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With the increasing demand of emission reductions from the automotive industry, advanced after-treatment strategies have been investigated to overcome the challenges associated with meeting increasingly stringent emission regulations. Ongoing investigations on low temperature combustion (LTC) strategies are being researched to meet future emission regulations, however, the lowered exhaust temperature presents an even greater issue for exhaust after-treatment due to the change in combustion modes. Catalyst temperature is critical for the catalytic ability to maintain effective conversion efficiency of regulated emissions. The use of periodic flow reversal has shown benefits of maintaining catalyst temperature by alternating the exhaust flow direction through the catalytic converter, reducing the catalyst sensitivity to inlet gas temperature fluctuations.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

Reduction of nitrogen oxides (NOx) in lean burn and diesel fueled Compression Ignition (CI) engines is one of the major challenges faced by automotive manufacturers. Lean NOx Trap (LNT) and urea-based Selective Catalytic Reduction (SCR) exhaust after-treatment systems are well established technologies to reduce NOx emissions. However, each of these technologies has associated advantages and disadvantages for use over a wide range of engine operating conditions. In order to meet future ultra-low NOx emission norms, the use of both alternative fuels and advanced after-treatment technology may be required. The use of an alcohol fuel such as n-butanol or ethanol in a CI engine can reduce the engine-out NOx and soot emissions. In CI engines using LNTs for NOx reduction, the fuel such as diesel is utilized as a reductant for LNT regeneration.

In this work, empirical investigations of the diesel-ethanol Premixed Pilot-Assisted Combustion (PPAC) are carried out on a high compression ratio (18.2:1) single-cylinder diesel engine. The tests focus on determining the minimum ethanol fraction for ultra-low NOx & soot emissions, effect of single-pilot vs. twin-pilot strategies on emissions and ignition controllability, reducing the EGR requirements, enabling clean combustion across the load range and achieving high efficiency full-load operation. The results show that both low NOx and almost zero soot emissions can be achieved but at the expense of higher unburned hydrocarbons. Compared to a single-pilot injection, a twin-pilot strategy reduces the soot emissions significantly and also lowers the NOx emissions, thereby reducing the requirements for EGR. The near-TDC pilot provides excellent control over the combustion phasing, further reducing the need of a higher EGR quantity for phasing control.

Dual fuel applications of alcohol fuels such as ethanol or butanol through port injection with direct injection of diesel can be effective in reduction of NOx. However, these dual fuel applications are usually associated with an increase in the incomplete combustion products such as hydrocarbons (HC), carbon monoxide (CO), and hydrogen (H2) emissions. An analysis of these products of incomplete combustion and the resulting combustion efficiency penalty was made in the diesel ignited alcohol combustion modes. The effect of EGR application was evaluated using ethanol and butanol as the port injected fuel, with varying alcohol fractions at the mid-load condition (10 -12 bar IMEP). The impact of varying the engine load (5 bar to 19 bar IMEP) in the diesel ignited ethanol mode on the incomplete combustion products was also studied. Emission measurements were taken and the net fuel energy loss as a result of the incomplete combustion was estimated.

Diesel aided by gasoline low temperature combustion offers low NOx and low soot emissions, and further provides the potential to expand engine load range and improve engine efficiency. The diesel-gasoline operation however yields high unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions. This study aims to correlate the chemical origins of the key hydrocarbon species detected in the engine exhaust under diesel-gasoline operation. It further aims to help develop strategies to lower the hydrocarbon emissions while retaining the low NOx, low soot, and efficiency benefits. A single-cylinder research engine was used to conduct the engine experiments at a constant engine load of 10 bar nIMEP with a fixed engine speed of 1600 rpm. Engine exhaust was sampled with a FTIR analyzer for speciation investigation.

Modern diesel engines were known for producing ultra-low levels of hydrogen and hydrocarbons. However, as emission control techniques such as exhaust gas recirculation (EGR) are implemented to meet stringent NOx standards, the resulting increase in partial-combustion products can be significant in quantity both as pollutants and sources of lost engine efficiency. In this work, a modern common-rail diesel engine was configured to investigate the EGR threshold for elevated carbon monoxide, hydrocarbon, and hydrogen emissions at fixed loads and fixed heat-release phasing. It is noted that increase in hydrocarbons, in particular light hydrocarbons (such as methane, ethylene, and acetylene) was concurrent with ultra-low NOx emissions. Hydrogen gas can be emitted in significant quantities with the application of very high EGR. Under ultra-low NOx production conditions for medium and high load conditions, the light hydrocarbon species can account for the majority of hydrocarbon emissions.

Exhaust gas recirculation, fuel injection strategy and boost pressure are among the key enablers to attain low NOx and soot emissions simultaneously on modern diesel engines. In this work, the individual influence of these parameters on the emissions are investigated independently for engine loads up to 8 bar IMEP. A single-shot fuel injection strategy has been deployed to push the diesel cycle into low temperature combustion with EGR. The results indicated that NOx was a stronger respondent to injection pressure levels than to boost when the EGR ratio is relatively low. However, when the EGR level was sufficiently high, the NOx was virtually grounded and the effect of boost or injection pressure becomes irrelevant. Further tests indicated that a higher injection pressure lowered soot emissions across the EGR sweeps while the effect of boost on the soot reduction appeared significant only at higher soot levels.

A production V-8 engine was redesigned to run on low temperature combustion (LTC) with conventional Diesel fuel. Two fuel injection strategies were used to attain reduction in soot and NOx; a) early premixed injection strategy: fuel injected early during the compression stroke and b) late premixed injection strategy: fuel injected close to TDC with heavy EGR. The early premixed injection strategy yielded low NOx and soot but struggled to vaporize the fuel as noted in unburned hydrocarbons readings. The late premixed injection strategy introduced the fuel at higher in-cylinder temperatures and densities, improving the fuel's vaporization and limited the unburned hydrocarbon and carbon monoxide. The use of high EGR and high injection pressure for late premixed injection strategy provided sufficiently long ignition delay that resulted in partially premixed cylinder charge before combustion, and thereby prevented high soot, even in presence of high EGR.