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Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

Compared with petroleum fuel, liquefied petroleum gas (LPG) demonstrates advantages in low CO2 emission because of propane and butane, which are the main components of LPG, making H/C ratio higher. In addition, LPG is suitable for high efficient operation of a spark ignition (SI) engine due to its higher research octane number (RON). Because of these advantages, that is, diversity of energy source and reduction of CO2, in the past several years, LPG vehicles have widely used as the alternate to gasoline vehicles all over the world. Consequently, it is absolutely essential for the performance increase of LPG vehicles to comprehend the combustion characteristics of LPG and to obtain the guideline for engine design and calibration. In this study, an LPG-SI engine was built up by converting fuel supply system of an in-line 4-cylinder gasoline engine, which has 1997 cm3 displacement with MPI system, to LPG liquid fuel injection system [1].

The object of this study is to investigate an on-board diagnostic method to detect the deterioration of a three-way catalyst (TWC) under actual vehicle operating conditions, including the acceleration state. The signal data of two oxygen sensors were processed by the fast Fourier transformation (FFT) method. As a result, we found that the power spectrum of the signal waves can be the index of catalyst deterioration degree. Furthermore, it was confirmed that the difference between the power spectrum of the upstream oxygen sensor signal and one of the downstream oxygen sensor signal named ΔPower is effective index for detection of deteriorated catalyst under acceleration conditions.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

The authors have explored the potential of fuel to control spray and its combustion processes in a diesel engine. Fuel has some potential for low emission and high thermal efficiency because its volatility and ignitability are one of the ultimate performing factors of the engines. In present study, the ignition process of mixed fuel spray was investigated in a constant volume combustion vessel and in a rapid compression and expansion machine, The ignition delay based on the diagram of rate of the heat release, the imaging of natural flame emissions and the numerical simulation were carried out to clarify the effect of the physical and chemical properties of mixed fuel on ignition characteristics.

In recent years, the dimethyl ether (DME) fuel has been attracting attention as an alternative engine in terms of diesel utilization. This is (a) because its cetane number is close to that of diesel fuel, (b) an innovative chemical process has been developed to produce DME efficiently from natural gas and coal, and (c) DME as a fuel has fewer environment-polluting characteristics than diesel fuel. Inasmuch as DME fuel have lower molecular weights, a molecular C-O bond, and are much more volatile or evaporative than diesel fuel, it is possible to control particulate matters much more easily when DME is used instead of diesel fuel. As for NOx, however, even when using DME, there still remain problems under stringent exhaust gas regulations. Developed and optimized accordingly has been the NOx storage-reduction (NSR) system, using the DME engine with a common-rail injection system. The NSR system is coated with an NOx storage catalyst principally comprised of Pt and Rh.

Fuel design for internal combustion engines has been proposed in our study. In this concept, the multicomponent fuel with high and low volatility fuels are used in order to control the spray and combustion processes in internal combustion engine. Therefore, it is necessary to understand the spray and combustion characteristics of the multicomponent fuels in detail. In the present study, the modeling of multicomponent spray vaporization was conducted using KIVA3V code. The physical fuel properties of multicomponent fuel were estimated using the source code of NIST Mixture Property Database. Peng-Robinson equation of state and fugacity calculation were applied to the estimation of liquid-vapor equilibrium in order to take account for non-ideal vaporization process. Two-zone model in which fuel droplet was divided into droplet surface and inner core was introduced in order to simply consider the temperature distribution in fuel droplet.

In this study, the novel fuel design concept has been proposed in order to realize the low emission and combustion control in engine systems. In this fuel design concept, the mixed fuels with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components) are used in order to improve the spray characteristics by flash boiling. In our previous papers on this study, the fundamental characteristics of spray and its combustion of mixed fuel were reported. In this paper, heat release and exhaust emission (smoke, NOx and THC) characteristics of single cylinder diesel engine operated with the mixed fuels were investigated under each load. The exhaust performance of diesel engine could be improved using mixed fuel, because fuel properties and spray characteristics were controlled by changing mixing fraction of the mixed fuel.

NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. We are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

It is well known that during engine cold-start, methanol fueled vehicles have a tendency to emit significant amount of unburnt methanol and formaldehyde, which is an oxidant of methanol The emission behavior and reduction methods of these components are studied in this paper The reduction rate of these unburnt components exceeds 99% when the temperature of a catalyst is enough high However during engine cold-start the oxidative reaction can not begin, and it takes several minutes to warm up the catalyst After the temperature of the catalyst reaches to the light-off temperature it rises steeply and high reduction rates of these components are obtained at the same time Therefore, the catalyst temperature must be raised quickly and effectively in order to realize the proper oxidative reduction of unburnt methanol and formaldehyde emissions during engine cold-start Consequently the effectiveness of installing pre-catalysts was examined in this study Some pre-catalysts (200cm3/piece) were placed after the exhaust manifold Results showed that within 10 minutes of initiating the idling experiment after engine cold-start the pre-catalysts were very effective and decreased emissions of the unburnt components by two thirds Moreover pre-catalysts which were electrically pre-heated with an external heater could more drastically decrease the amount of these components under the same experimental conditions However for such electrical heating to be practical it is necessary to reduce the level of heating energy to as low an amount as possible Therefore two power-saving methods were tried One method consisted of installing a glow plug in the upper stream of the pre-catalyst This method was based on an idea that unburnt components coming in contact with the glow plug are activated and easily oxidized and that they then release thermal energy for quick heating The results showed that this method was effective for reduction (more than 40%) of unburnt methanol but was ineffective for reducing formaldehyde since spot heating caused a balancing of formaldehyde formation/decomposition Therefore another method was examined A small-sized electric heated pre-catalyst(50cm3)was installed in order to heat a full section of the exhaust stream of the catalyst The results showed that this method had a great effect in reducing these harmful substances Moreover, it was demonstrated that this method consumes little energy and is more practical as a means of heating

Copper ion-exchanged ZSM-5 zeolite catalyst, which reduces nitrogen oxides (NOx) in the presence of oxygen and hydrocarbons, was applied to actual diesel engine exhaust. Copper ion-exchanged ZSM-5 zeolite effectively reduced NOx by 25% in normal engine operation, and by 80% when hydrocarbons in the exhaust were increased. Water in the exhaust gas decreased the NOx reduction efficiency, but oxygen and sulfur appeared to have only a small effect. Maximum NOx reduction was observed at 400°C irrespective of hydrocarbon species, and did not decrease with space velocity up to values of 20,000 1/h. THE PURPOSE of this paper is to evaluate the possibilities and problems in catalytic reduction of NOx in actual diesel engine exhaust. Here, a copper ion-exchanged ZSM-5 zeolite (Cu-Z) catalyst was applied to diesel engine exhaust to examine the dependency of the NOx reduction efficiency on temperature and space velocity. The effects of oxygen, water and hydrocarbons were also examined.