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Modern diesel engines were known for producing ultra-low levels of hydrogen and hydrocarbons. However, as emission control techniques such as exhaust gas recirculation (EGR) are implemented to meet stringent NOx standards, the resulting increase in partial-combustion products can be significant in quantity both as pollutants and sources of lost engine efficiency. In this work, a modern common-rail diesel engine was configured to investigate the EGR threshold for elevated carbon monoxide, hydrocarbon, and hydrogen emissions at fixed loads and fixed heat-release phasing. It is noted that increase in hydrocarbons, in particular light hydrocarbons (such as methane, ethylene, and acetylene) was concurrent with ultra-low NOx emissions. Hydrogen gas can be emitted in significant quantities with the application of very high EGR. Under ultra-low NOx production conditions for medium and high load conditions, the light hydrocarbon species can account for the majority of hydrocarbon emissions.

Extensive empirical work indicates that the exhaust emission and fuel efficiency of modern common-rail diesel engines characterise strong resilience to biodiesel fuels when the engines are operating in conventional high temperature combustion cycles. However, as the engine cycles approach the low temperature combustion (LTC) mode, which could be implemented by the heavy use of exhaust gas recirculation (EGR) or the homogeneous charge compression ignition (HCCI) type of combustion, the engine performance start to differ between the use of conventional and biodiesel fuels. Therefore, a set of fuel injection strategies were compared empirically under independently controlled EGR, intake boost, and exhaust backpressure in order to improve the neat biodiesel engine cycles.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

Preliminary empirical and modeling analyses are conducted to evaluate the energy efficiency of in-cylinder and external fuel injection strategies and their impact on the energy required to enable diesel particulate filter (DPF) regeneration for instance. During the tests, a thermal wave that is generated from the engine propagates along the exhaust pipe to the DPF substrate. The thermal response of the exhaust system is recorded with the thermocouple arrays embedded in the exhaust system. To implement the external fuel injection, an array of thermocouples and pressure sensors in the DPF provide the necessary feedback to the control system. The external fuel injection is dynamically adjusted based on the thermal response of the DPF substrate to improve the thermal management and to reduce the supplemental energy. This research intends to quantify the effectiveness of the supplemental energy utilization on aftertreatment enabling.

Experiments are carried out with the diesel particulate filter and oxidation catalyst embedded in the active-flow configurations on a single cylinder diesel engine. The combined use of various active flow control schemes are identified to be capable of shifting the exhaust gas temperature, flow rate, and oxygen concentration to favorable windows for filtration, conversion, and regeneration processes. Empirical and theoretical investigations are performed with a transient one-dimensional single channel aftertreatment model developed in FORTRAN and MATLAB. The influence of the supplemental energy distribution along the length of aftertreatment device is evaluated. The theoretical analysis indicates that the active-flow control schemes have fundamental advantages in optimizing the converter thermal management including reduction in supplemental heating, increase in thermal recuperation, and improving overheating protection.

The exhaust emission and performance characteristics of a 100% biodiesel fuel was evaluated on a single cylinder direct injection diesel engine that had been modified to allow multi-pulse diesel fuel injection at the intake port and independent control of intake heating, exhaust gas recirculation and throttling. Firstly, conventional single-shot direct injection tests were conducted and comparisons made between the use of an ultra-low sulphur diesel fuel and the biodiesel fuel. Secondly, tests for the premixed combustion of neat biodiesel were performed. Exhaust gas recirculation was applied extensively to initiate the low temperature combustion for the conventional in-cylinder single injection operation and to moderate the timing of the homogeneous charge compression ignition for the intake-port sequential injection. Because of the high viscosity and low volatility of the biodiesel, pilot-ignited homogeneous charge compression ignition was used.

Empirical and theoretical studies are made between active-flow control and passive-flow control schemes in investigating the influences of gas flow, heat transfer, chemical reaction, oxygen concentration, and substrate properties. The exhaust active-flow control includes the parallel alternating flow, partial restricting flow, periodic flow reversal, and extended flow stagnation that are found to be especially effective to treat engine exhausts that are difficult to cope with conventional passive-flow converters [1, 2]. The tests are set up on a single cylinder Yanmar engine. Theoretical studies are performed with the one-dimensional transient modeling techniques to analyze the thermal behavior of the diesel after-treatment systems when active flow control schemes are applied.

Diesel Particulate Filters (DPF) are viable to reduce smoke from diesel engines. An oxidation process is usually required to remove the Particulate Matter (PM) loading from the DPF substrates. In cases when the engine exhaust temperature is insufficient to initiate a thermal regeneration, supplemental energy is commonly applied to raise the exhaust gas and/or the DPF substrate temperatures. A flow reversal (FR) mechanism that traps a high temperature region in the DPF substrate by periodically altering the gas flow directions has been identified to be capable of reducing the supplemental energy and thus to improve the overall thermal efficiency of the engine. However, extended operations with low exhaust temperature lowers the DPF boundary temperatures that defers the regeneration processes. Furthermore, the temperature fluctuations caused by the periodic FR operation also increase the thermal stress in the DPF.

One-dimensional transient modeling techniques are adapted to analyze the thermal behavior of lean-burn after-treatment systems when active flow control schemes are applied. The active control schemes include parallel alternating flow, partial restricting flow, and periodic flow reversal (FR) that are found to be especially effective to treat engine exhausts that are difficult to cope with conventional passive flow converters. To diesel particulate filters (DPF), lean NOx traps (LNT), and oxidation converters (OC), the combined use of active flow control schemes are identified to be capable of shifting the exhaust gas temperature, flow rate, and oxygen concentration to more favorable windows for the filtration, conversion, and regeneration processes. Comparison analyses are made between active flow control and passive flow control schemes in investigating the influences of gas flow, heat transfer, chemical reaction, oxygen concentration, and converter properties.

The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.