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Diesel homogeneous charge compression ignition (HCCI) engines with early injection can result in significant spray/wall impingement which seriously affects the fuel efficiency and emissions. In this paper, the spray/wall interaction models which are available in the literatures are reviewed, and the characteristics of modeling including spray impingement regime, splash threshold, mass fraction, size and velocity of the second droplets are summarized. Then three well developed spray/wall interaction models, O'Rourke and Amsden (OA) model, Bai and Gosman (BG) model and Han, Xu and Trigui (HXT) model, are implemented into KIVA-3V code, and validated by the experimental data from recent literatures under the conditions related to diesel HCCI engines. By comparing the spray pattern, droplet mass, size and velocity after the impingement, the thickness of the wall film and vapor distribution with the experimental data, the performance of these three models are evaluated.

Modeling is of increasing significance to the automotive applications of catalyst systems. For exhaust gas after-treatment, prediction of exhaust emissions plays an important role in the design process for new vehicles. However both control and diagnosis requirements on the vehicle have created the need for control-oriented models. A control-oriented model is both compact and accurate and may be embedded in a computer system as a component of a real-time algorithm. Modeling of catalysts can take place at a molecular level where computational techniques are only just emerging. Detailed kinetics modeling done alongside thermal and fluid modeling of the catalyst yields important details about the dynamic behavior of the catalyst system. Approaches to developing control-oriented model have tended to use the simplest statements of kinetics. In general, the development of such models requires the inclusion of some chemical kinetics.