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Low speed pre-ignition (LSPI) is a limiting phenomenon for several of the technologies being pursued as part of the low carbon agenda. To achieve maximum power density and efficiency engines are being downsized and turbocharged, while Direct- injection technologies are becoming ever more prominent. All changes that increase the propensity of LSPI. The low speed-high load operation envelope is limited due to LSPI. Hydrogen engines are also being explored, however, with such a low minimum enthalpy of ignition, LSPI is a major limitation to thermal efficiency. Several techniques are utilized in this study to investigate physical and physio-chemical aspects of lubricant initiated LSPI. Where possible attempts have been to validate methodologies or directional alignment with published data. The basis of the methodologies used is a validated 1D predictive combustion model of a single cylinder GTDI engine, that was used to provide simulation boundary conditions.

A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

The design of a Diesel injector is a key factor in achieving higher engine efficiency. The injector's fuel atomisation characteristics are also critical for minimising toxic emissions such as unburnt Hydrocarbons (HC). However, when developing injection systems, the small dimensions of the nozzle render optical experimental investigations very challenging under realistic engine conditions. Therefore, Computational Fluid Dynamics (CFD) can be used instead. For the present work, transient, Volume Of Fluid (VOF), multiphase simulations of the flow inside and immediately downstream of a real-size multi-hole nozzle were performed, during and after the injection event with a small air chamber coupled to the injector downstream of the nozzle exit. A Reynolds Averaged Navier-Stokes (RANS) approach was used to account for turbulence. Grid dependency studies were performed with 200k-1.5M cells.

Flash-boiling of sprays may occur when a superheated liquid is discharged into an ambient environment with lower pressure than its saturation pressure. Such conditions normally exist in direct-injection spark-ignition engines operating at low in-cylinder pressures and/or high fuel temperatures. The addition of novel high volatile additives/fuels may also promote flash-boiling. Fuel flashing plays a significant role in mixture formation by promoting faster breakup and higher fuel evaporation rates compared to non-flashing conditions. Therefore, fundamental understanding of the characteristics of flashing sprays is necessary for the development of more efficient mixture formation. The present computational work focuses on modelling flash-boiling of n-Pentane and iso-Octane sprays using a Lagrangian particle tracking technique.

Detailed chemical kinetics is essential for accurate prediction of combustion performance as well as emissions in practical combustion engines. However, implementation of that is challenging. In this work, dynamic adaptive chemistry (DAC) is integrated into large eddy simulations (LES) of an n-heptane spray flame in a constant volume chamber (CVC) with realistic application conditions. DAC accelerates the time integration of the governing ordinary differential equations (ODEs) for chemical kinetics through the use of locally (spatially and temporally) valid skeletal mechanisms. Instantaneous flame structures and global combustion characteristics such as ignition delay time, flame lift-off length (LOL) and emissions are investigated to assess the effect of DAC on LES-DAC results. The study reveals that in LES-DAC simulations, the auto-ignition time and LOL obtain a well agreement with experiment data under different oxygen concentrations.

Hybrid electric vehicles offer significant fuel economy benefits, because battery and fuel can be used as complementing energy sources. This paper presents the use of dynamic programming to find the optimal blend of power sources, leading to the lowest fuel consumption and the lowest level of harmful emissions. It is found that the optimal engine behavior differs substantially to an on-line adaptive control system previously designed for the Lotus Evora 414E. When analyzing the trade-off between emission and fuel consumption, CO and HC emissions show a traditional Pareto curve, whereas NOx emissions show a near linear relationship with a high penalty. These global optimization results are not directly applicable for online control, but they can guide the design of a more efficient hybrid control system.

The tumble flow in modern spark ignition engines is assuming an evermore important role for fuel guiding, air/fuel mixing and the generation of turbulence kinetic energy to enhance the combustion process. This paper describes results obtained with laser Doppler anemometry in multiple vertical planes in the cylinder of a motored, tumble flow engine and looks at the post processed data in terms of tumble ratios and mean and turbulence kinetic energies. The tumble results indicate very different flow fields in parallel planes lying in the main tumble direction, showing the complex nature of the flows in the cylinder. A simple method of integrating the tumble ratios from the different planes is suggested, leading to a tumble ratio more in line with those expected from an integrated method of measuring tumble, albeit these results are crank angle dependent. The tumble in a perpendicular plane shows unexpected asymmetries and values for the tumble.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).

This paper presents a study of the combustion mechanism of hydrous and anhydrous ethanol in comparison to iso-octane and gasoline fuels in a single-cylinder spark-ignition research engine operated at 1000 rpm with 0.5 bar intake plenum pressure. The engine was equipped with optical access and tests were conducted with both Port Fuel Injection (PFI) and Direct Injection (DI) mixture preparation methods; all tests were conducted at stoichiometric conditions. The results showed that all alcohol fuels, both hydrous and anhydrous, burned faster than iso-octane and gasoline for both PFI and DI operation. The rate of combustion and peak cylinder pressure decreased with water content in ethanol for both modes of mixture preparation. Flame growth data were obtained by high-speed chemiluminescence imaging. These showed similar trends to the mass fraction burned curves obtained by in-cylinder heat release analysis for PFI operation; however, the trend with DI was not as consistent as with PFI.

International obligations to reduce carbon dioxide emissions and requirements to strengthen security of fuel supply, indicate a need to diversify towards the use of cleaner and more sustainable fuels. Hydrogen has been recommended as an encouraging gaseous fuel for future road transportation since with reasonable modifications it can be burned in conventional internal combustion engines without producing carbon-based tailpipe emissions. Direct injection of hydrogen into the combustion chamber can be more preferable than port fuel injection since it offers advantages of higher volumetric efficiency and can eliminate abnormal combustion phenomena such as backfiring. The current work applied a fully implicit computational methodology along with the Reynolds-Averaged Navier-Stokes (RANS) approach to study the mixture formation and combustion in a direct-injection spark-ignition engine with hydrogen fuelling.

Particulate emissions are of growing concern due to health impacts. Many urban areas around the world currently have particulate matter levels exceeding the World Health Organisation safe limits. Gasoline engines, especially when equipped with direct injection systems, contribute to this pollution. In recognition of this fact European limits on particulate mass and number are being introduced. A number of ways to meet these new stringent limits have been under investigation. The focus of this paper is on particulate emissions reduction through improvements in fuel delivery. This investigation is part of the author's ongoing particulate research and development that includes optical engine spray and combustion visualisation, CFD method development, engine and vehicle testing with the aim to move particulate emission development upstream in the development process.

The paper discusses the concept, design and final results from the ‘Ultra Boost for Economy’ collaborative project, which was part-funded by the Technology Strategy Board, the UK's innovation agency. The project comprised industry- and academia-wide expertise to demonstrate that it is possible to reduce engine capacity by 60% and still achieve the torque curve of a modern, large-capacity naturally-aspirated engine, while encompassing the attributes necessary to employ such a concept in premium vehicles. In addition to achieving the torque curve of the Jaguar Land Rover naturally-aspirated 5.0 litre V8 engine (which included generating 25 bar BMEP at 1000 rpm), the main project target was to show that such a downsized engine could, in itself, provide a major proportion of a route towards a 35% reduction in vehicle tailpipe CO2 on the New European Drive Cycle, together with some vehicle-based modifications and the assumption of stop-start technology being used instead of hybridization.

Unlike RANS method, LES method needs more time and much more grids to accurately simulate the spray process. In KIVA, spray process was modeled by Lagrangain-drop and Eulerian-fluid method. The coarse grid can cause errors in predicting the droplet-gas relative velocity, so for reducing grid dependency due to the relative velocity effects, an improved spray model based on a gas-jet theory is used in this work and in order to validate the model seven different size grids were used. In this work, the local dense grid was used to reduce the computation cost and obtain accurate results that also were compared with entire dense grid. Another method to improve computation efficiency is the MUSCL (Monotone Upstream-centered Schemes for Conservation Laws) differencing scheme that was implemented into KIVA3V-LES code to calculate the momentum convective term and reduce numerical errors.

Hydrogen has been largely proposed as a possible fuel for internal combustion engines. The main advantage of burning hydrogen is the absence of carbon-based tailpipe emissions. Hydrogen's wide flammability also offers the advantage of very lean combustion and higher engine efficiency than conventional carbon-based fuels. In order to avoid abnormal combustion modes like pre-ignition and backfiring, as well as air displacement from hydrogen's large injected volume per cycle, direct injection of hydrogen after intake valve closure is the preferred mixture preparation method for hydrogen engines. The current work focused on computational studies of hydrogen injection and mixture formation for direct-injection spark-ignition engines. Hydrogen conditions at the injector's nozzle exit are typically sonic.

Iso-stoichiometric ternary blends - in which three-component blends of gasoline, ethanol and methanol are configured to the same stoichiometric air-fuel ratio as an equivalent binary ethanol-gasoline blend - can function as invisible "drop-in" fuels suitable for the existing E85/gasoline flex-fuel vehicle fleet. This has been demonstrated for the two principal means of detecting alcohol content in such vehicles, which are considered to be a virtual, or software-based, sensor, and a physical sensor in the fuel line. Furthermore when using such fuels the tailpipe CO₂ emissions are essentially identical to those found when the vehicle is operated on E85. Because of the fact that methanol can be made from a wider range of feed stocks than ethanol and at a cheaper price, these blends then provide opportunities to improve energy security, to reduce greenhouse gas emissions and to produce a fuel blend which could potentially be cheaper on a cost-per-unit-energy basis than gasoline or diesel.

Five different fuels, including gasoline, commercial E85, pure methanol and two mixtures of gasoline, ethanol and methanol, (GEM), configured to a target stoichiometric air fuel ratio have been investigated in a fully-optically-accessed engine. The work investigated effects of injection duration, and performed spray imaging, thermodynamic analysis of the combustion and OH imaging, for two fixed engine conditions of 2.7 and 3.7 bar NMEP at 2000 rpm. The engine was operated with constant ignition timing for all fuels and both loads. One of the most important results from this study was the suitability of a single type of injector to handle all the fuels tested. There were differences observed in the spray morphology between the fuels, due to the different physical properties of the fuels. The energy utilisation measured in this study showed differences of up to 14% for the different GEM fuels whereas an earlier in-vehicle study had showed only 2 to 3%.

The paper presents vehicle-based test work using tri-component, or ternary, blends of gasoline, ethanol and methanol for which the stoichiometric air-fuel ratio (AFR) was controlled to be 9.7:1. This is the same as that of conventional "E85" alcohol-based fuel. Such ternary blends are termed "GEM" after the first initial of the three components. The present work was a continuation of an earlier successful project which established that the blends were effectively invisible to a car using a virtual alcohol sensor. The vehicle used here employed the other major technology in flex-fuel vehicles to determine the proportion of alcohol fuel in the tank, a physical alcohol sensor. Another aspect of the present work included the desire to investigate ternary blend replacements for E85 having low ethanol concentrations. Evidence from the previous work suggested that under specific conditions, ethanol was required in some amount to act as a cosolvent for the gasoline and methanol in the blend.

The paper presents the concept of ternary blends of gasoline, ethanol and methanol in which the stoichiometric air-fuel ratio (AFR) is controlled to be 9.7:1, the same as that of conventional ‘E85’ alcohol-based fuel. This makes them iso-stoichiometric. Such blends are termed ‘GEM’ after the first initial of the three components. Calculated data is presented showing how the volumetric energy density relationship between the three components in these blends changes as the stoichiometric AFR is held constant but ethanol content is varied. From this data it is contended that such GEM blends can be ‘drop-in’ alternatives to E85, because when an engine is operated on any of these blends the pulse widths of the fuel injectors would not change significantly, and so there will be no impact on the on-board diagnostics from the use of such blends in existing E85/gasoline flex-fuel vehicles.

Diesel fuels usually comprise a wide range of compounds having different molecular structures which can affect both the fuel's physical properties and combustion characteristics. In future, as synthetic fuels from fossil and sustainable sources become increasingly available, it could be possible to control the fuel's molecular structure to achieve clean and efficient combustion. This paper presents experimental results of combustion and emissions studies undertaken on a single cylinder diesel engine supplied with 18 different fuels each comprising a single, acyclic, non-oxygenated hydrocarbon molecule. These molecules were chosen to highlight the effect of straight carbon chain length, degree of saturation and the addition of methyl groups as branches to a straight carbon chain.