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This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.

A new heating strategy for electrically heated catalysts has been developed which reduces power consumption while achieving the desired hydrocarbon conversion. The relationship between catalyst volume and power consumption is presented. Observations of catalytic reactions by a thermoviewer camera and mathematical simulations are used to optimize the heating pattern. Significant reductions in power consumption, while maintaining conversion efficiency, are reported by heating only the front face of the catalyst. However, prior to mass production additional work is required to improve durability, and reliability and to resolve manufacturing issues.

In order to optimize air-fuel mixture formation in a small DI diesel engine, studies were conducted into the effects of combustion chamber shape and fuel spray impingement. Based on the findings of these studies, the shape of the combustion chamber was modified to induce complex air motion with high turbulence and fuel injection was carefully controlled to achieve optimum impingement intensity. As a result, the mixture formation process was greatly improved with a consequent gain in terms of engine performance. To clarify the reasons for this improvement in combustion, a three-dimensional calculation of the in-cylinder air motion was made. The behaviour of the spray and flame was observed using an endoscope. The new combustion system, named TOYOTA Reflex Burn system (TRB) thus developed has been adopted in production engines since August 1988.