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Low speed pre-ignition (LSPI) is a limiting phenomenon for several of the technologies being pursued as part of the low carbon agenda. To achieve maximum power density and efficiency engines are being downsized and turbocharged, while Direct- injection technologies are becoming ever more prominent. All changes that increase the propensity of LSPI. The low speed-high load operation envelope is limited due to LSPI. Hydrogen engines are also being explored, however, with such a low minimum enthalpy of ignition, LSPI is a major limitation to thermal efficiency. Several techniques are utilized in this study to investigate physical and physio-chemical aspects of lubricant initiated LSPI. Where possible attempts have been to validate methodologies or directional alignment with published data. The basis of the methodologies used is a validated 1D predictive combustion model of a single cylinder GTDI engine, that was used to provide simulation boundary conditions.

A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).