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Motorcycle OEMs faced with stringent global fuel economy and emission regulations are being forced to develop new hardware and emissions control technologies to remain compliant. Motorcycle oils have become an enabling technology for the development of smaller, more efficient engines operating at higher power density. Many OEMs have therefore become reliant on lubricants to not only provide enhanced durability under more extreme operating conditions, but to also provide fuel economy benefits through reduced energy losses. Unlike passenger car oils that only lubricate the engine, motorcycle oils must lubricate both the engine and the drive train. These additional requirements place different performance demands versus a crankcase lubricant. The drive train includes highly loaded gears that are exposed to high pressures, in turn requiring higher levels of oil film strength and antiwear system durability.

Downsized gasoline engines, coupled with gasoline direct injection (GDI) and turbocharging, have provided an effective means to meet both emissions standards and customers’ drivability expectations. As a result, these engines have become more and more common in the passenger vehicle marketplace over the past 10 years. To maximize fuel economy, these engines are commonly calibrated to operate at low speeds and high engine loads – well into the traditional ‘knock-limited’ region. Advanced engine controls and GDI have effectively suppressed knock and allowed the engines to operate in this high efficiency region more often than was historically possible. Unfortunately, many of these downsized, boosted engines have experienced a different type of uncontrolled combustion. This combustion occurs when the engine is operating under high load and low speed conditions and has been named Low Speed Pre-Ignition (LSPI). LSPI has shown to be very damaging to engine hardware.

Phosphorus is known to reduce effectiveness of the three-way catalysts (TWC) commonly used by automotive OEMs. This phenomenon is referred to as catalyst deactivation. The process occurs as zinc dialkyldithiophosphate (ZDDP) decomposes in an engine creating many phosphorus species, which eventually interact with the active sites of exhaust catalysts. This phosphorous comes from both oil consumption and volatilization. Novel low-volatility ZDDP is designed in such a way that the amounts of volatile phosphorus species are significantly reduced while their antiwear and antioxidant performances are maintained. A recent field trial conducted in New York City taxi cabs provided two sets of “aged” catalysts that had been exposed to GF-4-type formulations. The trial compared fluids formulated with conventional and low-volatility ZDDPs. Results of field test examination were reported in an earlier paper (1).

SAE 2004-01-3009 reported on work conducted to investigate the correlation between the Mack T-11 laboratory engine tests and vehicle field tests. It concluded that the T-11 test provides an effective screening tool to investigate soot-related viscosity increase, and the severity of the engine test limits provides a substantial margin of safety compared to the field. This follow-up paper continues the studies on the 2003 Mack CV713 granite dump truck equipped with an AI-427 internal EGR engine and introduces experimentation on a 2003 CX613 tractor unit equipped with an AC-460P cooled EGR engine. The paper further assesses the correlation of the field trials to the Mack T-11 engine test and reviews the impact of ultra low sulfur diesel (ULSD) and prototype CJ-4 lubricant formulations in these engines.

With the continued growth of the sport utility vehicle (SUV) market in North America in recent years more emphasis has been placed on fluid performance in these vehicles. In addition to fuel economy the key performance area sought by original equipment manufacturers (OEMs) in general has been temperature reduction in the axle. This is being driven by warranty claims that show that one of the causes of axle failure in these type vehicles is related to overheating. The overheating is, in turn, caused by high load situations, e.g., pulling a large trailer at or near the maximum rated load limit for the vehicle, especially when the vehicle or its main subcomponents are relatively new. The excessive temperature generally leads to premature failure of seals, bearings and gears. The choice of lubricant can have a significant effect on the peak and stabilized operating temperature under these extreme conditions.

A new generation of fluid technology using novel diesel fuel detergent/dispersant chemistry provides a multitude of beneficial effects to the diesel engine, especially the latest model designs. In addition to improved injector, valve and combustion chamber deposit removal, the additive restores power, fuel economy, performance and emission levels1. Positive observations have also been documented along with improved performance concerning crankcase lube viscosity, soot loading and TBN retention. An even greater added benefit is the inherent capability of the fuel additive to deal with several EGR issues now prominent with the introduction of new engines. Recent research, reported herein, has uncovered the extensive efficacy of this chemistry for piston durability and neutralization of ring corrosion phenomena. All of the beneficial additive attributes are further enhanced with increased oxidative and thermal fuel stability and no loss of filterability.

The tightening legislation in the on-road heavy-duty diesel area means that pollution control systems will soon be widely introduced on such engines. A number of different aftertreatment systems are currently being considered to meet the incoming legislation, including Diesel Particulate Filters (DPF), Diesel Oxidation Catalysts (DOC) and Selective Catalytic Reduction (SCR) systems. Relatively little is known about the interactions between lubricant-derived species and such aftertreatment systems. This paper describes the results of an experimental program carried out to investigate these interactions within DPF, DOC and SCR systems on a state-of-the-art 9 litre engine. The influence of lubricant composition and lube oil ash level was investigated on the different catalyst systems. In order to reduce costs and to speed up testing, test oil was dosed into the fuel. Tests without dosing lubricant into the fuel were also run.

Throughout the evolution of the automobile, passenger car motor oils have been developed to address issues of wear, corrosion, deposit formation, friction, and viscosity stability. As a result, the internal combustion engines are now developed with the expectation that the lubricants to be used in them will deliver certain performance attributes. Metallurgies, clearances, and built-in stresses are all chosen with certain expectations from the lubricant. A family of chemicals that has been universally used in formulating passenger car motor oils is zinc dithiophosphates (ZDPs). ZDPs are extremely effective at protecting highly stressed valve train components against wear failure, especially in engine designs with a sliding contact between cams and followers. While ZDPs' benefits on wear control are universally accepted, ZDPs have been identified as the source of phosphorus, which deactivates noble metal aftertreatment systems.

Experiments have been conducted in a laminar flow system and in a research engine to investigate the effect of additives on the combustion of gasoline-like fuels. The purpose of the laminar system is to enable rapid screening of additives to determine which, if any, have an enhancing effect on the early stages of combustion, especially under conditions of poor fuel vaporization which exist during cold-start in a spark ignited engine and which make flame propagation difficult to start and sustain. The base fuel used in the laminar and engine systems was a 9 component mixture formulated to simulate those components of gasoline expected to be present in the vapor phase in the intake system of an engine under cold-start conditions. In the laminar system, the pre-mixed, pre-vaporized fuel-air mixture is ignited and a time history of the combustion generated, hydroxyl radical chemiluminescence is recorded.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

The next generation of engine oil under development has been formulated to maintain beneficial oil lubrication properties at increased engine operating temperatures, increased drain-oil intervals, and with the recirculation of exhaust gas back through the engine (EGR). These conditions result in the formation of degradation products from decomposed fuel, additives, and base oil. Decomposition products containing reactive sulfur can result in the corrosion of copper alloys. Sulfur-containing compounds currently used in these formulations can include zinc dithiophosphates (ZDP), molydithiophosphates, molydithiocarbamates, and molybdic acid/amine complexes, along with sulfur containing detergents and antioxidants. Interactions among these components and others in the formulation often determine the propensity of these formulations for corrosion. This paper will discuss the results of corrosion bench tests used to screen oil formulations for copper corrosion.

A new gas phase kinetic model using Westbrook's gas phase n-heptane model and Frenklach's soot model was constructed. This model was then used to predict the impact on PAH formation as an indices of soot formation on ethanol/diesel fuel blends. The results were then compared to soot levels measured by various researchers. The ignition delay characteristics of ethanol were validated against experimental results in the literature. In this paper the results of the model and the comparison with experimental results will be discussed along with implications on the method of incorporation of additives and alternative fuels.

This paper features the results of emission tests conducted on diesel oxidation catalysts, and the combination of diesel oxidation catalysts and water blend fuel (diesel fuel continuous emulsion). Vehicle chassis emission tests were conducted using an urban bus. The paper reviews the impact and potential benefits of combining catalyst and water blend diesel fuel technologies to reduce exhaust emissions from diesel engines.

The Nissan KA24E engine test is designated to replace the Ford Sequence VE engine test as the low temperature valve train wear requirement for ILSAC (International Lubricant Standardization and Approval Committee) GF-3. The KA24E (recently designated the Sequence IV A) represents much of the current world-wide material and design technology while retaining the sliding cam/follower contact found in earlier engine designs. The work presented here is the first of two reports. In this first report, the physical and chemical environment the KA24E engine presents a lubricant is characterized and compared to those of the Sequence VE engine. Valve train materials and wear modes are investigated and described. Although chemical analysis of drain oils indicate the KA24E procedure does not degrade the lubricant to the extent seen in the Sequence VE test, valve train wear appears to proceed in a similar manner in both tests.

The work presented here is the second of two papers investigating the KA24E engine test. The first paper characterized the KA24E engine in terms of the physical and chemical operating environment it presents to lubricants. The authors investigated oil degradation and wear mechanisms, and examined the differences between the KA24E and the Sequence VE engine tests. It was shown that while the KA24E does not degrade the lubricant to the extent that occurs in the Sequence VE, wear could be a serious problem if oils are poorly formulated. This second paper examines the wear response of the KA24E to formulation variables. A statistically designed matrix demonstrated that the KA24E is sensitive to levels of secondary zinc dialkyldithiophosphate (ZDP), dispersant and calcium sulfonate detergent. This matrix also showed that the KA24E appears to have good repeatability for well formulated oils and is a reasonable replacement for the wear component of the Sequence VE.

A measurable incidence of driver complaints about vehicle driveability has occurred in certain imported passenger cars. Critical engines are higher specific output, lean burn designs that are sensitive to deposits formed on intake valves. U.S. engines are trending toward similar” designs but have not yet been tuned as close to the lean limit of combustion. It is reasoned that the continuing trend toward more precise management of air fuel ratio results in engines much less tolerant of deposits throughout the fuel metering and induction system. Consequently, more effective additive systems to control induction system deposits have been developed. Discussed in this paper are the interrelationships of fuel composition and engine configurations. Results of these continuing studies are helping to define the more important fuel and additive parameters for deposit control in various engines.

Multifunctional or universal lubricating oils which service both gasoline and diesel engines have gained widespread commercial acceptance. Since 1970, numerous changes and additions have altered the performance tests and specifications which define the quality of these lubricants. New parameters include single cylinder and multicylinder diesel engine testing, valve train wear protection, clutch plate friction retention, extended drain interval and lubricant related fuel economy. In response to these requirements, new additive systems were developed. This paper discusses observed base oil-additive-engine test interactions and compares the performance of one of these additive systems to that of the old.