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In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.

SI engines fueled with hydrogen represent a promising powertrain solution to meet the ambitious target of carbon-free emissions at the tailpipe. Therefore, fast and reliable numerical tools can significantly support the automotive industry in the optimization of such technology. In this work, a 1D-3D methodology is presented to simulate in detail the combustion process with minimal computational effort. First, a 1D analysis of the complete engine cycle is carried out on the user-defined powertrain configuration. The purpose is to achieve reliable boundary conditions for the combustion chamber, based on realistic engine parameters. Then, a 3D simulation of the power-cycle is performed to mimic the combustion process. The flow velocity and turbulence distributions are initialized without the need of simulating the gas exchange process, according to a validated technique.

Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.

The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.

Emissions regulations for engine and vehicle manufacturers are bound to become more limiting to prevent greenhouse gas emissions and mitigate the negative effects that potentiate global warming. To fulfill the energy demand necessary in the transportation sector for the short-to-medium term, a parallel optimization of the internal combustion engine, powertrain and fuels is necessary. The combination of novel combustion modes like the reactivity-controlled compression ignition (RCCI), that seeks the benefits of both compression ignition and spark ignition engines, with the so-called e-fuels, that reduce the carbon footprint from well-to-wheel, is worth exploring. This work investigates the potential of the RCCI concept using OMEx-gasoline to reduce the engine-out emissions beyond the current EURO VI legislation. To do so, eight representative operating conditions from several driving cycles for heavy-duty vehicles will be explored experimentally.

In recent years, the automotive industry has been increasingly committed to developing new solutions for better and more efficient engines. One of them is the use of new insulating materials (thermal conductivity < 0.4 W/m-K, heat capacitance < 500 kJ/m3-K) to coat the engine combustion chamber walls, as well as the exhaust manifold. The main idea when coating the combustion chamber with these materials is to obtain a reduction of the temperature difference (thermal swing) between gas and walls during the engine cycle and minimize heat losses. Experimental measurements of the possible performance improvements are very difficult to obtain, mainly because the techniques available to measure wall temperature are limited. Therefore, simulations are typically used to investigate insulated combustion chambers. Nevertheless, the new generation of insulating coatings is posing challenges to numerical modelling, as layer thickness is very small (~100 μm).

Low pressure exhaust gases recirculation (LP-EGR) is becoming a state-of-the-art technique for Nitrogen oxides (NOx) reduction in compression ignited (CI) engines. However, despite the pollutant reduction benefits, LP-EGR suffers from strong non-linearities and delays which are difficult to handle, resulting in reduced engine performance under certain conditions. Measurement and observation of oxygen concentration at the intake have been a research topic over the past few years, and it may be critical for transition phases (from low pressure to high pressure EGR). Here, an adequate selection of models and sensors is essential to obtain a precise and fast measurement for control purposes. The present paper analyses different sensor configurations, with oxygen concentration measurements at the intake and exhaust manifold and combines observation techniques with sensor models to determine the potential of each configuration.

The spatial and temporal locations of autoignition depend on fuel chemistry and the temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into fuel-chemistry aspects through variation of the proportions of fuels with different reactivities, and engine operating condition variations can provide information on physical effects. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.

Computational fluid dynamics (CFD) modeling has many potentials for the design and calibration of modern and future engine concepts, including facilitating the exploration of operation conditions and casting light on the involved physical and chemical phenomena. As more attention is paid to the matching of different fuel types and combustion strategies, the use of detailed chemistry in characterizing auto-ignition, flame stabilization processes and the formation of pollutant emissions is becoming critical, yet computationally intensive. Therefore, there is much interest in using tabulated approaches to account for detailed chemistry with an affordable computational cost. In the present work, the tabulated flamelet progress variable approach (TFPV), based on flamelet assumptions, was investigated and validated by simulating constant-volume Diesel combustion with primary reference fuels - binary mixtures of n-heptane and iso-octane.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

Nowadays the combination of strict regulations for pollutant and CO2 emissions, together with the irruption of electric vehicles in the automotive market, is arising many concerns for internal combustion engine community. For this purpose, many research efforts are being devoted to the development of a new generation of high-performance spark-ignition (SI) engines for passenger car applications. Particularly, the PC ignition concept, also known as Turbulent Jet Ignition (TJI), is the focus of several investigations for its benefits in terms of engine thermal efficiency. The passive or un-scavenged version of this ignition strategy does not require an auxiliary fuel supply inside the PC; therefore, it becomes a promising solution for passenger car applications as packaging and installation are simple and straightforward.

In order to face the new challenges, spark ignition engines are evolving by following some strategies and technologies. Among them, alternative combustion processes based on the dilution of the homogeneous mixture, either with fresh air or with Exhaust Gas Recirculation (EGR), are being explored. In a higher or lower extent, these changes modify in-cylinder thermodynamic conditions during the engine operation (pressure, temperature and gas composition) thus conditioning the spark ignition system requirements that will have to evolve to become more reliable and powerful. In this framework, an experimental study on the effect of the key in-cylinder conditions on the ignition system performance has been carried out in a single-cylinder spark-ignition (SI) research engine. The study includes EGR, lambda and energizing time sweeps to assess the behavior of the engine in different operating conditions.