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Technical Paper

Exploring methanol and naphtha as alternative fuels for a hybrid-ICE battery-driven light-duty vehicle

2024-06-12
2024-37-0021
In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.
Technical Paper

A Comparative Analysis of Thermal Runaway Propagation in Different Modular Lithium-Ion Battery Configuration

2024-05-06
2024-01-2901
Thermal runaway is a critical safety concern in lithium-ion battery systems, emphasising the necessity to comprehend its behaviour in various modular setups. This research compares thermal runaway propagation in different modular configurations of lithium-ion batteries by analysing parameters such as cell spacing and distribution, application of phase change materials (PCMs), and implementing insulating materials. The study at the module level includes experimental validation and employs a comprehensive model considering heat transfer due to electrical performance and thermal runaway phenomena. It aims to identify the most effective modular configuration for mitigating thermal runaway risks and enhancing battery safety. The findings provide valuable insights into the design and operation of modular lithium-ion battery systems, guiding engineers and researchers in implementing best practices to improve safety and performance across various applications.
Technical Paper

Numerical Approach for the Characterization of the Venting Process of Cylindrical Cells Under Thermal Runaway Conditions

2024-05-06
2024-01-2900
The increasing awareness on the harmful effects on the environment of traditional Internal Combustion Engines (ICE) is driving the industry toward cleaner powertrain technologies such as battery-driven Electric Vehicles. Nonetheless, the high energy density of Li-Ion batteries can cause strong exothermic reactions under certain conditions that can lead to catastrophic results, called Thermal Runaway (TR). Hence, a strong effort is being placed on understanding this phenomena and increase battery safety. Specifically, the vented gases and their ignition can cause the propagation of this phenomenon to adjancent batteries in a pack. In this work, Computational Fluid Dynamics (CFD) are employed to predict this venting process in a LG18650 cylindrical battery. The ejection of the generated gases was considered to analyze its dispersion in the surrounding volume through a Reynolds-Averaged Navier-Stokes (RANS) approach.
Technical Paper

Battery Surface Temperature Measurement Correction for an Accelerating Rate Calorimeter with Sapphire Optical Access

2023-08-28
2023-24-0164
Upcoming legislation towards zero carbon emission is pushing the electric vehicle as the main solution to achieve this goal. However, electric vehicles still require further battery development to meet customer’s requirements as fast charge and high energy density. Both demands come with the cost of higher heat dissipation as lithium transport and chemical reaction inside the battery need to be performed faster, increasing the joule effect inside the battery. Due to its working principle, which guarantees an adiabatic environment, an accelerating rate calorimeter is used to study thermal phenomena in batteries like a thermal runaway. However, this equipment is not prepared to work with optical access, which helps to study and to comprehend battery surface distribution and other thermal aspects. This paper aims to show a methodology to correct temperature measurement when using a thermographic camera and optical access of sapphire in an accelerating rate calorimeter.
Technical Paper

Thermal Model for the analysis of the Thermal Runaway in Lithium-Ion Batteries using Accelerating Rate Calorimetry

2023-08-28
2023-24-0162
Accelerating rate calorimetry (ARC) has emerged as a powerful tool for evaluating the thermal behavior of Li-ion cells and identifying potential safety hazards. In this work, a new physical thermal model has been developed based on the first law of thermodynamics for analyzing heat and mass generated by Lithium-ion battery cells under thermal abuse conditions during EV-ARC tests. The analysis is based on the experimental data gathered from an ARC, including different temperatures and pressure inside a gas-tight canister located in the calorimeter chamber, as well as the gas composition at the end of the test. The energy balance of the battery cell includes: the energy released by the cell, the internal energy of the elements inside the canister, heat transfer between elements inside the canister, as well as the mass transfer between the cell and the gases inside the canister.
Technical Paper

Experimental and Numerical Insights on Battery Venting during Thermal Runaway

2023-04-11
2023-01-0502
Lithium-ion batteries have a well-documented failure tendency under abuse conditions with a significant release of gases and heat. This failure originated from the decomposition reactions within the battery’s electrochemical components, resulting in gas generation and increased internal pressure. To optimize battery safety, it is crucial to understand their behaviors when subjected to abuse conditions. The 18650 format cell incorporates a vent mechanism within a crimped cap to relieve pressure and mitigate the risk of rupture. However, cell venting introduces additional safety concerns associated with flammable gases and liquid electrolyte that flow into the environment. Experiments were performed with two venting caps with well-known geometries to quantify key parameters in describing the external dynamic flow of battery venting and to validate a CFD model.
Technical Paper

Combining DMDF and Hybrid Powertrains: A Look on the Effects of Different Battery Modelling Approaches

2022-03-29
2022-01-0658
Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.
Journal Article

Identifying Key Aspects of Thermal Runaway Modelling for Lithium-ion Battery Cells

2022-03-29
2022-01-0718
Electrification and hybridization of powerplants in the transportation sector is one of the most important changes in the last few decades. Lithium-ion batteries are the main energy storage systems, but despite the maturity of this technology, it has certain constrains compared to traditional internal combustion engines in the day-to-day usage. As the operating conditions of the batteries are pushed to the limits to overcome certain disadvantages relative to other conventional systems like charge and discharge times or vehicle driving range, new concerns and safety limitations must be considered. High power rates and cooling deficiencies can produce excessive operating temperatures within the cells, leading to problems with degradation or even unchain chemical reactions that can end in thermal runaway, one of the most worrying failure modes attaining electric platforms nowadays.
Journal Article

High-Speed Thermographic Analysis of Diesel Injector Nozzle Tip Temperature

2022-03-29
2022-01-0495
The temperature of fuel injectors can affect the flow inside nozzles and the subsequent spray and liquid films on the injector tips. These processes are known to impact fuel mixing, combustion and the formation of deposits that can cause engines to go off calibration. However, there is a lack of experimental data for the transient evolution of nozzle temperature throughout engine cycles and the effect of operating conditions on injector tip temperature. Although some measurements of engine surface temperature exist, they have relatively low temporal resolutions and cannot be applied to production injectors due to the requirement for a specialist coating which can interfere with the orifice geometry. To address this knowledge gap, we have developed a high-speed infrared imaging approach to measure the temperature of the nozzle surface inside an optical diesel engine.
Technical Paper

Optimal Sensor Placement for High Pressure and Low Pressure EGR Estimation

2021-04-06
2021-01-0423
Low pressure exhaust gases recirculation (LP-EGR) is becoming a state-of-the-art technique for Nitrogen oxides (NOx) reduction in compression ignited (CI) engines. However, despite the pollutant reduction benefits, LP-EGR suffers from strong non-linearities and delays which are difficult to handle, resulting in reduced engine performance under certain conditions. Measurement and observation of oxygen concentration at the intake have been a research topic over the past few years, and it may be critical for transition phases (from low pressure to high pressure EGR). Here, an adequate selection of models and sensors is essential to obtain a precise and fast measurement for control purposes. The present paper analyses different sensor configurations, with oxygen concentration measurements at the intake and exhaust manifold and combines observation techniques with sensor models to determine the potential of each configuration.
Journal Article

Comparison of the Diffusive Flame Structure for Dodecane and OMEX Fuels for Conditions of Spray A of the ECN

2020-09-15
2020-01-2120
A comparison of the flame structure for two different fuels, dodecane and oxymethylene dimethyl ether (OMEX), has been performed under condition of Spray A of the Engine Combustion Network (ECN). The experiments were carried out in a constant pressure vessel with wide optical access, at high pressure and temperature and controlled oxygen concentration. The flame structure analysis has been performed by measuring the formaldehyde and OH radical distributions using planar Laser-Induced Fluorescence (PLIF) techniques. To complement the analysis, this information was combined with that obtained with high-speed imaging of OH* chemiluminescence radiation in the UV. Formaldehyde molecules are excited with the 355-nm radiation from the third harmonic of a Nd:YAG laser, whilst OH is excited with a wavelength of 281.00-nm from a dye laser.
Technical Paper

An Experimental Investigation on Spray Mixing and Combustion Characteristics for Spray C/D Nozzles in a Constant Pressure Vessel

2018-09-10
2018-01-1783
The Engine Combustion Network (ECN) is a coordinate effort from research partners from all over the world which aims at creating a large experimental database to validate CFD calculations. Two injectors from ECN, namely Spray C and D, have been compared in a constant pressure flow vessel, which enables a field of view of more than 100 mm. Both nozzles have been designed with similar flow metrics, with Spray D having a convergent hole shape and Spray C a cylindrical one, the latter being therefore more prone to cavitation. Although the focus of the study is on reacting conditions, some inert cases have also been measured. High speed schlieren imaging, OH* chemiluminescence visualization and head-on broadband luminosity have been used as combustion diagnostics to evaluate ignition delay, lift off length and reacting tip penetration. Parametric variations include ambient temperature, oxygen content and injection pressure variations.
Technical Paper

Influence of Direct-Injected Fuel Properties on Performance and Emissions from a Light-Duty Diesel Engine Running Under RCCI Combustion Mode

2018-04-03
2018-01-0250
The dual-fuel combustion mode known as reactivity controlled compression ignition (RCCI) allows an effective control of the combustion process by means of modulating the in-cylinder fuel reactivity depending on the engine operating conditions. This strategy has been found to be able to avoid the NOx-soot trade-off appearing during conventional diesel combustion (CDC), with diesel-like or better thermal efficiency in a great part of the engine map. The role of the low reactivity fuel properties and engine settings over RCCI combustion has been widely investigated in literature, concluding that the direct-injected fuel injection timing is a key parameter for controlling the in-cylinder fuel stratification. From this, it can be inferred that the physical and chemical characteristics of the direct-injected fuel should have also an important role on the RCCI combustion process.
Technical Paper

Soot Characterization of Diesel/Gasoline Blends Injected through a Single Injection System in CI engines

2017-09-04
2017-24-0048
In the past few years’ various studies have shown how the application of a highly premixed dual fuel combustion for CI engines leads a strong reduction for both pollutant emissions and fuel consumption. In particular a drastic soot and NOx reduction were achieved. In spite of the most common strategy for dual fueling has been represented by using two different injection systems, various authors are considering the advantages of using a single injection system to directly inject blends in the chamber. In this scenario, a characterization of the behavior of such dual-fuel blend spray became necessary, both in terms of inert and reactive ambient conditions. In this work, a light extinction imaging (LEI) has been performed in order to obtain two-dimensional soot distribution information within a spray flame of different diesel/gasoline commercial fuel blends. All the measurements were conducted in an optically accessible two-stroke engine equipped with a single-hole injector.
Technical Paper

Numerical Simulation of a Direct-Acting Piezoelectric Prototype Injector Nozzle Flow for Partial Needle Lifts

2017-09-04
2017-24-0101
Actual combustion strategies in internal combustion engines rely on fast and accurate injection systems to be successful. One of the injector designs that has shown good performance over the past years is the direct-acting piezoelectric. This system allows precise control of the injector needle position and hence the injected mass flow rate. Therefore, understanding how nozzle flow characteristics change as function of needle dynamics helps to choose the best lift law in terms of delivered fuel for a determined combustion strategy. Computational fluid dynamics is a useful tool for this task. In this work, nozzle flow of a prototype direct-acting piezoelectric has been simulated by using CONVERGE. Unsteady Reynolds-Averaged Navier-Stokes approach is used to take into account the turbulence. Results are compared with experiments in terms of mass flow rate. The nozzle geometry and needle lift profiles were obtained by means of X-rays in previous works.
Journal Article

Study of Air Flow Interaction with Pilot Injections in a Diesel Engine by Means of PIV Measurements

2017-03-28
2017-01-0617
With ever-demanding emission legislations in Compression Ignition (CI) engines, new premixed combustion strategies have been developed in recent years seeking both, emissions and performance improvements. Since it has been shown that in-cylinder air flow affects the combustion process, and hence the overall engine performance, the study of swirling structures and its interaction with fuel injection are of great interest. In this regard, possible Turbulent Kinetic Energy (TKE) distribution changes after fuel injection may be a key parameter for achieving performance improvements by reducing in-cylinder heat transfer. Consequently, this paper aims to gain an insight into spray-swirl interaction through the analysis of in-cylinder velocity fields measured by Particle Image Velocimetry (PIV) when PCCI conditions are proposed. Experiments are carried out in a single cylinder optical Diesel engine with bowl-in-piston geometry.
Journal Article

An Experimental Study on Diesel Spray Injection into a Non-Quiescent Chamber

2017-03-28
2017-01-0850
Visualization of single-hole nozzles into quiescent ambient has been used extensively in the literature to characterize spray mixing and combustion. However in-cylinder flow may have some meaningful impact on the spray evolution. In the present work, visualization of direct diesel injection spray under both non-reacting and reacting operating conditions was conducted in an optically accessible two-stroke engine equipped with a single-hole injector. Two different high-speed imaging techniques, Schlieren and UV-Light Absorption, were applied here to quantify vapor penetration for non-reacting spray. Meanwhile, Mie-scattering was used to measure the liquid length. As for reacting conditions, Schlieren and OH* chemiluminescence were simultaneously applied to obtain the spray tip penetration and flame lift-off length under the same TDC density and temperature. Additionally, PIV was used to characterize in-cylinder flow motion.
Technical Paper

Characterization of Spray Evaporation and Mixing Using Blends of Commercial Gasoline and Diesel Fuels in Engine-Like Conditions

2017-03-28
2017-01-0843
Recent studies have shown that the use of highly premixed dual fuel combustion reduces pollutant emissions and fuel consumption in CI engines. The most common strategy for dual fueling is to use two injection systems. Port fuel injection for low reactivity fuel and direct injection for high reactivity fuel. This strategy implies some severe shortcomings for its real implementation in passenger cars such as the use of two fuel tanks. In this sense, the use of a single injection system for dual fueling could solve this drawback trying to maintain pollutant and efficiency benefits. Nonetheless, when single injection system is used, the spray characteristics become an essential issue. In this work the fundamental characteristics of dual-fuel sprays with a single injection system under non-evaporating engine-like conditions are presented.
Journal Article

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

2016-04-05
2016-01-0734
The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.
Technical Paper

Soot Model Calibration Based on Laser Extinction Measurements

2016-04-05
2016-01-0590
In this work a detailed soot model based on stationary flamelets is used to simulate soot emissions of a reactive Diesel spray. In order to represent soot formation and oxidation processes properly, a calibration of the soot reaction rates has to be performed. This model calibration is usually performed on basis of engine out soot measurements. Contrary to this, in this work the soot model is calibrated on local soot concentrations along the spray axis obtained from laser extinction chamber measurements. The measurements are performed with B7 certification Diesel and a series production multihole injector to obtain engine similar boundary conditions. In order to ensure that the flow and mixture field is captured well by the CFD-simulation, the simulated liquid penetration lengths and flame lift-off lengths are compared to chamber measurements.
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