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Exhaust emissions of seventeen 2,3,7,8-substituted chlorinated dibenzo-p-dioxin/furan (CDD/F) congeners, tetra-octa CDD/F homologues, twelve WHO 2005 chlorinated biphenyls (CB) congeners, mono-nona CB homologues, and nineteen polycyclic aromatic hydrocarbons (PAHs) from a model year 2008 Cummins ISB engine equipped with aftertreatment including a diesel oxidation catalyst (DOC) and wall flow copper or iron urea selective catalytic reduction filter (SCRF) were investigated. These systems differ from a traditional flow through urea selective catalytic reduction (SCR) catalyst because they place copper or iron catalyst sites in close proximity to filter-trapped particulate matter. These conditions could favor de novo synthesis of dioxins and furans. The results were compared to previously published results of modern diesel engines equipped with a DOC, catalyzed diesel particulate filter (CDPF) and flow through urea SCR catalyst.

Exhaust emissions were evaluated for four different catalytic exhaust emission control systems. Each system utilized a diesel oxidation catalyst, a metal-substrate partial-flow diesel particulate filter, an iron-exchanged or copper-exchanged Y-zeolite catalyst for urea selective catalytic reduction, and an ammonia slip catalyst. A 5.9-liter diesel truck engine was modified to match the exhaust conditions of a four-stroke diesel locomotive engine meeting the current Tier 2 locomotive emissions standards. NOx emissions, CO₂ emissions and exhaust temperatures were matched to the eight locomotive "throttle notch" power settings while exhaust mass flow was maintained near a constant fraction of locomotive exhaust mass flow for each "throttle notch" position. Regulated and unregulated exhaust emissions were measured over a steady-state test cycle for each of the four systems at low hours and following accelerated thermal aging and accelerated oil ash accumulation.