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In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.

Increasing awareness of the harmful effects on the environment of traditional Internal Combustion Engines (ICE) drives the industry toward cleaner powertrain technologies such as battery-driven Electric Vehicles (EV). Nonetheless, the high energy density of Li-Ion batteries can cause strong exothermic reactions under certain conditions that can lead to catastrophic results, called Thermal Runaway (TR). Hence, a strong effort is being made to understand this phenomenon and increase battery safety. Specifically, the vented gases and their ignition can cause the propagation of this phenomenon to adjacent batteries in a pack. In this work, Computational Fluid Dynamics (CFD) is employed to predict this venting process in an LG18650 cylindrical battery. The shape of the venting cap deformation obtained from experimental results was introduced in the computational model.

Thermal runaway is a critical safety concern in lithium-ion battery systems, emphasising the necessity to comprehend its behaviour in various modular setups. This research compares thermal runaway propagation in different modular configurations of lithium-ion batteries by analysing parameters such as cell spacing and applying phase change materials (PCMs) and Silica Aerogel. The study at the module level includes experimental validation and employs a comprehensive model considering heat transfer due to thermal runaway phenomena. It aims to identify the most effective modular configuration for mitigating thermal runaway risks and enhancing battery safety. The findings provide valuable insights into the design and operation of modular lithium-ion battery systems, guiding engineers and researchers in implementing best practices to improve safety and performance across various applications.

Upcoming legislation towards zero carbon emission is pushing the electric vehicle as the main solution to achieve this goal. However, electric vehicles still require further battery development to meet customer’s requirements as fast charge and high energy density. Both demands come with the cost of higher heat dissipation as lithium transport and chemical reaction inside the battery need to be performed faster, increasing the joule effect inside the battery. Due to its working principle, which guarantees an adiabatic environment, an accelerating rate calorimeter is used to study thermal phenomena in batteries like a thermal runaway. However, this equipment is not prepared to work with optical access, which helps to study and to comprehend battery surface distribution and other thermal aspects. This paper aims to show a methodology to correct temperature measurement when using a thermographic camera and optical access of sapphire in an accelerating rate calorimeter.

Mitigating human-made climate change means cutting greenhouse gas (GHG) emissions, especially carbon dioxide (CO2), which causes climate change. One approach to achieving this is to move to a carbon-free economy where carbon emissions are offset by carbon removal or sequestration. Transportation is a significant contributor to CO2 emissions, so finding renewable alternatives to fossil fuels is crucial. Green hydrogen-fueled engines can reduce the carbon footprint of transportation and help achieve a carbon-free economy. However, hydrogen combustion is challenging in an internal combustion engine due to flame instabilities, pre-ignition, and backfire. Numerical modeling of hydrogen combustion is necessary to optimize engine performance and reduce emissions. In this work, a numerical methodology is proposed to model lean hydrogen combustion in a turbocharged port fuel injection (PFI) spark-ignition (SI) engine for automotive applications.

After-treatment sensors are used in the ECU feedback control to calibrate the engine operating parameters. Due to their contact with exhaust gases, especially NOx sensors are prone to soot deposition with a consequent decay of their performance. Several phenomena occur at the same time leading to sensor contamination: thermophoresis, unburnt hydrocarbons condensation and eddy diffusion of submicron particles. Conversely, soot combustion and shear forces may act in reducing soot deposition. This study proposes a predictive 3D-CFD model for the analysis of the development of soot deposition layer on the sensor surfaces. Alongside with the implementation of deposit and removal mechanisms, the effects on both thermal properties and shape of the surfaces are taken in account. The latter leads to obtain a more accurate and complete modelling of the phenomenon influencing the sensor overall performance.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

Internal combustion engines (ICEs) exhaust emissions, particularly nitrogen oxides (NOx), have become a growing environmental and health concern. The biggest challenge for contemporary ICE industry is the development of clean ICEs, and the use of advanced design tools like Computational Fluid Dynamics (CFD) simulation is paramount to achieve this goal. In particular, the development of aftertreatment systems like Selective Catalyst Reduction (SCR) is a key step to reduce NOx emissions, and accurate and efficient CFD models are essential for its design and optimization. In this work, we propose a novel 3D-CFD methodology, which uses a Machine Learning (ML) approach as a surrogate model for the SCR catalyst chemistry, which aims to enhance accuracy of the simulations with a moderate computational cost. The ML approach is trained on a dataset generated from a set of 1D-CFD simulations of a single channel of an SCR catalyst.

Heating devices are effective technologies to strengthen emission robustness of AfterTreatment Systems (ATS) and to guarantee emission compliance in the new boundaries given by upcoming legislations. Moreover, they allow to manage the ATS warm-up independently from engine operating conditions, thereby reducing the need for specific combustion strategies. Within heating devices, an attractive solution to provide the required thermal power without mandating a 48V platform is the fuel burner. In this work, a model-based control coordinator to manage the interaction between engine, ATS and fuel burner device has been developed, virtually validated, and optimized. The control function features a burner model and a control logic to deliver the needed amount of thermal energy, while ensuring ATS hardware protection.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.

Accelerating rate calorimetry (ARC) has emerged as a powerful tool for evaluating the thermal behavior of Li-ion cells and identifying potential safety hazards. In this work, a new physical thermal model has been developed based on the first law of thermodynamics for analyzing heat and mass generated by Lithium-ion battery cells under thermal abuse conditions during EV-ARC tests. The analysis is based on the experimental data gathered from an ARC, including different temperatures and pressure inside a gas-tight canister located in the calorimeter chamber, as well as the gas composition at the end of the test. The energy balance of the battery cell includes: the energy released by the cell, the internal energy of the elements inside the canister, heat transfer between elements inside the canister, as well as the mass transfer between the cell and the gases inside the canister.

SI engines fueled with hydrogen represent a promising powertrain solution to meet the ambitious target of carbon-free emissions at the tailpipe. Therefore, fast and reliable numerical tools can significantly support the automotive industry in the optimization of such technology. In this work, a 1D-3D methodology is presented to simulate in detail the combustion process with minimal computational effort. First, a 1D analysis of the complete engine cycle is carried out on the user-defined powertrain configuration. The purpose is to achieve reliable boundary conditions for the combustion chamber, based on realistic engine parameters. Then, a 3D simulation of the power-cycle is performed to mimic the combustion process. The flow velocity and turbulence distributions are initialized without the need of simulating the gas exchange process, according to a validated technique.

Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.

Hydrogen Internal Combustion Engines (H2-ICEs) are subject to increased attention thanks to their extremely low criteria pollutant emission and near-zero CO2 tailpipe emissions. However, to further minimize exhaust emissions and increase the efficiency of a H2-ICE, it is important to carefully control the relative air-fuel ratio of operation, i.e. Lambda (λ), which will lead in turn to an optimal combustion process. The precise λ control mainly relies upon the methodology to calculate λ on board of the engine, where the availability of reliable sensors specifically-developed for hydrogen combustion is currently limited. In this article, a comparative analysis of different methodologies for the calculation of λ is performed, comparing four methodologies: exhaust gas analysis through a Spindt-Brettschneider approach (λEMI), raw Universal Exhaust Gas Oxygen (λR-UEGO), processed Universal Exhaust Gas Oxygen (λP-UEGO) and speed-density (λSD) outputs.

In recent decades, the importance of emerging alternative fuels has increased significantly as a solution to the problems of global warming and air pollution from energy production. In this context, ammonia (NH3) is seen as a potential option and energy vector that may be able to overcome the technical challenges associated with the use of other carbon-free fuels such as hydrogen (H2) in internal combustion engines (ICE). In this research, a numerical methodology for evaluating the impact of using ammonia as a fuel for spark-ignition ICEs has been developed. A combination of a single-cylinder and multi-cylinder numerical experiments has been performed to identify the main challenges and determine correct engine configuration. In addition, the performance of the engine has been evaluated through standard homologation driving cycles, contrasting it with other alternative propulsion configurations.

Lithium-ion batteries have a well-documented failure tendency under abuse conditions with a significant release of gases and heat. This failure originated from the decomposition reactions within the battery’s electrochemical components, resulting in gas generation and increased internal pressure. To optimize battery safety, it is crucial to understand their behaviors when subjected to abuse conditions. The 18650 format cell incorporates a vent mechanism within a crimped cap to relieve pressure and mitigate the risk of rupture. However, cell venting introduces additional safety concerns associated with flammable gases and liquid electrolyte that flow into the environment. Experiments were performed with two venting caps with well-known geometries to quantify key parameters in describing the external dynamic flow of battery venting and to validate a CFD model.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

Euro 7/VII regulations are currently under discussion and are expected to be the last big regulatory step in Europe. From available documentation, it is clear the aim of further regulating the extended conditions of use which are still responsible of high emission events (e. g. cold start or altitude) as well as regulating secondary emissions such as NH3, N2O, CH4, Aldehydes (HCHO). Even if not completely fixed yet, the EU7 limits will be challenging for internal combustion engines and even more for Diesel. Despite a consistent reduction of market share, Diesel engines are expected to remain a significant portion in certain sectors such as Heavy duty (HD) and Light-commercial vehicle (LCV) for some decades. In order to reach the new limits being proposed, besides minimizing engine-out emissions, Diesel powertrain will need an aftertreatment system able to work at very high efficiency right after engine start and in almost every working and environmental condition.