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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Post-Mortem Analysis of DAAAC and Conventionally Aged Aftertreatment Systems

2023-10-31
2023-01-1656
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.
Technical Paper

Development of a 5-Component Diesel Surrogate Chemical Kinetic Mechanism Coupled with a Semi-Detailed Soot Model with Application to Engine Combustion and Emissions Modeling

2023-08-28
2023-24-0030
In the present work, five surrogate components (n-Hexadecane, n-Tetradecane, Heptamethylnonane, Decalin, 1-Methylnaphthalene) are proposed to represent liquid phase of diesel fuel, and another different five surrogate components (n-Decane, n-Heptane, iso-Octane, MCH (methylcyclohexane), Toluene) are proposed to represent vapor phase of diesel fuel. For the vapor phase, a 5-component surrogate chemical kinetic mechanism has been developed and validated. In the mechanism, a recently updated H2/O2/CO/C1 detailed sub-mechanism is adopted for accurately predicting the laminar flame speeds over a wide range of operating conditions, also a recently updated C2-C3 detailed sub-mechanism is used due to its potential benefit on accurate flame propagation simulation. For each of the five diesel vapor surrogate components, a skeletal sub-mechanism, which determines the simulation of ignition delay times, is constructed for species C4-Cn.
Technical Paper

Verification of Driver Status Monitoring Camera Position Using Virtual Knowledge-Based Engineering

2023-04-11
2023-01-0090
A DMS (Driver Monitoring System) is one of the most important safety features that assist in the monitoring functions and alert drivers when distraction or drowsiness is detected. The system is based in a DSMC (Driver Status Monitoring Camera) mounted in the vehicle's dash, which has a predefined set of operational requirements that must be fulfilled to guarantee the correct operation of the system. These conditions represent a trade space analysis challenge for each vehicle since both the DSMC and the underlying vehicle’s requirements must be satisfied. Relying upon the camera’s manufacturer evaluation for every iteration of the vehicle’s design has proven to be time-consuming, resources-intensive, and ineffective from the decision-making standpoint.
Technical Paper

Synergizing Artificial Intelligence with Product Recall Management Process

2023-04-11
2023-01-0867
There are a multitude of dynamics faced by any industry. There is also a consistent search and development of technological platforms and services to address these changes. This necessitates a shared work philosophy which involves multiple stakeholders. Verification and validation are integral part of any development irrespective of product, process, or services. Also, every industry has a regulatory compliance to adhere too. But the extent of complexity and the level of dependencies or interactions between modules as well as stakeholders involved, creates slippage at some or other level. Nowadays the industries are also driven by reuse for cost effectiveness. Though it marks the significant improvement in the capability to compete, compatibility is a key measure to a successful product or service launch and sustainability.
Technical Paper

Evaluation of Indrio’s Ammonia Sensor using a Diesel Fuel Based Burner Platform

2023-04-11
2023-01-0383
This program involved the detailed evaluation of a novel laser-based in-exhaust ammonia sensor using a diesel fuel-based burner platform integrated with an ammonia injection system. Test matrix included both steady-state modes and transient operation of the burner platform. Steady-state performance evaluation included tests that examined impact of exhaust gas temperature, gas velocity and ammonia levels on sensor response. Furthermore, cross sensitivity of the sensor was examined at different levels of NOX and water vapor. Transient tests included simulation of the FTP test cycles at different ammonia and NOX levels. A Fourier transform infrared (FTIR) spectrometer as well as NIST traceable ammonia gas bottles (introduced into the exhaust stream via a calibrated flow controller) served as references for ammonia measurement.
Journal Article

Low Ambient Temperature Impact on a Low NOX Demonstration System

2023-04-11
2023-01-0361
In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.
Technical Paper

Generation of Reactive Chemical Species/Radicals through Pilot Fuel Injection in Negative Valve Overlap and Its Effects on Engine Performances

2022-08-30
2022-01-1002
This study investigated the potential of generating reactive chemical species (including radicals) through pilot fuel injection in negative valve overlap for improving the combustion and emissions performances of spark ignition gasoline engines under low load and low speed operating conditions. Several Ford sub-models were used for simulating the physics and chemistry processes of injecting a small amount of fuel in NVO (negative valve overlap). Effects of different NVO degrees and different pilot injection timings, factors for fuel conversion were simulated and investigated. CO and H2 conversions during NVO, CO and H2 amounts before spark timing were used for comparing different schemes.
Technical Paper

DAAAC Protocol for Durability Demonstration of Diesel Aftertreatment Systems: Emissions Performance Validation

2022-08-30
2022-01-1015
Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.
Technical Paper

An Optimization Model for Die Sets Allocation to Minimize Supply Chain Cost

2022-07-08
2022-01-5057
In this paper, a novel mixed-integer programming model is developed to optimally assign the die sets to candidate plants to minimize the total costs. The total costs include freight shipping stamped parts to assembly plants, die set movement, outsourcing, and utilization. Therefore, the objective function is weighted multi-criteria and it takes into consideration some of the key constraints in the real-world condition including “must-move die sets”. An optimization tool has been developed that takes several inputs and feeds them as the input to the mathematical model and generates the optimal assignments with the directional costs as the output. The tool has been tested for several plants at Ford and has proved its robustness by saving millions of dollars. The developed tool can easily be applied to other manufacturing systems and original equipment manufacturers (OEMs).
Journal Article

Development of Steady State NO2:NOX Control via an Independent Nitric Decomposition System for the Exhaust Composition Transient Operation Laboratory

2022-03-29
2022-01-0548
Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.
Journal Article

Laser-Based In-Exhaust Gas Sensor for On-Road Vehicles

2022-03-29
2022-01-0535
A novel laser-absorption gas sensing apparaOn-vehicle Testing at VERtus capable of measuring NO directly within vehicle exhaust was developed and tested. The sensor design was enabled by key advances in the construction of optical probes that are sufficiently compact for deployment in real-world exhaust systems and can survive the harsh, high-temperature, and strongly vibrating environment typical of exhaust streams. Prototype test campaigns were conducted at high-temperature flow facilities intended to simulate exhaust gas conditions and within the exhaust of vehicles mounted on a chassis dynamometer. Results from these tests demonstrated that the sensor prototype is fundamentally free of cross-interference with competing species in the exhaust stream, can achieve a 1 ppmv NO detection limit, and can be operated across the full range of thermodynamic conditions expected for typical vehicle exhausts.
Technical Paper

Application of Data Analytics to Decouple Historical Real-World Trip Trajectories into Representative Maneuvers for Driving Characterization

2021-04-06
2021-01-0169
Historical driver behavior and drive style are crucial inputs in addition to V2X connectivity data to predict future events as well as fuel consumption of the vehicle on a trip. A trip is a combination of different maneuvers a driver executes to navigate a route and interact with his/her environment including traffic, geography, topography, and weather. This study leverages big data analytics on real-world customer driving data to develop analytical modeling methodologies and algorithms to extract maneuver-based driving characteristics and generate a corresponding maneuver distribution. The distributions are further segmented by additional categories such as customer group and type of vehicle. These maneuver distributions are used to build an aggressivity distribution database which will serve as the parameter basis for further analysis with traffic simulation models.
Journal Article

Graphene Coating as a Corrosion Protection Barrier for Metallic Terminals in Automotive Environments

2021-04-06
2021-01-0354
Inside an automobile, hundreds of connectors and electrical terminals in various locations experience different corrosive environments. These connectors and electrical terminals need to be corrosion-proof and provide a good electrical contact for a vehicle’s lifetime. Saltwater and sulfuric acid are some of the main corrosion concerns for these electrical terminals. Currently, various thin metallic layers such as gold (Au), silver (Ag), or tin (Sn) are plated with a nickel (Ni) layer on copper alloy (Cu) terminals to ensure reliable electrical conduction during service. Graphene due to its excellent chemical stability can serve as a corrosion protective layer and prevent electrochemical oxidation of metallic terminals. In this work, effects of thin graphene layers grown by plasma-enhanced chemical vapor deposition (PECVD) on Au and Ag terminals and thin-film devices were investigated. Various mechanical, thermal/humidity, and electrical tests were performed.
Journal Article

Quantitative Analysis of Gasoline Direct Injection Engine Emissions for the First 5 Firing Cycles of Cold Start

2021-04-06
2021-01-0536
A series of cold start experiments using a 2.0 liter gasoline turbocharged direct injection (GTDI) engine with custom controls and calibration were carried out using gasoline and iso-pentane fuels, to obtain the cold start emissions profiles for the first 5 firing cycles at an ambient temperature of 22°C. The exhaust gases, both emitted during the cold start firing and emitted during the cranking process right after the firing, were captured, and unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start were analyzed and quantified. The HCs emitted during gasoline-fueled cold starts was found to reduce significantly as the engine cycle increased, while CO and CO2 emissions were found to stay consistent for each cycle. Crankcase ventilation into the intake manifold through the positive-crankcase ventilation (PCV) valve system was found to have little effect on the emissions results.
Technical Paper

Comparison of Partial and Total Dilution Systems for the Measurement of Polycyclic Aromatic Hydrocarbons and Hydrocarbon Speciation in Diesel Exhaust

2020-09-15
2020-01-2190
Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.
Technical Paper

How Well Can mPEMS Measure Gas Phase Motor Vehicle Exhaust Emissions?

2020-04-14
2020-01-0369
“Real world emissions” is an emerging area of focus in motor vehicle related air quality. These emissions are commonly recorded using portable emissions measurement systems (PEMS) designed for regulatory application, which are large, complex and costly. Miniature PEMS (mPEMS) is a developing technology that can significantly simplify on-board emissions measurement and potentially promote widespread use. Whereas full PEMS use analyzers to record NOx, CO, and HCs similar to those in emissions laboratories, mPEMS tend to use electrochemical sensors and compact optical detectors for their small size and low cost. The present work provides a comprehensive evaluation of this approach. It compares measurements of NOx, CO, CO2 and HC emissions from five commercial mPEMS to both laboratory and full regulatory PEMS analyzers. It further examines the use of vehicle on-board diagnostics data to calculate exhaust flow, as an alternative to on-vehicle exhaust flow measurement.
Technical Paper

Investigation of Mechanical Behavior of Chopped Carbon Fiber Reinforced Sheet Molding Compound (SMC) Composites

2020-04-14
2020-01-1307
As an alternative lightweight material, chopped carbon fiber reinforced Sheet Molding Compound (SMC) composites, formed by compression molding, provide a new material for automotive applications. In the present study, the monotonic and fatigue behavior of chopped carbon fiber reinforced SMC is investigated. Tensile tests were conducted on coupons with three different gauge length, and size effect was observed on the fracture strength. Since the fiber bundle is randomly distributed in the SMC plaques, a digital image correlation (DIC) system was used to obtain the local modulus distribution along the gauge section for each coupon. It was found that there is a relationship between the local modulus distribution and the final fracture location under tensile loading. The fatigue behavior under tension-tension (R=0.1) and tension-compression (R=-1) has also been evaluated.
Journal Article

A Novel Technique for Measuring Cycle-Resolved Cold Start Emissions Applied to a Gasoline Turbocharged Direct Injection Engine

2020-04-14
2020-01-0312
There is keen interest in understanding the origins of engine-out unburned hydrocarbons emitted during SI engine cold start. This is especially true for the first few firing cycles, which can contribute disproportionately to the total emissions measured over standard drive cycles such as the US Federal Test Procedure (FTP). This study reports on the development of a novel methodology for capturing and quantifying unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start. The method was demonstrated by applying it to a 4 cylinder 2 liter GTDI (Gasoline Turbocharged Direct Injection) engine for cold start conditions at an ambient temperature of 22°C. For this technique, the entirety of the engine exhaust gas was captured for a predetermined number of firing cycles.
Technical Paper

Semi-Volatile Organic Compounds from a Combined Dual Port Injection/Direct-Injection Technology Light-Duty Gasoline Vehicle

2019-09-09
2019-24-0051
Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.
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