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Technical Paper

Development of Three-Way Catalysts Enhanced NOx Purifying Activity

2018-04-03
2018-01-0942
Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).
Technical Paper

Analysis of Friction Coefficient Variation with Moisture between Friction Surfaces

2016-04-05
2016-01-0411
If a vehicle is left in a humid environment, the coefficient of friction between the brake pads and discs increases, generating a discomforting noise during braking called brake squeal. It is assumed that this increase in the coefficient of friction in a humid environment is the effect of moisture penetrating between the brake friction surfaces. Therefore, this paper analyzes the factors causing coefficient of friction variation with moisture between the friction surfaces by dynamic observation of these surfaces. The observation was achieved by changing the disc materials from cast iron to borosilicate glass. One side of the glass brake disc was pushed onto the brake pad and the sliding surface was observed from the opposite side by a charge coupled device (CCD) camera. First, a preliminary test was carried out in a dry state using two pad materials with different wear properties to select the appropriate pad for observing the friction surfaces.
Technical Paper

Development of Advanced Three-Way Catalyst with Improved NOx Conversion

2015-04-14
2015-01-1005
Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.
Technical Paper

Stereo Vision System for Advanced Vehicle Safety System

2007-04-16
2007-01-0405
In this paper, we will introduce a stereo vision system developed as a sensor for a vehicle's front monitor. This system consists of three parts; namely, a stereo camera that collects video images of the forward view of the vehicle, a stereo ECU that processes its output image, and a near-infrared floodlight for illuminating the front at night. We were able to develop an obstacle detection function for the Pre-Crash Safety System and also a traffic lane detection function for a Lane-Keeping Assist System. Especially in regard to the obstacle detection function, we were able to achieve real-time processing of the disparity image calculations that had formerly required long processing times by using two types of recently developed LSIs.
Technical Paper

Low Friction Property and its Mechanism of DLC-Si Films Under Dry Sliding Conditions

2007-04-16
2007-01-1015
Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.
Technical Paper

Improvement of NOx Storage-Reduction Catalyst

2007-04-16
2007-01-1056
In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.
Technical Paper

Development of High Performance Three-Way-Catalyst

2006-04-03
2006-01-1061
In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.
Technical Paper

NOx Reduction Behavior on Catalysts With Non-Thermal Plasma in Simulated Oxidizing Exhaust Gas

2004-06-08
2004-01-1833
NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.
Technical Paper

A New Method of Engine Sound Design for Car Interior Noise Using a Psychoacoustic Index

2004-03-08
2004-01-0406
In this study, a new practical design method (tool) for engine sound quality in a car interior is proposed. The tool can automatically create the target interior sound using the psychoacoustic index ‘powerfulness’ based on subjective tests. Moreover, it can calculate the intake noise characteristic to create the target interior sound and select the suitable intake specification from the prepared database. By using this method sound engineering can be easily and effectively carried out without manufacturing an experimental car.
Technical Paper

Improvement of Heat Resistance for Bioplastics

2003-03-03
2003-01-1124
We studied the adoption of plastics derived from plants (bioplastics) such as poly(lactic acid) (PLA) for automotive parts in order to contribute to suppressing the increase in CO, emissions. For this application. major improvements of heat and impact resistance are needed. As a method to improve heat resistance, we developed PLA combined with clay of high heat resistance. As a result. we succeeded in synthesizing a PLA-clay nanocomposite using 18(OH)2-Mont. In-mold crystallization of PLA-clay nanocomposite lead to the great suppression of storage modulus decrease at high temperature. which in turn improved the heat resistance of PLA.
Technical Paper

An Intelligent Catalyst

2001-03-05
2001-01-1301
The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.
Technical Paper

Fretting Fatigue Analysis in Rapidly Solidified Powder Aluminum Alloy

1998-02-23
980698
Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.
Technical Paper

Multifunctional Surface Treatment for Car Air Conditioners

1998-02-23
980284
In order to improve corrosion resistance and thermal efficiency of the air conditioner evaporator, a coating which provides hydrophilicity was formed over the chromate coating. In addition, there has been greater demand for air with fewer smells. This report describes the cause of “dusty odor” and a method to reduce it. The dusty odor is caused by a little corrosion of the substrate aluminum. Hydrophilic coating film dissolves little by little in condensed water, and substrate aluminum is exposed. A method to prevent the odor was developed by forming a coating giving hydrophilicity and durability to the evaporator surface.
Technical Paper

Development of an On-Board Type Oil Deterioration Sensor

1993-10-01
932840
According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.
Technical Paper

The Development Tool for the Real-Time Fuzzy Control System on a Vehicle

1992-09-01
922128
Recently, there has been many practical applications of fuzzy control. Applications of fuzzy control to vehicles are more effective. However, they require more input and output channels as well as higher speed inference ability than typical applications require. We have developed a tool for developing a fuzzy control system available on a vehicle. The tool consists of a fuzzy inference board and a laptop personal computer with a color display executing a user interface software. The fuzzy inference board can be directly connected with an electronic control unit for vehicle control, and has 10 input channels, 5 output channels and 256 rules. The user interface software mainly provides two functions: 1) The screen editor for membership functions and rules. 2) The real-time monitor for input, output, and grade values when fuzzy inference is executed.
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