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The increasing need to reduce greenhouse gas emissions and shift away from fossil fuels has raised an interest for methanol. Methanol can be produced from renewable sources and can drastically lower soot emissions from compression ignition engines (CI). As a result, research and development efforts have intensified focusing on the use of methanol as a replacement for diesel in CI engines. The issue with methanol lies in the fact that methanol is challenging to ignite through compression alone, particularly at low-load and cold starts conditions. This challenge arises from methanol's high octane number, low heating value, and high heat of vaporization, all of which collectively demand a substantial amount of heat for methanol to ignite through compression.

Methanol has recently emerged as a promising fuel for internal combustion engines due to its multiple carbon-neutral production routes and advantageous properties when combusting. Methanol is intrinsically more suitable for spark-ignition (SI) operation thanks to its high octane number, but its potential in heavy-duty applications also encourages engine manufacturers in this field to retrofit their existing compression-ignition products into methanol/diesel dual-fuel (DF) operation. For both SI operation and DF operation, injecting methanol into the engine’s intake path at low pressure is a relatively simple and robust method to introduce methanol into the cylinders. However, the much higher heat of vaporization (HoV) of methanol compared to conventional SI fuels like gasoline can be a double-edged sword.

In the upcoming decade sustainable powertrain technologies will seek for market entrance in the transport sector. One promising solution is the utilization of dual-fuel engines using renewable methanol ignited by a pilot diesel fuel. This approach allows the displacement of a significant portion of fossil diesel, thereby reducing greenhouse gas emissions. Additionally, this technology is, next to newbuilds, suited for retrofitting existing engines, while maintaining high efficiencies and lowering engine-out emissions. Various researchers have experimentally tested the effects of replacing diesel by methanol and have reported different boundaries for substituting diesel by methanol, including misfire, partial burn, knock and pre-ignition. However, little research has been conducted to explore ways to extend these substitution limits.

To mitigate climate change, it is essential that sustainable technologies emerge in the transport industry. One viable solution is the use of methanol or hydrogen combined with internal combustion engines (ICEs). The dual-fuel technology in particular, in which a diesel pilot ignites port fuel injected methanol or hydrogen, is of great interest to transition from diesel engines to ICEs using purely these fuels. This approach allows for a significant portion of fossil diesel to be replaced with sustainable methanol or hydrogen, while maintaining high efficiencies and the possibility to run solely on diesel if required. Additionally, lower engine-out pollutant emissions (NOx, soot) are produced. Although multiple experimental research results are available, numerical literature on both fuels in dual-fuel mode is scarce. Therefore, this study aims to develop a multi-zone dual-fuel combustion model for engine simulations.

The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines.

An increasing need to lower greenhouse gas emissions, and so move away from fossil fuels like diesel and gasoline, has greatly increased the interest for methanol. Methanol can be produced from renewable sources and eliminate soot emissions from combustion engines [1]. Since compression ignition (CI) engines are used for the majority of commercial applications, research is intensifying into the use of methanol, as a replacement for diesel fuel, in CI engines. This includes work on dual-fuel set-ups, different fuel blends with methanol, ignition enhancers mixed with methanol, and partially premixed combustion (PPC) strategies with methanol. However, methanol is difficult to ignite, using compression alone, at low load conditions. The problem comes from methanol’s high octane number, low lower heating value and high heat of vaporization, which add up to a lot of heat being needed from the start to combust methanol [2].

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

In order to reduce the carbon footprint of the Internal Combustion Engine (ICE), biofuels have been in use for a number of years. One of the problems with first-generation (1G) biofuels however is their competition with food production. In search of second-generation (2G) biofuels, that are not in competition with food agriculture, a novel biorefinery process has been developed to produce biofuel from woody biomass sources. This novel technique, part of the Belgian federal government funded Ad-Libio project, uses a catalytic process that operates at low temperature and is able to convert 2G feedstock into a stable light naphtha. The bulk of the yield consists out of hydrocarbons containing five to six carbon atoms, along with a fraction of oxygenates and aromatics. The oxygen content and the aromaticity of the hydrocarbons can be varied, both of which have a significant influence on the fuel’s combustion and emission characteristics when used in Internal Combustion Engines.

To speed up the development of the next-generation combustion engines with renewable fuels, the importance of reliable and robust simulations cannot be overemphasized. Compared to gasoline, methanol is a promising fuel for spark-ignited engines due to its higher research octane number to resist auto-ignition, higher flame speed for faster combustion and higher heat of vaporization for intake charge cooling. These advantageous properties all contribute to higher thermal efficiency and lower knock tendency, and they need to be well-captured in the simulation environment in order to generate accurate predictions. In this paper, the sub-models which estimate the burning velocities and ignition delay of methanol are revisited. These building blocks are implemented and integrated in a quasi-dimensional simulation environment to predict the combustion behavior, which are subsequently validated against test data measured on both light-duty and heavy-duty engines.

In the challenge to reduce CO2, NOx and PM emissions, the application of natural gas or biogas in engines is a viable approach. In heavy duty and marine, either a conventional dual fuel (CDF), or a reactivity-controlled compression ignition (RCCI) approach is feasible on existing diesel engines. In both technologies a pilot diesel injection is used to ignite the premixed natural gas. However, the influence of injection-timing and -pressure on the start of combustion timing (SOC) is opposite between both modes. For a single operating point these relations can be explained by a detailed CFD simulation, but an intuitive overall explanation is lacking. This makes it difficult to incorporate both modes into one engine application, using a single controller. In an experimental campaign by the authors, on a medium speed engine, the lowest emissions were found to be very close to the SOC corresponding to the transition from RCCI to CDF.

Methanol is a promising fuel for future spark-ignition engines. Its properties enable increased engine efficiency. Moreover, the ease with which methanol can be reformed, using waste exhaust heat, potentially offers a pathway to even higher efficiencies. The primary objective of this study was to build and validate a model for a methanol fueled direct-injection spark-ignition engine with on-board fuel reforming for future investigation and optimization. The second objective was to understand the combustion characteristics, energy losses and engine efficiency. The base engine model was developed and calibrated before adding a reformed-exhaust gas recirculation system (R-EGR). A newly developed laminar burning velocity correlation with universal dilution term was implemented into the model to predict the laminar burning velocity with the presence of hydrogen in the reforming products.

In this work, the possibility to perform a cold-flow simulation as a way to improve the accuracy of the starting conditions for a combustion simulation is examined. Specifically, a dual-fuel marine engine running on methanol/diesel and natural gas/diesel fueling conditions is investigated. Dual-fuel engines can provide a short-term solution to cope with the more stringent emission legislations in the maritime sector. Both natural gas and methanol appear to be interesting alternative fuels that can be used as main fuel in these dual-fuel engines. Nevertheless, it is observed that combustion problems occur at part load using these alternative fuels. Therefore, different methods to increase the combustion efficiency at part load are investigated. Numerical simulations prove to be very suitable hereto, as they are an efficient way to study the effect of different parameters on the combustion characteristics.

Partially premixed combustion (PPC) has shown to produce high gross indicated efficiencies while yielding lower pollutant emissions, such as oxides of nitrogen and soot, than conventional diesel combustion. Gasoline fuels with a research octane number (RON) of 60-70 have been proposed as optimal for PPC as they balance the trade-off between ensuring good combustion stability at low engine loads and avoiding excessive peak pressure rise rates at high loads. However, measures have to be taken when optimizing the engine operating parameters to avoid soot emissions. In contrast, methanol has a much lower propensity for soot formation. However, due to a higher RON of methanol the required intake temperature is higher for the same engine compression ratio to ensure auto-ignition at an appropriate timing. Increasing the compression ratio allows a lower intake temperature and improves combustion stability as well as engine brake efficiency.

The present work describes the numerical modeling of medium-speed marine engines, operating in a fumigated dual-fuel mode, i.e. with the second fuel injected in the ports. This engine technology allows reducing engine-out emissions while maintaining the engine efficiency and can be fairly easily retrofitted from current diesel engines. The main premixed fuel that is added can be a low-carbon one and can additionally be of a renewable nature, thereby reducing or even completely removing the global warming impact. To fully optimize the operational parameters of such a large marine engine, computational fluid dynamics can be very helpful. Accurately describing the combustion process in such an engine is key, as the prediction of the heat release and the pollutant formation is crucial. Auto-ignition of the diesel fuel needs to be captured, followed by the combustion and flame propagation of the premixed fuel.

Partially premixed combustion (PPC) is one of several advanced combustion concepts for the conventional diesel engine. PPC uses a separation between end of fuel injection and start of combustion, also called ignition dwell, to increase the mixing of fuel and oxidizer. This has been shown to be beneficial for simultaneously reducing harmful emissions and fuel consumption. The ignition dwell can be increased by means of exhaust gas recirculation or lower intake temperature. However, the most effective means is to use a fuel with high research octane number (RON). Methanol has a RON of 109 and a recent study found that methanol can be used effectively in PPC mode, with multiple injections, to yield high brake efficiency. However, the early start of injection (SOI) timings in this study were noted as a potential issue due to increased combustion sensitivity. Therefore, the present study attempts to quantify the changes in engine performance for different injection strategies.

Partially premixed combustion (PPC) with gasoline fuels is a new promising combustion concept for future internal combustion engines. However, many researchers have argued the capabilities of research octane number (RON) and Motor Octane Number (MON) to describe the autoignition behaviour of gasoline fuels in advanced combustion concepts like PPC. The objective of this study is to propose a new method, called PPC number, to characterize the auto ignition quality of gasoline fuels in a light-duty direct injected compression ignition engine under PPC conditions. The experimental investigations were performed on a 4-cylinder Volvo D4 2 litre engine. The ignition delay which was defined as the crank angle degrees between the start of injection (SOI) and start of combustion (SOC) was used to represent the auto ignition quality of a fuel.

Low temperature combustion concepts used in compression ignition engines have shown to be able to produce simultaneous reduction of oxides of nitrogen and soot as well as generating higher gross indicated efficiencies compared to conventional diesel combustion. This is achieved by a combination of premixing, dilution and optimization of combustion phasing. Low temperature combustion can be complemented by moving away from fossil fuels in order to reduce the net output of CO2 emissions. Alternative fuels are preferably liquid and of sufficient energy density. As such methanol is proposed as a viable option. This paper reports the results from a simulation based investigation on a heavy-duty multi-cylinder direct injection compression ignition engine with standard compression ratio. The engine was simulated using two different fuels: methanol and gasoline with an octane number of 70.

Lean operation is a promising approach to increase the engine efficiency. One of the main challenges for lean-burn technology is the combustion instability. Using a high laminar burning velocity fuel such as methanol might solve that problem. The potential of lean-burn limit extension with methanol was investigated through a comparison with conventional gasoline. In this work, a direct injection turbocharged SI engine was operated at wide open throttle (WOT), with the load controlled by a lean-burn strategy. The amount of fuel was decreased (or lambda increased) until the combustion became unstable. For methanol, the lambda limit was about 1.5, higher than the lambda limit for gasoline which was only about 1.2. The brake thermal efficiency for methanol increased as lambda increased and reached its peak at ~41% in a lambda range of 1.2-1.4. Then, the efficiency decreased as lambda increased.

Low Temperature Combustion is a technology that enables achieving both a higher efficiency and simultaneously lower emissions of NOx and particulate matter. It is a noun for combustion regimes that operate with a lean air-fuel mixture and where the combustion occurs at a low temperature, such as Homogeneous Charge Compression Ignition and Partially Premixed Combustion. In this work a new model is proposed to predict the instantaneous heat flux in engines with Low Temperature Combustion. In-cylinder heat flux measurements were used to construct this model. The new model addresses two shortcomings of the existing heat transfer models already present during motored operation: the phasing of the instantaneous heat flux and the overprediction of the heat flux during the expansion phase. This was achieved by implementing the in-cylinder turbulence in the heat transfer model. The heat transfer during the combustion was taken into account by using the turbulence generated in the burned zone.

Engine optimization requires a good understanding of the in-cylinder heat transfer since it affects the power output, engine efficiency and emissions of the engine. However little is known about the convective heat transfer inside the combustion chamber due to its complexity. To aid the understanding of the heat transfer phenomena in a Spark Ignition (SI) engine, accurate measurements of the local instantaneous heat flux are wanted. An improved understanding will lead to better heat transfer modelling, which will improve the accuracy of current simulation software. In this research, prototype thin film gauge (TFG) heat flux sensors are used to capture the transient in-cylinder heat flux within a Cooperative Fuel Research (CFR) engine. A two-zone temperature model is linked with the heat flux data. This allows the distinction between the convection coefficient in the unburned and burned zone.