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Recent growth in automotive applications of magnesium die cast alloys has made the refining and recycling of magnesium scrap a key issue for the automotive and magnesium industries, if growth is to continue. Today, with only a few exceptions, commercially refined and recycled alloy is produced using a variety of flux-based processes. However, fluxless refining, has been the focus of growing interest, particularly for the in-house refining of scrap by the die cast producers. This paper summarizes the results of a study conducted to better understand the behavior of non-metallic contaminants in scrap melts and the requirements for their separation, using argon sparging. Brightness measurements were used to experimentally determine the distribution of non-metallic contaminants within scrap melts both before and after argon treatment.

Continued development of Reinforced Reaction Injection Molding (RRIM) polyurea polymers for toughness, blister resistance and large-part processing as exterior vertical body panels has launched ELPO-compatible exterior outers into automotive assembly-line operations. This allows automotive OEM design to take advantage of the unique molding shapes for side outers and fenders while reducing weight, assembly (DFA) and time/operations costs (DFM). Polyurea RRIM body panels have been successful in meeting the demanding auto industry requirement for lightweight, damage-resistant exterior outer panels as an economical alternative to steel. Design freedom advantages, low prototype cost and tooling savings through predictive modelling have allowed the commercial use of RRIM body panels. This high-temperature-resistant polyurea RRIM composite allows on-line painting, including passing through the steel corrosion protection primer (E-coat) cure environments.

The opportunity for composites in engine closure systems such as valve covers, oil pans, and timing belt covers is expanding rapidly. The primary driving forces are lighter weight finished components, integrated designs, improved isolation of engine noise, improved materials systems, and matured manufacturing processes for composite materials. Thermoset-based composite materials, particularly those based on high-temperature resistant epoxy vinyl ester matrices, offer improved performance with respect to thermoplastic and thermoset polyester-based composites and can be manufactured using different processing methods. This paper presents the current state-of-the-art design, engineering and optimization techniques for engine closure systems. The performance requirements of different systems such as valve covers and oil pans are explained in detail. Techniques for long-term structural stiffness evaluation, vibration performance assessment and noise transmission estimation are described.

The use of low density reinforced Reaction Injection Molded (RIM) substrates for covered interior automotive articles continues to increase globally. Reduced party mass, consolidation of manufacturing steps (labor), and the use of aluminum tooling, instead of steel, are cited advantages that LD-RIM offers when compared to traditional wood based and thermoplastic materials. Two RIM processes are successfully being used to produce covered interior door panels. Low density structural RIM (LD-SRIM), utilizing conventional RIM equipment, involves the placement of a pre-cut fiberglass mat in the tool cavity prior to open-pour injection of the 2-stream liquid urethane components. Low density reinforced RIM (LD-RRIM), utilizing lance cylinder RIM equipment, incorporates reinforcing fibers, such as milled fiberglass or wollastonite, in the liquid resin component. The liquid resin containing reinforcing filler is injected with the isocyanate component into a closed mold.

The persistent occurrence of microporosity defects in AZ91 castings has made it difficult to consistently produce sound parts. Earlier work established that dissolved hydrogen gas causes microporosity defects in AZ91; however, the exact role of hydrogen in the nucleation and growth of microporosity was not determined. In this paper, the behavoir of dissolved hydrogen gas in elemental magnesium, AZ91 alloy, and liquid binary Mg/Al alloys was studied. The results show that during the last stages of solidification, hydrogen gas is rejected from the Mg17Al12 intermetallic compound to assist in the nucleation and/or growth of microporosity.

The objective of this paper will be to review a novel recycle process involving Structural Reaction Injection Molding(SRIM) which enables a variety of coarsely ground plastic recycle materials to be incorporated into the molded part. What makes this approach novel, is that flexural modulus of the fabricated parts are actually increased when the recycled granulate is employed in the part. This paper will present data for the recycle of a variety of automotive parts, including painted fascia, door skins, covered interior door panels, armrests and instrument panels along with composite bumper beams into the SRIM recycle core process. Resulting part economics will be reviewed along with potential applications to utilize this technology.

The relationship between hydrogen gas and microporosity in magnesium alloy AZ91 was quantified, refuting the belief that hydrogen levels less than the maximum solid solubility are of no detriment. Sand castings were made from melts containing measured levels of hydrogen gas, and the amount of porosity was determined by density measurements. At concentrations below the maximum solid solubility, it was established that the amount of microporosity is directly proportional to the gas content. This supports the premise that dissolved hydrogen gas provides nucleation sites for microporosity, and that it is useful to remove all gas to achieve porosity-free cast parts.

Adhesive materials are required to bond cover fabrics to most molded interior headliner substrates. Several thermoplastic adhesive films are qualified and used at U.S. and Japanese OEM's. These adhesive films offer benefits such as convenience, cost effectiveness, excellent adhesive performance and process efficiency while reducing concerns of emissions and hazardous waste handling compared to prior bonding methods. The automotive headliner part is a multifunctional component of the vehicle's interior trim. One of the main headliner functions is to reduce the interior cabin noise. Various adhesive materials are used in a lamination process to form a composite headliner. The purpose of this study was to compare the effects of this lamination process and various alternative adhesive materials on the overall acoustical performance of the headliner composite. Various headliner samples were fabricated under controlled process conditions and tested by an independent acoustics testing lab.

A method for refining magnesium scrap which produces consistent, high quality magnesium metal has been developed. High quality magnesium metal is defined in this paper as metal which has heavy metal contaminants controlled within high-purity ASTM chemical specification, and is relatively free of internal impurities such as non-metallic inclusions (oxides and flux) and dissolved gas. The refining process utilizes a protective gas atmosphere, inert gas sparging and filtration techniques, rather than salt based fluxes, to remove both non-metallic inclusions and dissolved gases. Experimentation results of this refining process indicate magnesium scrap can be remelted and refined to a quality equal to or better than virgin ingot, without the introduction of salt based fluxes or a large capital investment.

The construction of most automotive interior headliners requires an adhesive material to bond polyurethane foam-backed fabric to a molded headliner shell. More than ten years ago, The Dow Chemical Company qualified and began supplying a thermoplastic adhesive polymer film for headliner applications which replaced wet adhesive systems at several fabricators. DAF 899 adhesive film has gained acceptance in the industry due to excellent performance, convenience, and cost effectiveness without additional waste handling or volatile organic emission concerns. Recent advancements in headliner design such as additional recessed areas with more demanding contours, new substrate materials and the desire for more efficient operations created an opportunity to design improved adhesive films to meet the emerging industry demands.

A new family of high heat stable, few gloss ABS resins has been developed specifically to offer the automotive industry improved performance in molded interior trim parts. The new resins offer excellent fabrication and property performance similar to that of standard-heat low gloss ABS resins. Advantages over current high heat ABS resins include improved injection moldability, greater resistance to heat warping and to U.V. degradation, improved color stability, improved toughness, and consequent good finished part economics while maintaining equivalent heat resistance. Physical property and testing-evaluation data are provided.

Gas generators for filling auto air cushions have been developed in several compact sizes and configurations. All-solid chemical-generating compositions have been developed to give nearly pure nitrogen gas. Other compositions developed give mainly carbon dioxide. Gas cushions ranging in size from 1-12 ft3 have been inflated. Deployment time, bag temperature, and sound level are within safe limits. Toxicity tests have been performed on dogs without harmful effects being observed.