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The effects of charge non-uniformity on autoignition of methane/air mixtures in a motored engine are investigated analytically using a varying global kinetic data model derived from the results of a detailed chemical kinetic scheme under similar conditions in a simple adiabatic constant volume reactor. These derived varying global kinetic data model was implemented in the CFD KIVA-3 code. The relative contribution of fluid motion generated by piston motion, heat transfer, chemical reactivity of the cylinder charge and swirl movement to the inhomogeneities in the properties of the cylinder charge and their consequent effects on the evolution of the autoignition process are presented and discussed.

The effects of residual gases on the combustion process of engines are examined through analysing the cyclic variations of autoignition in a motored engine fuelled with homogeneous gaseous fuel-air mixtures. The changes in composition and temperature of residual gases as well as the associated rates of the preignition reactions are followed over a number of consecutive working cycles at a constant engine speed to establish whether autoignition will take place and how many cycles are need for its occurrence. It is in that the residual gases associated with partial oxidation reactions tend to have strong kinetic but hardly any thermal or diluting effects, while residual gases produced from the more complete combustion following autoignition tend to possess significant thermal, kinetic and diluting effects.