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This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

It may be possible to simplify the structure and control systems of a lithium-ion battery by replacing the conventional liquid electrolyte with a solid electrolyte, resulting in higher energy density. However, power performance is a development issue of batteries using a solid electrolyte. To increase battery power performance, in addition to lithium ionic conductivity within the bulk of the electrolyte, it is also necessary to boost the lithium ionic conductivity at the interface between the electrode active material and the electrolyte, and to boost electron and lithium ionic conductivity within the cathode and anode active material. This research studied the mechanism of resistance reduction by electrode surface modification. Subsequently, this research attempted to improve electron conductivity by simultaneously introducing oxygen vacancies and carrying out nitrogen substitution in the crystalline structure of the Li4Ti5O12 anode active material.

A full vehicle multi-body dynamic (MBD) model with suspension control system is developed for fatigue life prediction under rough road condition. The model consists of tires, a trimmed body, heavy attached parts, powertrain, suspension, joints, and a driver model, and includes a suspension control system that varies characteristics of the suspension according to the rough road inputs. For tires, a commercial MBD tire model is employed with identifiable parameters. The models are simulated to run on the optically measured road surface of the proving ground. Apart from the trimmed body, several important heavy attached parts are modeled separately, that represent dynamic behavior that induces complex body input load. These parts, along with suspension and powertrain systems are connected to the body using nonlinear elements such as joints, springs, and dampers. Contact conditions are used to represent mount bushing, hood lock, stopper rubber, etc.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Diamond-like carbon (DLC) coating has excellent properties like high hardness and low friction. So it has attracted considerable attention in recent years as a low-friction coating material. However, some DLC coatings display increased wear in oil containing Mo-DTC (Molybdenum-dithiocarbamates). Wear analyses of sliding surface after block-on-ring tests were conducted suggest that the decomposition product from Mo-DTC, MoO3, reacts with active sites in the DLC to promote the wear of DLC.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

Newly designed gears are subject to higher loads that demand a steel that is capable of greater pitting resistance. The application of shot peening to gears has been increasing to improve tooth root strength, but pitting resistance had not been necessarily high. This study examines the effect of alloying additions mainly on tempering resistance and the formation of a non-martensitic layer. The developed high Si-Mo type steel shows excellent pitting resistance, even in shot peened gears, as compared to that of conventional steels due to high tempering resistance and the thin, uniform non-martensitic layer. This new steel is of practical use in some multi-speed automatic transmission gears.

We developed a new Manual Transmission Gear Oil (MTF) named LV for improved fuel economy and CO2 reduction. MTF LV is a low viscosity fluid to reduce stir losses at lower temperatures. In general, low viscosity fluids can cause metal fatigue, wear and seizure. The MTF LV was designed to overcome these problems by maintaining the oil film thickness after it is deteriorated and improving the wear characteristics with additives. As a result, the MTF LV provides equal or better durability than the current MTF. In addition, it also has good performance at low temperatures, better shift feeling characteristics, and improved oxidation stability.

A new, free-cutting steel, hereafter referred to as “non-lead-added free-cutting steel”, has been developed with the intention of replacing currently applied lead containing free cutting steel. The ultimate goal of this project is to provide a new lead-free steel grade that will contribute to the removal of environmentally harmful substances from automobile parts. In this project, we have targeted the development of a material that would demonstrate levels of machinability and other mechanical properties equivalent to those of the conventional free-cutting steel to which sulfur (S), lead (Pb) and calcium (Ca) or combinations, thereof have been added. The fine dispersion of sulfide, modified by adding Mg and Ca, is most effective in enhancing the chip breakability that would otherwise deteriorate due to the absence of lead. The practical application of the non-lead-added free-cutting steel has rendered the goal of total removal of lead from special steel products highly obtainable.

It is important to reduce the viscosity of automatic transmission fluid (ATF) in order to improve fuel economy. However, in general, low viscosity fluid can cause metal fatigue, wear, and seizure. It is necessary to increase the viscosity of the fluid at higher temperatures to maintain the durability of the automatic transmission (AT). The key point is the selection of the base oil and the viscosity index improver (VII) with both a high viscosity index (VI) and excellent shear stability. On the basis of this concept, a new generation high performance ATF named WS was developed. WS can achieve the highest level of fuel economy, while maintaining the durability of the AT.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

The Vapor Reducing Fuel Tank System (Bladder Tank System) using a flexible plastic membrane (Bladder Membrane) was newly developed in order to reduce the amount of vaporized gasoline in a steel fuel tank. This Bladder Membrane is flexible to expand in proportion to a fuel volume and prevents the permeation of the vaporized gasoline. As a result of our initial study for various materials, we decided to apply a multi-layer plastic material which could achieve both low fuel permeability and good flexibility. This multi-layer material consists of polyethylene(PE) for structural material and polyamide(PA) for low permeability. The modulus of the PE needs to achieve a sufficient flexibility in order to keep the movement of the membrane. While PA material must have not only low fuel permeability but also strong adhesion with the structural material of PE. We also clarify the membrane design to keep a good flexibility and to reduce a strain.

In preparation for compliance with California's SULEV standard and Euro STAGE 4 standard, which will take effect in 2002 and 2005, respectively, we have developed a laminated planar oxygen sensor. The developed sensor has the following characteristics: high thermal conductivity and superior dielectric characteristic, due to direct joining of the heater element alumina substrate and the sensor element zirconia electrolyte; low heat stress at temperature rise, due to optimized heater design; superior sensor protection from water droplets, and improved sensor response, due to optimized arrangement of intake holes in the sensor cover. With these characteristics, the developed oxygen sensor can be activated in 10 seconds after cold start. This report describes the technologies we used to develop the early-activation oxygen sensor.

The deterioration of the friction reducing properties of engine oils containing molybdenum dithiocarbamates (MoDTCs) in service was studied. A quantitative analysis of MoDTCs and zinc dithiophosphates (ZDTPs) remaining in aged oils revealed that ZDTPs were consumed faster than MoDTCs. The consumption rate of ZDTPs was slow in the presence of MoDTCs and peroxide-decomposing antioxidants. The frictional properties of aged oils were evaluated with a reciprocating friction tester (SRV tester). The friction coefficient measured with the SRV tester was correlated to the properties of the aged oils, such as the TAN increase, TBN, and concentration of remaining ZDTPs.

This paper describes the development of alloy cast iron that can be used for the cutting edges of the trimming die of a press die. Usually, a block of tool steel or steel casting is inserted at the cutting edge of the trimming die of a press die. However, we unified the structure part and the cutting-edge part of a press die with alloy cast iron. As it can''t bear as the cutting edge in this state, the cutting edge is processed by flame-hardening. After the flame- hardening, we developed the alloy cast iron so that enough hardness may be obtained by natural air cooling. Thereby, the machining of the installation seat of the cutting edge decreased and the expense of dies has been reduced.

A method of fatigue life estimation for the spot-welds of vehicle body structures by means of Finite Element Analysis (FEA) was studied. 6 general forces applied to a nugget of spot-weld under multiaxial loads were determined and the Nominal Structural Stress (σns) was calculated from them. It was confirmed that fatigue strength of the spot-welds under various multiaxial loads could be estimated universally by using σns. Based on the theory of elasticity of plates, stress of spot-weld nugget was analyzed. The theoretical equations for determining the principal stress at the nugget edge from6 general forces acting on a nugget were derived. And the principal stress was defined as the σns. The value of σns was determined by FEM that used a solid model and compared with the theoretical calculation value. They agreed quite well. Fatigue tests of DC specimens under various multiaxial loads (shear plus cross tension and tensile shear plus torsion) were conducted.