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Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Technical Paper

Development of In Mold Coating Clear Coat Paint for Carbon Fiber Sheet Molding Compound Roof

2022-03-29
2022-01-0345
Carbon Fiber Reinforced Plastic (CFRP) is used for various products in the aerospace and sports industries due to its superior specific tensile strength and specific rigidity. With increasing attention to Carbon Neutrality (CN) in the world, vehicle electrification and lightweighting are expanding. As a result, the application of CFRP to luxury cars, electric cars, and sports cars, is increasing. For example, CFRP is used on Lexus LC and RC-F, and Toyota 86 GRMN. However, there are two technical concerns. The first is its durability, which caused by CFRP resin characteristic. The second is poor appearance, which is caused by CFRP surface pinholes. In order to secure good durability and surface appearance, CFRP must be pre-treated before painting (putty applied as a filler for plastic surface coverage, followed by surface sanding) and needs multiple painting steps. Current painted CFRP is not suitable for mass production due to this long and complicated process.
Technical Paper

Variable Axial Composite Lightweight Automotive Parts Using Anisotropic Topology Optimization and Tailored Fiber Placement

2022-03-29
2022-01-0344
This paper presents a design method for continuous fiber composites in three-dimensional space with locally varying orientation distribution and their fabrication method. The design method is formulated based on topology optimization by augmented tensor field design variables. The fabrication method is based on Tailored Fiber Placement technology, whereby a CNC embroidery machine prepares the preform. The fiber path is generated from an optimized orientation distribution field. The preform is formed with vacuum-assisted resin transfer molding. The fabricated prototype weighs 120 g, a 70% weight reduction, achieving 3.5× mass-specific stiffness improvement.
Technical Paper

Development of a New High Orientation Paint System to Achieve Outstanding Real Metallic Designs

2020-04-14
2020-01-0899
Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.
Journal Article

Improving Winter Fuel Economy by Using Weather Information

2020-04-14
2020-01-1241
When the air conditioning (A/C) is turned on, the intake air to the HVAC is cooled at the evaporator. This is not only used for cooling the air temperature but also to dehumidify. Therefore, for a typical automatic climate control system, A/C will automatically operate even in winter (cold ambient temperature conditions) in order to prevent the windows from fogging despite its effect on fuel economy. In some applications, a humidity sensor is installed on top of the windshield and when the probability of fogging is low the A/C operation is disabled automatically to prevent unnecessary compressor operation which can increase fuel consumption. However, humidity sensor is not widely adopted as it requires some space to be installed and the cost is relatively expensive compared with other HVAC equipped sensors. In this study, a system was invented that disables the compressor operation when the fogging probability is low without using the conventional humidity sensor.
Technical Paper

Development of Three-Way Catalyst with Advanced Coating Layer

2020-04-14
2020-01-0653
Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.
Technical Paper

Development of Three-Way Catalysts Enhanced NOx Purifying Activity

2018-04-03
2018-01-0942
Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).
Journal Article

Development of New IGBT to Reduce Electrical Power Losses and Size of Power Control Unit for Hybrid Vehicles

2017-03-28
2017-01-1244
One way to improve the fuel efficiency of HVs is to reduce the losses and size of the Power Control Unit (PCU). To achieve this, it is important to reduce the losses of power devices (such as IGBTs and FWDs) used in the PCU since their losses account for about 20% of the total loss of an HV. Furthermore, another issue when reducing the size of power devices is ensuring the thermal feasibility of the downsized devices. To achieve the objectives of the 4th generation PCU, the following development targets were set for the IGBTs: reduce power losses by 19.8% and size by 30% compared to the 3rd generation. Power losses were reduced by the development of a new Super Body Layer (SBL) structure, which improved the trade-off relationship between switching and steady-state loss. This trade-off relationship was improved by optimizing the key SBL concentration parameter.
Technical Paper

Toyota New TNGA High-Efficiency Eight-Speed Automatic Transmission Direct Shift-8AT for FWD Vehicles

2017-03-28
2017-01-1093
The new eight-speed automatic transmission direct shift-8AT (UA80) is the first automatic transmission to be developed based on the Toyota New Global Architecture (TNGA) design philosophy. Commonizing or optimizing the main components of the UA80 enables compatibility with a wide torque range, including both inline 4-cylinder and V6 engines, while shortening development terms and minimizing investment. Additionally, it has superior packaging performance by optimizing the transmission size and arrangement achieving a low gravity center. It contributes to Vehicle’s attractiveness by improving driving performance and NVH. At the same time, it drastically improves fuel economy and quietness.
Technical Paper

Development of Instantaneous Temperature Measurement Technique for Combustion Chamber Surface and Verification of Temperature Swing Concept

2016-04-05
2016-01-0675
To improve the thermal efficiency of an internal combustion engine, the application of ceramics to heat loss reduction in the cylinders has been studied [1-2]. The approach taken has focused on the low heat conductivity and high heat resistance of the ceramic. However, since the heat capacity of the ceramic is so large, there is a problem in that the wall temperature increases during the combustion cycle. This leads to a decrease in the charging efficiency, as well as knocking in gasoline engines. To overcome these problems, the application of thermal insulation without raising the gas temperature during the intake stroke has been proposed [3-4]. As a means of achieving this, we developed a "temperature swing heat insulation coating" [5, 6, 7, 8, 9]. This reduces the heat flux from the combustion chamber into the cooling water by making the wall temperature follow the gas temperature as much as possible during the expansion and exhaust strokes.
Technical Paper

Improvement of Adhesion Properties between Epoxy Resin and Primer and between Primer and Ni Plating in Hybrid Vehicle Power Semiconductor Module under High Temperature Conditions

2016-04-05
2016-01-0500
In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.
Technical Paper

Development of a Compact Adsorption Heat Pump System for Automotive Air Conditioning System

2016-04-05
2016-01-0181
In order to reduce the energy consumption of the automotive air conditioning system, adsorption heat pump (AHP) system is one of the key technologies. We have been developing compact AHP system utilizing the exhaust heat from the engine coolant system (80-100 °C), which can meet the requirements in the automotive application. However, AHP systems have not been practically used in automotive applications because of its low volumetric power density of the adsorber. The volumetric power density of the adsorber is proportional to sorption rate, packing density and latent heat. In general, the sorption rate is determined by mass transfer resistance in primary particle of an adsorbent and heat and mass transfer resistance in packed bed. In order to improve the volumetric power density of the adsorber, it is necessary to increase the production of the sorption rate and the packing density.
Journal Article

Reaction Mechanism Analysis of Di-Air-Contributions of Hydrocarbons and Intermediates

2012-09-10
2012-01-1744
The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.
Journal Article

Development of iQ with CVT for USA

2011-04-12
2011-01-1425
TOYOTA has developed the iQ with a 1.3L engine for the Scion brand in USA. Due to the importance of fun-to-drive factor for the Scion brand image, a responsive driving performance is required even with compact packaging and a small engine. In addition, because of the recent attention to global-warming and energy issues on a global scale, development of vehicles with high fuel economy is one of the most important issues for a car manufacturer. Therefore, it is necessary for a vehicle to have both high driving performance and fuel economy. TOYOTA has adopted the CVT-i as the transmission for this purpose. The following were achieved by adopting the CVT-i as the transmission for the iQ(1.3L). 1 Responsive driving performance with shift changes without a time lag. 2 Compact transmission for efficient vehicle packaging 3 Class-leading fuel economy performance. Moreover, it was developed with adjustments for the US market by improving the shift schedule for a linear acceleration feel.
Technical Paper

New Drivetrain for Toyota's Flagship Lexus LFA Sports Car

2011-04-12
2011-01-1427
Toyota Motor Corporation has developed a new drivetrain for their flagship Lexus LFA sports car. Passionate driving experience was pursued at the forefront of development. Superior vehicle performance, handling, and responsiveness that seem to anticipate the driver's intentions are achieved. Special vehicle packaging and component placement are adopted in the LFA in order to realize such performance. The engine, clutch, and front counter gear are positioned at the front of the vehicle, and the transaxle at the rear. The engine and transaxle are connected by a rigid torque tube. The transaxle is an automated manual transmission equipped with an electrohydraulic actuator for controlling both the shift and clutch operations. This actuator enables accurate control of the transmission and extremely quick response to shift paddle operation by the driver. This paper describes a general outline of the drivetrain and each component that has significantly contributed to LFA product appeal.
Technical Paper

A Study of Mixed-FAME and Trace Component Effects on the Filter Blocking Propensity of FAME and FAME Blends

2010-10-25
2010-01-2116
Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.
Technical Paper

Study of Large OSC Materials (Ln2O2SO4) on the Basis of Sulfur Redox Reaction

2009-04-20
2009-01-1071
Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.
Technical Paper

Design Concept and Advantages of Steer-by-Wire System

2008-04-14
2008-01-0493
Because of recent advances in steering control technology, steer-by-wire systems have continued to become more realistic. The principal issue for these steer-by-wire systems is considered to be promoting reliability through the construction of a design concept that can be utilized appropriately by drivers. This paper first describes the flow between the concept and system structure, and proposes a steer-by-wire system with a mechanical backup mechanism as one possibility. This paper also describes an investigation into its potential advantages using an experimental vehicle installed with the proposed system structure. The potential advantages of steer-by-wire are improved vehicle driving performance, vehicle maneuverability, and the feasibility of innovative packaging and design. In order to make improved maneuverability and design innovations compatible, it is critical to achieve steering characteristics that require little maneuvering angle.
Technical Paper

Hexagonal Cell Ceramic Substrates for Lower Emission and Backpressure

2008-04-14
2008-01-0805
Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass
Technical Paper

Development of Sealing Material Used in the Body Welding Shop

2007-04-16
2007-01-0418
1 The principal characteristics required of sealing materials used in the body shop have focused on their adhesion to oily steel sheets and quick curing performance. Means for attaining these characteristics have been narrowed down to a basic resin system and a curing system. Various techniques have been studied to ensure proper anti-corrosion performance at the sealer application boundaries and thin application areas. They include the addition of anti-corrosion fillers, the provision of conductivity (through electro-deposition), and the application of a micro foam film over the application boundaries. Thus, prospects for attaining the same level of anti-corrosion performance as existing materials have been achieved.
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