-road and transportation sectors. Although methanol is typically seen as an alternative fuel for spark ignition engines, mixing-controlled compression ignition (MCCI) combustion is typically preferred in most off-road and medium-and heavy-duty applications due to its high reliability, durability and high-efficiency. In this paper, the potential of using ignition enhancers to enable methanol MCCI combustion was investigated. Methanol was blended with 2-ethylhexyl nitrate (EHN) and experiments were performed in a single-cylinder production-like diesel research engine, which has a displacement volume of 0.83 L and compression ratio of 16:1. The effect of EHN has been evaluated with three different levels (3%vol, 5%vol, and 7%vol) under low- and part-load conditions. The injection timing has been swept to find the stable injection window for each EHN level and load.

Ethanol blending is one method that can be used to reduce knock in spark ignition engines by decreasing the autoignition reactivity of the fuel and modifying its laminar flame speed. In this paper, the effects of ethanol blending on knock propensity and flame speed of petroleum and low-carbon gasoline fuels is analyzed. To do so, surrogate fuels were formulated for methanol-to-gasoline (MTG) and ethanol-to-gasoline (ETG) based on the fuels’ composition, octane number, and select physical properties; and 0-D and 1-D chemical kinetics simulations were performed to investigate reactivity and laminar flame speed, respectively. Results of MTG and ETG were compared against those of PACE-20, a well-characterized surrogate for regular E10 gasoline. Similarly to PACE-20, blending MTG and ETG with ethanol increases the fuel’s research octane number (RON) and sensitivity.

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies with very low NOx and soot emissions, but rapid control of the combustion timing remains a challenge. Partial Fuel Stratification (PFS) was demonstrated to be an effective approach to control combustion in LTGC engines. PFS is produced by a double-direct injection (DI) strategy with most of the fuel injected early in the cycle and the remainder of the fuel supplied by a second injection at a variable time during the compression stroke to vary the amount of stratification. Adjusting the stratification changes the combustion phasing, and this can be done on cycle-to-cycle basis by adjusting the injection timing. In this paper, the ability of PFS to control the combustion during wide engine load sweeps is assessed for regular gasoline and gasoline doped with 2-ethylhexyl nitrate (EHN). For PFS, the load control range is limited by combustion instability and poor combustion efficiency at low loads.

Methanol emerges as a compelling renewable fuel for decarbonizing engine applications due to a mature industry with high production capacity, existing distribution infrastructure, low carbon intensity and favorable cost. Methanol’s high flame speed and high autoignition resistance render it particularly well-suited for spark-ignition (SI) engines. Previous research showed a distinct phenomenon, known deflagration-based knock in methanol combustion, whereby knocking combustion was observed albeit without end-gas autoignition. This work studies the implications of deflagration-based knock on noise emissions by investigating the knock intensity and combustion noise at knock-limited operation of methanol in a single-cylinder direct-injection SI engine operated at both stoichiometric and lean (λ = 2.0) conditions. Results are compared against observations from a premium-grade gasoline.

Surrogate fuels that reproduce the characteristics of full-boiling range fuels are key tools to enable numerical simulations of fuel-related processes and ensure reproducibility of experiments by eliminating batch-to-batch variability. Within the PACE initiative, a surrogate fuel for regular-grade E10 (10%vol ethanol) gasoline representative of a U.S. market gasoline, termed PACE-20, was developed and adopted as baseline fuel for the consortium. Although extensive testing demonstrated that PACE-20 replicates the properties and combustion behavior of the full-boiling range gasoline, several concerns arose regarding the purity level required for the species that compose PACE-20. This is particularly important for cyclo-pentane, since commercial-grade cyclo-pentane typically shows 60%–85% purity. In the present work, the effects of the purity level of cyclo-pentane on the properties and combustion characteristics of PACE-20 were studied.

The influence of early induction stroke direct injection on late-cycle flows was investigated for a lean-burn, high-tumble, gasoline engine. The engine features side-mounted injection and was operated at a moderate load (8.5 bar brake mean effective pressure) and engine speed (2000 revolutions per minute) condition representative of a significant portion of the duty cycle for a hybridized powertrain system. Thermodynamic engine tests were used to evaluate cam phasing, injection schedule, and ignition timing such that an optimal balance of acceptable fuel economy, combustion stability, and engine-out nitrogen oxide (NOx) emissions was achieved. A single cylinder of the 4-cylinder thermodynamic engine was outfitted with an endoscope that enabled direct imaging of the spark discharge and early flame development.

End-gas temperature stratification has long been studied with respect to its effect on stoichiometric spark-ignition (SI) engine knock. The role of temperature stratification for homogeneous-charge compression ignition (HCCI) engine operation is also reasonably well understood. However, the role of temperature stratification in ultra-lean SI engines has had less coverage. Literature is lacking well-controlled studies of how knock is affected by changes in the full cylinder temperature fields, especially since cycle-to-cycle variability can impede a determination of cause and effect. In this work, the knocking propensity of specific cylinder conditions is investigated via 3D computational fluid dynamics (CFD) simulations utilizing a large eddy simulation (LES) framework.

To cope with regulatory standards, minimizing tailpipe emissions with rapid catalyst light-off during cold-start is critical. This requires catalyst-heating operation with increased exhaust enthalpy, typically by using late post injections for retarded combustion and, therefore, increased exhaust temperature. However, retardability of post injection(s) is constrained by acceptable pollutant emissions such as unburned hydrocarbon (UHC). This study provides further insight into the mechanisms that control the formation of UHC under catalyst-heating operation in a medium-duty diesel engine, and based on the understanding, develops combustion strategies to simultaneously improve exhaust enthalpy and reduce harmful emissions. Experiments were performed with a full boiling-range diesel fuel (cetane number of 45) using an optimized five-injections strategy (2 pilots, 1 main, and 2 posts) as baseline condition.

Nitric Oxide (NO) can significantly influence the autoignition reactivity and this can affect knock limits in conventional stoichiometric SI engines. Previous studies also revealed that the role of NO changes with fuel type. Fuels with high RON (Research Octane Number) and high Octane Sensitivity (S = RON - MON (Motor Octane Number)) exhibited monotonically retarding knock-limited combustion phasing (KL-CA50) with increasing NO. In contrast, for a high-RON, low-S fuel, the addition of NO initially resulted in a strongly retarded KL-CA50 but beyond the certain amount of NO, KL-CA50 advanced again. The current study focuses on same high-RON, low-S Alkylate fuel to better understand the mechanisms responsible for the reversal in the effect of NO on KL-CA50 beyond a certain amount of NO.

Autoignition enhancing additives have been used for years to enhance the ignition quality of diesel fuel, with 2-ethylhexyl nitrate (EHN) being the most common additive. EHN also enhances the autoignition reactivity of gasoline, which has advantages for some low-temperature combustion techniques, such as Sandia’s Low-Temperature Gasoline Combustion (LTGC) with Additive-Mixing Fuel Injection (AMFI). LTGC-AMFI is a new high-efficiency and low-emissions engine combustion process based on supplying a small, variable amount of EHN into the fuel for better engine operation and control. However, the mechanism by which EHN interacts with the fuel remains unclear. In this work, a chemical-kinetic mechanism for EHN was developed and implemented in a detailed mechanism for gasoline fuels. The combined mechanism was validated against shock-tube experiments with EHN-doped n-heptane and HCCI engine data for EHN-doped regular E10 gasoline. Simulations showed a very good match with experiments.

Injector performance in gasoline Direct-Injection Spark-Ignition (DISI) engines is a key focus in the automotive industry as the vehicle parc transitions from Port Fuel Injected (PFI) to DISI engine technology. DISI injector deposits, which may impact the fuel delivery process in the engine, sometimes accumulate over longer time periods and greater vehicle mileages than traditional combustion chamber deposits (CCD). These higher mileages and longer timeframes make the evaluation of these deposits in a laboratory setting more challenging due to the extended test durations necessary to achieve representative in-use levels of fouling. The need to generate injector tip deposits for research purposes begs the questions, can an artificial fouling agent to speed deposit accumulation be used, and does this result in deposits similar to those formed naturally by market fuels?

To comply with increasingly stringent pollutant emissions regulations, diesel engine operation in a catalyst-heating mode is critical to achieve rapid light-off of exhaust aftertreatment catalysts during the first minutes of cold starting. Current approaches to catalyst-heating operation typically involve one or more late post injections to retard combustion phasing and increase exhaust temperatures. The ability to retard post injection timing(s) while maintaining acceptable pollutant emissions levels is pivotal for improved catalyst-heating calibrations. Higher fuel cetane number has been reported to enable later post injections with increased exhaust heat and decreased pollutant emissions, but the mechanism is not well understood. The purpose of this experimental and numerical simulation study is to provide further insight into the ways in which fuel cetane number affects combustion and pollutant formation in a medium-duty diesel engine.

This work is a comprehensive technical review of existing literature and a synthesis of current understanding of the governing physics behind the interaction of multiple fuel injections, ignition, and combustion behavior of multiple-injections in diesel engines. Multiple-injection is a widely adopted operating strategy applied in modern compression-ignition engines, which involves various combinations of small pre-injections and post-injections of fuel before and after the main injection and splitting the main injection into multiple smaller injections. This strategy has been conclusively shown to improve fuel economy in diesel engines while achieving simultaneous NOX, soot, and combustion noise reduction - in addition to a reduction in the emissions of unburned hydrocarbons (UHC) and CO by preventing fuel wetting and flame quenching at the piston wall.

Compliance with future ultra-low nitrogen oxide regulations with diesel engines requires the fastest possible heating of the exhaust aftertreatment system to its proper operating temperature upon cold starting. Late post injections are commonly integrated into catalyst-heating operating strategies. This experimental study provides insight into the complex interactions between the injection-strategy calibration and the tradeoffs between exhaust heat and pollutant emissions. Experiments are performed with certification diesel fuel and blends of diesel fuel with butylal and hexyl hexanoate. Further analyses of experimental data provide insight into fuel reactivity and oxygen content as potential enablers for improved catalyst-heating operation. A statistical design-of-experiments approach is developed to investigate a wide range of injection strategy calibrations at three different intake dilution levels.

The effect of an annular, piston bowl-rim cavity on in-cylinder and engine-out soot emissions is measured in a heavy-duty, optically accessible, single-cylinder diesel engine using in-cylinder soot diagnostics and exhaust smoke emission measurements. The baseline piston configuration consists of a right-cylindrical bowl, while the cavity-piston configuration features an additional annular cavity that is located below the piston bowl-rim and connected to the main-combustion chamber through a thin annular passage, accounting for a 3% increase in the clearance volume, resulting in a reduction in geometric compression ratio (CR) from 11.22 to 10.91. Experiments using the cavity-piston configuration showed a significant reduction of engine-out smoke ranging from 20-60% over a range of engine loads.

Low-temperature gasoline combustion engines can provide high efficiencies with very low NOx and particulate emissions, but rapid control of the combustion timing (50% burn point, CA50) remains a challenge. Partial Fuel Stratification (PFS) was recently demonstrated [2019-01-1156] to control CA50 over a wide range at some selected operating conditions using a regular-grade E10 gasoline. PFS was produced by a double direct injection (D-DI) strategy using a gasoline-type direct injector. For this D-DI-PFS strategy, the majority of the fuel is injected early in the intake stroke, establishing the minimum equivalence ratio in the charge, while the remainder of the fuel is supplied by a second injection at a variable time (SOI2) during the compression stroke to vary the amount of stratification. Adjusting the stratification changes the combustion timing, and this can be done on a cycle-to-cycle basis by adjusting SOI2.

Performance and emissions characteristics were measured for a part- load operating point using an optically-accessible single-cylinder gasoline research engine equipped with three different exploratory nanosecond repetitively pulse discharge (NRPD) igniters. The three igniters investigated are as follows: 1) a four-prong advanced corona ignition system (ACIS) that produces large ignition volumes from streamer discharges, 2) a barrier discharge igniter (BDI) that generates strong surface plasma along the insulator that completely encases the power electrode, and 3) a J-hook non-resistive nanosecond spark (NRNS) igniter. For select conditions, high-speed imaging (20 kHz) of excited state hydroxyl (OH*) chemiluminescence was performed to measure flame development in-cylinder. An available NRPD pulse generator was used to supply positive direct current (DC) pulses (~ 10 ns pulse width) to each igniter at a fixed 100 kHz frequency.

Understanding and prediction of flash-boiling spray behavior in gasoline direct-injection (GDI) engines remains a challenge. In this study, computational fluid dynamics (CFD) simulations using the homogeneous relaxation model (HRM) for not only internal nozzle flow but also external spray were evaluated using CONVERGE software and compared to experimental data. High-speed extinction imaging experiments were carried out in a real-size axial-hole transparent nozzle installed at the tip of machined GDI injector fueled with n-pentane under various ambient pressure conditions (Pa/Ps = 0.07 - 1.39). The width of the spray during injection was assessed by means of projected liquid volume, but the structure and timing for boil-off of liquid within the sac of the injector were also assessed after the end of injection, including cases with different designed sac volumes.

Combustion issued from an eight-hole, direct-injection spray was experimentally studied in a constant-volume pre-burn combustion vessel using simultaneous high-speed diffused back-illumination extinction imaging (DBIEI) and OH* chemiluminescence. DBIEI has been employed to observe the liquid-phase of the spray and to quantitatively investigate the soot formation and oxidation taking place during combustion. The fuel-air mixture was ignited with a plasma induced by a single-shot Nd:YAG laser, permitting precise control of the ignition location in space and time. OH* chemiluminescence was used to track the high-temperature ignition and flame. The study showed that increasing the delay between the end of injection and ignition drastically reduces soot formation without necessarily compromising combustion efficiency. For long delays between the end of injection and ignition (1.9 ms) soot formation was eliminated in the main downstream charge of the fuel spray.

ϕ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. However, regular gasoline is not very ϕ-sensitive at low-pressure conditions, meaning that intake boosting (typically Pin ≥ 1.3 bar) is required to take advantage of this property. Thus, there is strong motivation to design a gasoline-like fuel that simultaneously improves ϕ-sensitivity, RON and octane sensitivity, to make an improved fuel suitable for both LTGC and modern SI engines. In a previous study [SAE 2019-01-0961], a 5-component regulation-compliant fuel blend (CB#1) was computationally designed; and simulations showed promising results when it was compared to a regular E10 gasoline (RD5-87). The current study experimentally evaluates CB#1 in the Sandia LTGC engine and compares the results with those of RD5-87. The RON and octane sensitivity were improved 1.3 and 3.6 units by CB#1, respectively.