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An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.

Vehicles have been more required to save energy against the background of the tendency of ecology. As the result of improving efficiency of internal combustion engines and adoption of electric power train, heat loss from engine coolant, which is used to heat the cabin, decreases and consequently additional energy may be consumed to maintain thermal comfort in the passenger compartment in winter. This paper is concerned with the humidity control system that realizes reduction of ventilation heat loss by controlling recirculation rate of the HVAC system by using highly accurate humidity sensor to evaluate risk of fogging on the windshield. As the results of the control, fuel consumption of hybrid vehicles decreases and maximum range of electric vehicles increases.

The potential of high efficiency zero-emission engines fueled by hydrogen, which is regarded as a promising form of energy for the future, is being researched. The argon circulated hydrogen engine [ 1 ] is one system theoretically capable of achieving both high efficiency and zero emissions, and its feasibility for use in vehicles has been studied. Specifically, tests were performed to verify the following issues. It was examined whether stable hydrogen combustion could be achieved under an atmosphere of argon and oxygen, which has a high specific heat ratio, and whether the substantial thermal efficiency improvement effect of the argon working gas could be achieved. An argon circulation system was also studied whereby steam, which is the combustion product of the hydrogen and oxygen emitted from the engine, is separated by condensation to enable the remaining argon to be re-used.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

Two effects of rich-spike duration on NOx-storing have been analyzed. The first one, that NOx-storing speed decreases as rich-spike duration increases, is explained as the influence of NOx diffusion in wash-coat layer, which is quantified by a simple mathematical expression for NOx-storing rate. The second one, a peculiar behavior of NOx-storing in appearance of the outlet NOx concentration, is clarified: Heat produced directly or indirectly (via oxygen storage in ceria) by rich-spike warms up the downstream part, which releases excess NOx at the raised temperature. Contributions of the oxygen storage and the carbonate of NOx-storage material are also discussed.

In October 1998, a new mass-produced car with titanium engine-valves was released from TOYOTA Motor Corporation. Both intake and exhaust valves were manufactured via a newly developed cost-effective P/M forging process. Furthermore, the material which was specially designed for the exhaust one is a unique titanium metal matrix composite (MMC). This paper discusses the materials and manufacturing methods used. The tensile, fatigue strength and creep resistance of the MMC are always superior to those for the typical heat-resistant steel of 21-4N. Both valves have achieved sufficient durability and reliability with a manufacturing cost acceptable for mass-produced automobile parts.

Recently, there has been a tendency of high power and high speed in automotive engines. In addition they have been also required high reliability. And engine bearings have been required to be advanced in wear resistance as well as seizure resistance. Therefore, copper-lead alloy bearings with overlay, which have better seizure resistance, have been widely used for high speed engines up to the present. But it becomes very important for them to advance the overlay wear resistance. In this paper, the composite overlay is mainly researched to improve wear resistance regarding kind of hard particles and their amounts in the overlay.

A new 3-way catalyst with NOx conversion performance for lean-burn engines has been developed. The catalyst oxidizes NOx and stores the resulting nitrate, which is then reduced by HC and CO during engine operation around the stoichiometric air/fuel ratio. Both the composition of the storage component and the particle sizes of the noble metal were optimized. In addition, a special air fuel mixture control has been developed to make the best of the NOx storage-reduction function. The present catalyst showed 90% conversion efficiency and improved fuel economy by 4% in the Japanese 10-15 mode test cycle. The efficiency remained at 60% or more after durability test.

This paper describes lubricant technology which helps to prevent intake valve deposit (IVD) formation for use with conventional gasolines without detergents, as well as the IVD evaluation method used in testing. The FED 3462 method was modified to establish a new panel coking test method, with excellent correlation with the engine stand IVD test, for the quantitative evaluation of IVD. Tests have shown that IVD increases when the volatility of base oils becomes higher due to condensation and polymerization of engine oil additives. Furthermore, viscosity index improvers, metallic detergents and ashless dispersants have considerable effect on IVD formation. Based on various experiments, the authors have established a formulation technology for engine oils to lower IVD, which they incorporated in two newly formulated SG oils with lower IVD than conventional 5W-30 SG oil.

In Toyota, a robot off-line programming system was developed five years ago for the use at spot welding processes. And it has been effective to reduce and level off the engineering time. This time we have developed the new robot simulation system. It has three newly features so that the system becomes capable of simulating and programming robots from various manufacturers with different functions. As a result, the new system can be applied to a variety of processes in automobile manufacturing. First, a universal robot programming language was developed which includes a variety of commands such as definitions of motion attributes, signals of inputs/outputs, control of program flow, special functions proper to each process, and so on. And the language can be translated to and from any particular programming language using pre / post processor, so the simulation system needs to deal with only one language.

ϵ-caprolactam was polymerized in the interlayer space of montmorillonite, the clay mineral yielding a nylon-clay hybrid (NCH). X-ray and TEM measurements revealed that each template of the silicate, which was 1 nm thick, was dispersed in the nylon 6 matrix, and that the interlayer distance of clay increased continuously from 1.2 nm for the unintercalated material to 21.4 nm for the intercalated material. Thus, NCH is a polymer-based molecular composite or a nano-composite. NCH contains 1-15 vol% of monolayer clay. Injection-molded NCH showed excellent mechanical properties compared with nylon 6 in terms of tensile strength, tensile modulus and heat resistance. The tensile modulus of NCH was twice that of Nylon 6, and the heat distortion temperature increased from 65°C for nylon 6 to 145°C for the NCH containing only 1.6 vol% of a clay mineral. It was found that such excellent properties of an NCH system was due to the strong ionic interaction between nylon 6 and the silicate layer.