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This paper investigates the gaseous and particulate emissions of a hydrogen powered direct injection spark ignition engine. Experiments were performed over different engine speeds and loads and with varying air- fuel ratio, start of injection and intake manifold pressure. An IAG FTIR system was used to detect and measure a variety of gaseous emissions, which include standard emissions such as NOX and unburned hydrocarbons as well as some non-standard emissions such as formaldehyde, formic acid, and ammonia. The particle number concentration and size distribution were measured using a DMS 500 fast particle analyzer from Cambustion. Particle composition was investigated using ICP analysis as well as a Sunset OC/EC analyzer to determine the soot content and the presence of any unburned engine oil. The results show that NOX emissions range between 0.1 g/kWh for a λ of 2.5 and 10 g/kWh λ of 1.5.

The transport sector is experiencing a shift to zero-carbon powertrains driven by aggressive international policies aiming to fight climate change. Battery electric vehicles (BEVs) will play the main role in passenger car applications, while diversified solutions are under investigation for the heavy-duty sector. Within this framework, Light Commercial Vehicles (LCVs) impact is not negligible and accountable for about 2.5% of greenhouse gas (GHG) emissions in Europe. In this regard, few LCV comparative assessments on green powertrains are available in the scientific literature and justified by the fact that several factors and limitations should be considered and addressed to define optimal powertrain solutions for specific use cases. The proposed research study deals with a comparative numerical assessment of different zero-carbon powertrain solutions for LCV. BEVs are compared to hydrogen-based fuel cells (FC) and internal combustion engines (ICE) powered vehicles.

The combustion instability at low loads is one of the key technology risks that needs to be addressed with the development of gasoline compression ignition (GCI) engine. The misfires and partial burns due to combustion instability leads to excessive hydrocarbon (HC) and carbon monoxide (CO) emissions. This study aims to improve the combustion robustness and reduce the emissions at low loads. The GCI engine used in this study has unique hardware features of a spark plug placed adjacent to the centrally mounted gasoline direct injector and a shallow pent roof combustion chamber coupled with a bowl in piston geometry. The engine experiments were performed in a single cylinder GCI engine at 3 bar indicated mean effective pressure (IMEP) and 1500 rpm for certified gasoline with research octane number (RON) = 91.

The global need for de-carbonization and stringent emission regulations are pushing the current engine research toward alternative fuels. Previous studies have shown that the uHC, CO, and CO2 emissions are greatly reduced and brake thermal efficiency increases with an increase in hydrogen concentration in methane-hydrogen blends for the richer mixture compositions. However, the combustion suffers from high NOx emissions. While these trends are well established, there is limited information on a detailed optical study on the effect of air-excess ratio for different methane-hydrogen mixtures. In the present study, experimental investigations of different methane-hydrogen blends between 0 and 100% hydrogen concentration by volume for the air-excess ratio of 1, 1.4, 1.8, and 2.2 were conducted in a heavy-duty optical diesel engine converted to spark-ignition operation. The engine was equipped with a flat-shaped optical piston to allow bottom-view imaging of the combustion chamber.

The pre-chamber combustion (PCC) concept is a proven lean or diluted combustion technique for internal combustion engines with benefits in engine efficiency and reduced NOx emissions. The engine lean operation limit can be extended by supplying auxiliary fuel into the pre-chamber and thereby, achieving mixture stratification inside the pre-chamber over the main chamber. Introducing liquid fuels into the pre-chambers is challenging owing to the small form factor of the pre-chamber. With a conventional injector, the fuel penetrates in liquid form and impinges on the pre-chamber walls, which leads to increased unburned hydrocarbon emissions from the pre-chamber. In this study, a prototype liquid fuel injector is introduced which preheats the fuel within a heated chamber fitted with an electrical heating element before injecting an effervescently atomized spray into the pre-chamber.

Typical automotive emission testing systems usually employ Flame Ionization Detection (FID) analyzers to measure unburned fuel species in the exhaust, but the technique is not suitable for engines operating on alcohol fuels. The FID method is not sensitive to measuring unburned alcohol fuels due to the presence of oxygen bonds in the fuel molecule. Other techniques, such as Fourier Transform Infrared (FTIR), can provide accurate unburned fuel measurements with alcohol fuel. However, these techniques are expensive and are less accessible compared to FID analyzers. In this study, the unburned fuel emissions from the engine exhaust were measured simultaneously with FID and FTIR analyzers, with the engine operating on pure alcohols, which are methanol, ethanol, and n-butanol. While most previous work focuses on stoichiometric air-fuel mixtures, a wide range of lean operating conditions between global-λ 1.6 to 2.8 will be tested in this study.

Lean combustion is one of the most applied methods to increase engine efficiency and maintain a good trade-off with engine emissions. The pre-chamber combustion (PCC) is one of the most promising combustion concepts to extend the lean operating limits of the engine. The Narrow throat pre-chamber has shown better lean limit extension compared to other ignition sources. The pre-chamber jets and the main-chamber combustion were studied in a Heavy-Duty optical engine using methane fuel. The tested conditions covered global excess air ratios (λ), between 1.9 to 2.3. The combustion process was recorded using three collection systems: (a) Natural Flame Luminosity (NFL) with a temporal resolution of 0.1 CAD; (b) OH* Chemiluminescence, and (c) CH* Chemiluminescence with a temporal resolution of 0.2 CAD for both. The propagating velocity of the reacting jets was studied using Combustion Image Velocimetry (CIV) based on bottom view images of the main chamber.

The shift toward electrification and limitations in battery electric vehicle technology have led to high demand for hybrid vehicles (HEVs) that utilize a battery and an internal combustion engine (ICE) for propulsion. Although HEVs enable lower fuel consumption and emissions compared to conventional vehicles, they still require combustion of fuels for ICE operation. Thus, emissions from hybrid vehicles are still a major concern. Engine starts are a major source of emissions during any driving event, especially before the three-way catalyst (TWC) reaches its light-off temperature. Since the engine is subjected to multiple starts during most driving events, it is important to mitigate and better understand the impact of these emissions. In this study, experiments were conducted to analyze engine starts in a hybrid powertrain on different experimental setup.

An electrically heated catalyst (EHC) in the three-way catalyst (TWC) aftertreatment system of a gasoline internal combustion engine (ICE) provides cold engine start exhaust pollutant emission reduction potential. The EHC can be started before switching on the ICE, thereby offering the possibility to pre-heat (PRH) the TWC, in the absence of exhaust flow. The EHC can also provide post engine start heat (PSH) when the heat is accompanied by exhaust mass flow over the TWC. A mixed heating strategy (MXH) comprises both PRH and PSH. All three strategies are evaluated under a range of engine start variations using an ICE-exhaust aftertreatment (EATS) simulation framework. It is driven by an engine speed-torque requested trace, with an engine-out emissions model focused on cold-start, engine heating and catalyst heating engine measures and a physics- based EATS with EHC model.

Compared to conventional diesel combustion (CDC), isobaric combustion can achieve higher thermal efficiency while lowering heat transfer losses and nitrogen oxides (NOx). However, isobaric combustion suffers from higher soot emissions. While the aforementioned trends are well established, there is limited literature about the high-temperature reaction zones, the liquid-phase penetration distance, and the flame tip propagation velocity of isobaric combustion. In the present study, the line-of-sight integrated imaging of Mie-scattering, combustion luminosity, and CH* chemiluminescence were conducted in an optically accessible single-cylinder heavy-duty diesel engine. The engine was equipped with a flat-bowl-shaped optical piston to allow bottom-view imaging of the combustion chamber. The experiments were conducted using n-heptane fuel for CDC and isobaric combustion modes.

Soot particle size, particle concentration and volume fraction were measured by laser based methods in optically dense, highly turbulent combusting diesel sprays under engine-like conditions. Experiments were done in the Chalmers High Pressure, High Temperature spray rig under isobaric conditions and combusting commercial diesel fuel. Laser Induced Incandescence (LII), Elastic Scattering and Light Extinction were combined quasi-simultaneously to quantify particle characteristics spatially resolved in the middle plane of a combusting spray at two instants after the start of combustion. The influence that fuel injection pressure, gas temperature and gas pressure exert on particle size, particle concentration and volume fraction were studied. Probability density functions of particle size and two-dimensional images of particle diameter, particle concentration and volume fraction concerning instantaneous single-shot cases and average measurements are presented.

Investigating combustion characteristics of oxygenated gasoline and gasoline blended ethanol is a subject of recent interest. The non-linearity in the interaction of fuel components in the oxygenated gasoline can be studied by developing chemical kinetics of relevant surrogate of fewer components. This work proposes a new reduced four-component (isooctane, heptane, toluene, and ethanol) oxygenated gasoline surrogate mechanism consisting of 67 species and 325 reactions, applicable for dynamic CFD applications in engine combustion and sprays. The model introduces the addition of eight C1-C3 species into the previous model (Li et al; 2019) followed by extensive tuning of reaction rate constants of C7 - C8 chemistry. The current mechanism delivers excellent prediction capabilities in comprehensive combustion applications with an improved performance in lean conditions.

This paper investigates how particulates number PN is influenced by fuel wall-film, liner wetting, and the mixing quality for different start of injection timings (SOI). Both experimental data with PN measurements, endoscope images from a high-speed camera from a single-cylinder engine, and CFD simulations were used for the analysis. Engine geometry was a spray-guided system with 300 bar fuel pressure and with single injections. Data was captured for 2000 rpm / 9 bar IMEPn. The results show that fuel film on the piston was only found to significantly increase PN for over-advanced SOI (in our engine geometry, earlier than -310 CAD). This results in luminescence from diffusion burn on the piston surface, which strongly contributes to PN. For an SOI timing of -310 CAD, fuel film on piston reaches a maximum of 3% of the injected fuel, vaporizes, and no remaining fuel film is found at the time of ignition. Approximately 0.5-1% of the fuel ends up on the liner.

The increasing demand for high-octane fuels is pushing the combustion research towards investigating new potential fuels and octane boosters. In addition to their high-octane, those additives should be environmentally friendly. In this study, the anti-knock properties of Dicyclopentadiene (DCPD) as an additive to primary reference fuels (PRF) and toluene primary reference fuels (TPRF) have been investigated. The Research octane number (RON) and Motor octane number (MON) were measured using Cooperative Fuels Research (CFR) engine for four different fuel blends; PRF 60 + 10% DCPD, PRF 60 + 20% DCPD, PRF 70 + 10% DCPD and TPRF 70 + 10% DCPD. In addition, homogenous charge compression ignition (HCCI) was also performed using the CFR engine to show the effect of DCPD on suppressing low temperature chemistry of reference fuels.

Drag reducing agents (DRAs) are extensively used to increase the capacity of pipelines to transport crude oils and finished products. The amount of DRA that can be used in gasoline is limited by the tendency of the high molecular weight DRAs to form engine deposits. The use of deposit control additives (DCAs) could help to mitigate this effect, enabling increased DRA treatment rates and improved pipeline capacity. A study has been undertaken to investigate the engine test response of these additives, and has suggested that higher DRA treat rates may be possible when accompanied by a deposit control additive to address increased intake valve deposits. Conversely, the effect on combustion chamber deposits is not clear and further studies would be required. Other engine related aspects such as intake valve deposit stick have also been investigated and under the conditions tested do not appear to be adversely affected by either the DRA or the deposit control additive.

Compared to conventional diesel combustion (CDC), isobaric combustion can achieve a similar or higher indicated efficiency, lower heat transfer losses, reduced nitrogen oxides (NOx) emissions; however, with a penalty of soot emissions. While the engine performance and exhaust emissions of isobaric combustion are well known, the overall flame development, in particular, the flow-field details within the flames are unclear. In this study, the performance analysis of CDC and two isobaric combustion cases was conducted, followed by high-speed imaging of Mie-scattering and soot luminosity in an optically accessible, single-cylinder heavy-duty diesel engine. From the soot luminosity imaging, qualitative flow-fields were obtained using flame image velocimetry (FIV). The peak motoring pressure (PMP) and peak cylinder pressure (PCP) of CDC are kept fixed at 50 and 70 bar, respectively.

Isobaric combustion has shown the potential of improving engine efficiency by lowering the heat transfer losses. Previous studies have achieved isobaric combustion through multiple injections from a single central injector, controlling injection timing and duration of the injection. In this study, we employed three injectors, i.e. one centrally mounted (C) on the cylinder head and two side-injectors (S), slant-mounted on cylinder head protruding their nozzle tip near piston-bowl to achieve the isobaric combustion. This study visualized the flame development of isobaric combustion, linking flow-field details to the observed trends in engine efficiency and soot emissions. The experiments were conducted in an optically accessible single-cylinder heavy-duty diesel engine using n-heptane as fuel. Isobaric combustion, with a 50 bar peak pressure, was achieved with three different injection strategies, i.e. (C+S), (S+C), and (S+S).

The high-pressure isobaric combustion has been proposed as the most suitable combustion mode for the double compre4ssion expansion engine (DCEE) concept. Previous experimental and simulation studies have demonstrated an improved efficiency compared to the conventional diesel combustion (CDC) engine. In the current study, isobaric combustion was achieved using a single injector with multiple injections. Since this concept involves complex phenomena such as spray to spray interactions, the computational models were extensively validated against the optical engine experiment data, to ensure high-fidelity simulations. The considered optical diagnostic techniques are Mie-scattering, fuel tracer planar laser-induced fluorescence (PLIF), and natural flame luminosity imaging. Overall, a good agreement between the numerical and experimental results was obtained.

The effects of intake pressure (Pin), start of injection (SOI), injection pressure (Pinj), injection split ratio (Qsplit), internal and external exhaust gas recirculation rates were varied to optimize several key parameters at a partially pre-mixed combustion low load/low speed condition using CFD. These include indicated specific fuel consumption (ISFC), combustion phasing (CA50), maximum rate of pressure rise (MRPR), maximum cylinder pressure (Pmax), indicated specific NOx (sNOx), indicated specific hydrocarbons (sHC) and Filter Smoke Number (FSN) emissions. Low-load point (6 bar indicated mean effective pressure (IMEP), 1500 revolutions per minute (RPM)) was selected where Pin varied between 1.25 and 1.5 bar, SOI between -100 and -10 crank angle degree (CAD) after top dead center (aTDC), Pinj between 100 and 200 bar, split ratio between 0 and 0.5, EGR between 0 and 45% and internal EGR measured by rebreathing valve height was varied between 0 and 4.5 mm.

Alcohol-based fuels are a viable alternative to fossil fuels for powering vehicles. As a drop-in fuel, an oxygenated fuel blend containing the C8 alcohol 2-ethylhexanol (isomer of octanol), hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) can reduce soot and NOx emissions whilst maintaining engine performance. However, fuel injection strategy significantly affects combustion and hence has been investigated with a view to reducing emissions whilst maintaining engine efficiency. In a single cylinder light-duty compression ignition research engine, the effect of different injection strategies (main, main/post, double pre/main, double pre/main/post injection) and EGR levels (0%, 19%) on specifically NOx, soot emissions and particle size distribution was investigated for three different fuels: fossil diesel fuel, HVO and the oxygenated blend. The blend was designed to have diesel-like combustion properties (cetane number of 52) and had an oxygen content of 5.4% by mass.