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Fe16N2 is one of the promising candidates for rare-earth free magnets. It possesses a giant saturation magnetization (Ms) and reasonably high magnetocrystalline anisotropy. Past efforts made in synthesizing Fe16N2 were mostly on thin films, foils, and fine powders through different processes including sputtering, ion implantation, chemical reactions, and ball milling; this could cause a challenge of scaling up into massive production. The limitation in massive production of Fe16N2 requires intensive investigations to conquer. Compared with our previous endeavor of the low-temperature synthesizing process of Fe16N2 in bulk form, this paper proposes a method of gaseous nitridation with a high-temperature approach that can improve the process efficiency by applying the quenching and tempering treatment to address the challenge.

Previously, the authors have proposed a novel strategy called trajectory based combustion control for the free piston engine (FPE) where the shape of the piston trajectory between top and bottom dead centers is used as a control input to modulate the chemical kinetics of the fuel-air mixture inside the combustion chamber. It has been shown that in case of a hydraulic free piston engine (HFPE), using active motion control, the piston inside the combustion chamber can be forced to track any desired trajectory, despite the absence of a crankshaft, providing reliable starting and stable operation. This allows the use of optimized piston trajectory for every operating point which minimizes fuel consumption and emissions. In this work, this concept is extended to an electrical free piston engine (EFPE) as a modular power source.

In this work, engine-out particle mass (PM) and particle number (PN) emissions were experimentally examined from a gasoline direct injection (GDI) engine operating in two lean combustion modes and one stoichiometric mode with a fuel of known properties. Ten steady state operating points, two constant speed load steps, and an engine cold start were examined. Results showed that solid particles emitted from the engine under steady state stoichiometric conditions had a uniquely broad size distribution that was relatively flat between the diameters of 10 and 100 nm. In most operating conditions, lean homogenous modes can achieve lower particle emissions than stoichiometric modes while improving engine thermal efficiency. Alternatively, lean stratified operating modes resulted in significantly higher PN and PM emissions than both lean homogeneous and stoichiometric modes with increased efficiency only at low engine load.

A key challenge for the practical introduction of dual-fuel reactivity controlled compression ignition (RCCI) combustion modes in diesel engines is the requirement to store two fuels on-board. This work demonstrates that partially reforming diesel fuel into less reactive products is a promising method to allow RCCI to be implemented with a single stored fuel. Experiments were conducted using a thermally integrated reforming reactor in a reformed exhaust gas recirculation (R-EGR) configuration to achieve RCCI combustion using a light-duty diesel engine. The engine was operated at a low engine load and two reformed fuel percentages over ranges of exhaust gas recirculation (EGR) rate and main diesel fuel injection timing. Results show that RCCI-like emissions of NOx and soot were achieved load using the R-EGR configuration. It was also shown that complete fuel conversion in the reforming reactor is not necessary to achieve sufficiently low fuel reactivity for RCCI combustion.

Fuel reforming during a Negative Valve Overlap (NVO) period is an effective approach to control Low Temperature Gasoline Combustion (LTGC) ignition. Previous work has shown through experiments that primary reference fuels reform easily and produce several species that drastically affect ignition characteristics. However, our previous research has been unable to accurately predict measured reformate composition at the end of the NVO period using simple single-zone models. In this work, we use a stochastic reactor model (SRM) closed cycle engine simulation to predict reformate composition accounting for in-cylinder temperature and mixture stratification. The SRM model is less computationally intensive than CFD simulations while still allowing the use of large chemical mechanisms to predict intermediate species formation rates.

Partially premixed low temperature combustion (LTC) in diesel engines is a strategy for reducing soot and NOX formation, though it is accompanied by higher unburned hydrocarbon (UHC) emissions compared to conventional mixing-controlled diesel combustion. In this work, two independent methods of quantifying light UHC species from a diesel engine operating in early LTC (ELTC) modes were compared: Fourier transform infrared (FT-IR) spectroscopy and gas chromatography-mass spectroscopy (GC-MS). A sampling system was designed to capture and transfer exhaust samples for off-line GC-MS analysis, while the FT-IR sampled and quantified engine exhaust in real time. Three different ELTC modes with varying levels of exhaust gas recirculation (EGR) were implemented on a modern light-duty diesel engine. GC-MS and FT-IR concentrations were within 10 % for C2H2, C2H4, C2H6, and C2H4O. While C3H8 was identified and quantified by the FT-IR, it was not detected by the GCMS.

Many dual fuel technologies have been proposed for diesel engines. Implementing dual fuel modes can lead to emissions reductions or increased efficiency through using partially premixed combustion and fuel reactivity control. All dual fuel systems have the practical disadvantage that a secondary fuel storage and delivery system must be included. Reforming the primary diesel to a less reactive vaporized fuel on-board has potential to overcome this key disadvantage. Most previous research regarding on-board fuel reforming has been focused on producing significant quantities of hydrogen. However, only partially reforming the primary fuel is sufficient to vaporize and create a less volatile fuel that can be fumigated into an engine intake. At lower conversion efficiency and higher equivalence ratio, reforming reactors retain higher percentage of the inlet fuel’s heating value thus allowing for greater overall engine system efficiency.

In-cylinder reforming of injected fuel during an auxiliary negative valve overlap (NVO) period can be used to optimize main-cycle auto-ignition phasing for low-load Low-Temperature Gasoline Combustion (LTGC), where highly dilute mixtures can lead to poor combustion stability. When mixed with fresh intake charge and fuel, these reformate streams can alter overall charge reactivity characteristics. The central issue remains large parasitic heat losses from the retention and compression of hot exhaust gases along with modest pumping losses that result from mixing hot NVO-period gases with the cooler intake charge. Accurate determination of total cycle energy utilization is complicated by the fact that NVO-period retained fuel energy is consumed during the subsequent main combustion period. For the present study, a full-cycle energy analysis was performed for a single-cylinder research engine undergoing LTGC with varying NVO auxiliary fueling rates and injection timing.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

The impact of compression ratio on engine efficiency is well known. A plethora of mechanical concepts have been proposed for altering engine compression ratio in real time. Some of these, like free-piston configurations or complex crank-slider mechanisms have the added ability to alter piston trajectory along with compression ratio. This secondary modality raises the question: Is there a more optimal piston position versus crank-angle profile for spark-ignition (SI) engines than the near-sinusoidal motion produced by a traditional four-bar crank-slider mechanism? Very little published literature directly addresses this question. This work presents the results of a quasi-dimensional SI engine model using piston trajectory as an input. Specific trajectory traits including increased dwell at top dead center and asymmetric compression and expansion strokes were swept. The trajectory also was optimized using a single objective genetic algorithm with 60 individuals and 40 generations.

The human thermal comfort, which has been a subject of extensive research, is a principal objective of the automotive climate control system. Applying the results of research studies to the practical problems require quantitative information of the thermal environment in the passenger compartment of a vehicle. The exposure to solar radiation is known to alter the thermal environment in the passenger compartment. A photovoltaic-cell based sensor is commonly used in the automotive climate control system to measure the solar radiation exposure of the passenger compartment of a vehicle. The erroneous information from a sensor however can cause thermal discomfort to the occupants. The erroneous measurement can be due to physical or environmental parameters. Shading of a solar sensor due to the opaque vehicle body elements is one such environmental parameter that is known to give incorrect measurement.

The critical speed method uses measurements of the radii of yawmarks left by vehicles, together with values for centripetal acceleration, to estimate the speeds of the vehicles when the yawmarks were made. Several field studies have indicated that equating the centripetal force with braking friction produced biased estimates, but that the biases tended to be small (e.g. within 10%-15% on average) and led to underestimates, suggesting that the method can be useful for forensic purposes. Other studies, however, have challenged this conclusion. The critical speed method has also seen use in safety-related research, where it is important to have a reliable assessment of the uncertainty associated with a speed estimate. This paper describes a variant of the critical speed method, where data from field tests lead to an informative prior probability distribution for the centripetal acceleration.

The development of the WorldSID 50th percentile male dummy was initiated in 1997 by the International Organization for Standardization (ISO/SC12/TC22/WG5) with the objective of developing a more biofidelic side impact dummy and supporting the adoption of a harmonized dummy into regulations. More than 45 organizations from all around the world have contributed to this effort including governmental agencies, research institutes, car manufacturers and dummy manufacturers. The first production version of the WorldSID 50th male dummy was released in March 2004 and demonstrated an improved biofidelity over existing side impact dummies. Full-scale vehicle tests covering a wide range of side impact test procedures were performed worldwide with the WorldSID dummy. However, the vehicle safety performance could not be assessed due to lack of injury risk curves for this dummy. The development of these curves was initiated in 2004 within the framework of ISO/SC12/TC22/WG6 (Injury criteria).

The most recent goal of our research program was to identify the optimal features of each of three garments to maintain core temperature and comfort under intensive physical exertion. Four males and 2 females between the ages of 22 and 46 participated in this study. The garments evaluated were the MACS-Delphi, Russian Orlan, and NASA LCVG. Subjects were tested on different days in 2 different environmental chamber temperature/humidity conditions (24°C/H∼28%; 35°C/H∼20%). Each session consisted of stages of treadmill walking/running (250W to 700W at different stages) and rest. In general, the findings showed few consistent differences among the garments. The MACS-Delphi was better able to maintain subjects within a skin and core temperature comfort zone than was evident in the other garments as indicated by a lesser fluctuation in temperatures across physical exertion levels.

Homogeneous Charge Compression Ignition (HCCI) combustion shows a high potential of reducing both fuel consumption and exhaust gas emissions. Many works have been devoted to extend the HCCI operation range in order to maximize its fuel economy benefit. Among them, fuel injection strategies that use fuel reforming to increase the cylinder charge temperature to facilitate HCCI combustion at low engine loads have been proposed. However, to estimate and control an optimal amount of fuel reforming in the cylinder of an HCCI engine proves to be challenging because the fuel reforming process depends on many engine variables. It is conceivable that the amount of fuel reforming can be estimated since it correlates with the combustion phasing which in turn can be measured using a cylinder pressure sensor.

General Motors recently demonstrated two driveable test vehicles powered by a Homogeneous Charge Compression Ignition (HCCI) engine. HCCI combustion has the potential of a significant fuel economy benefit with reduced after-treatment cost. However, the biggest challenge of realizing HCCI in vehicle applications is controlling the combustion process. Without a direct trigger mechanism for HCCI's flameless combustion, the in-cylinder mixture composition and temperature must be tightly controlled in order to achieve robust HCCI combustion. The control architecture and strategy that was implemented in the demo vehicles is presented in this paper. Both demo vehicles, one with automatic transmission and the other one with manual transmission, are powered by a 2.2-liter HCCI engine that features a central direct-injection system, variable valve lift on both intake and exhaust valves, dual electric camshaft phasers and individual cylinder pressure transducers.

Exhaust gas recirculation (EGR) is one of the key approaches applied to reduce emissions for an internal combustion engine. Recirculating a desired amount of EGR requires accurately estimating EGR mass flow. This can be calculated either from the gas flow equation of an orifice, or from the difference between charge air mass flow and fresh air mass flow. Both calculations need engine exhaust pressure as an input variable. This paper presents a method to estimate exhaust pressure for a variable geometry turbo charged diesel engine. The method is accurate and simple to fit production ECU application, therefore, saves cost of using a physical sensor.

Under the initiative of the United States Council for Automotive Research LLC (USCAR§) Transmission Working Group, a collaborative effort was made with LuK USA LLC to study the influence of the friction interface parameters on the shudder durability of a wet launch clutch. Clutch configurations with different combinations of four friction materials (A, B, C and D), three groove patterns (waffle, radial and waffle-parallel) and two separator plate conditions (nitrided and non-nitrided) were considered. Durability testing consisted of a test profile, with 110 kJ energy per test cycle, developed earlier in this project. Materials A, B and C with nitrided separator plates reached the end of test criteria for the torque gradient and showed shudder. Materials B and C were more wear resistant as compared to materials A and D. The loss of friction coefficient (μ) was lower for materials B, C and D as compared to material A.

A fully flexible valve actuation (FFVA) system was developed for a single cylinder research engine to investigate high efficiency clean combustion (HECC) in a diesel engine. The main objectives of the study were to examine the emissions, performance, and combustion characteristics of the engine using late intake valve closing (LIVC) to determine the benefits and limitations of this strategy to meet Tier 2 Bin 5 NOx requirements without after-treatment. The most significant benefit of LIVC is a reduction in particulates due to the longer ignition delay time and a subsequent reduction in local fuel rich combustion zones. More than a 95% reduction in particulates was observed at some operating conditions. Combustion noise was also reduced at low and medium loads due to slower heat release. Although it is difficult to assess the fuel economy benefits of LIVC using a single cylinder engine, LIVC shows the potential to improve the fuel economy through several approaches.

With increasingly stringent emissions regulations and concurrent requirements for enhanced engine thermal efficiency, a comprehensive characterization of the automotive gasoline fuel spray has become essential. The acquisition of accurate and repeatable spray data is even more critical when a combustion strategy such as gasoline direct injection is to be utilized. Without industry-wide standardization of testing procedures, large variablilities have been experienced in attempts to verify the claimed spray performance values for the Sauter mean diameter, Dv90, tip penetration and cone angle of many types of fuel sprays. A new SAE Recommended Practice document, J2715, has been developed by the SAE Gasoline Fuel Injection Standards Committee (GFISC) and is now available for the measurement and characterization of the fuel sprays from both gasoline direct injection and port fuel injection injectors.