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The cold start process is critical to control the emissions in a gasoline direct injection (GDI) engine. However, the optimization is very challenging due to the transient behavior of the engine cold start. A series of engine simulations using CONVERGE CFD™ were carried out to show the detailed process in the very first firing event of a cold start. The engine operating parameters used in the simulations, such as the transient engine speed and the fuel rail pressure (FRP), came from companion experiments. The cylinder pressure traces from the simulations were compared with experiments to help validate the simulation model. The effects of variation of the transient parameters on in-cylinder mixture distribution and combustion are presented, including the effects of the rapidly changing engine speed, the slowly vaporized fuel due to the cold walls, and the low FRP during the first firing cycle of a 4-cylinder engine. Comparison was also made with non-transient steady state operation.