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Research on alternative fuels is necessary to reduce CO2 emissions. Hydrotreated Vegetable Oil (HVO) of light fuel physically improves spray and combustion characteristics. Fatty Acid Methyl Ester (FAME) is an oxygenated fuel and its combustion characteristics are chemically improved, although its spray characteristics such as penetration and atomization are deteriorated. The purpose of this study is to understand the effects of blending HVO, which has carbon neutral (CN) characteristics, with FAME, which also has CN characteristics, on spray and combustion characteristics, and to further improve emission such as THC and Smoke. This report presents the effect of the combination of improved spray characteristics and oxygenated fuel on emissions. Spray characteristics such as penetration, spray angle and spray volume were investigated by shadowgraph photography.

Fuel design concept has been proposed for low emission and combustion control in engine systems. In this concept, the multicomponent fuels, which are mixed with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components), are used for artificial control of fuel properties. In addition, these multicomponent fuels can easily lead to flash boiling which promote atomization and vaporization in the spray process. In order to understand atomization and vaporization process of multicomponent fuels in detail, the model for flash boiling spray of multicomponent fuel have been constructed and implemented into KIVA3V rel.2. This model considers the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets.

For developing complicated after-treatment equipment for diesel-engine vehicles, such as urea-selective catalytic reduction (urea-SCR) systems, construction of a reaction model that can accurately predict ammonia (NH3) formation from urea is required. Hydrolysis of isocyanic acid (HNCO) is an important intermediate reaction in NH3 formation from urea. In our previous studies [1], a new rate constant for HNCO hydrolysis over fresh Cu-ZSM5 was derived using the measurements of the reaction rate of HNCO hydrolysis with high-purity HNCO formed from cyanuric acid. In this study, the reaction rates of the HNCO hydrolysis and NH3-SCR reactions were measured over a hydrothermally aged Cu-ZSM5 catalyst. A steady-state flow reactor equipped with a Fourier transform infrared spectrometer (FTIR) was employed to obtain the reaction rate of the HNCO hydrolysis and NH3-SCR reactions.

This study employed a diesel particulate generator (DPG), with an installed engine oil injector for soot and ash accumulation in a diesel particulate filter (DPF). Ash was generated by engine oil injection into the diesel burner flame. The amount of soot accumulation per loading varied from 0.5 g/L to 8 g/L while ash accumulation amount per loading was maintained at 0.5 g/L. Initially, ash accumulation distribution in the DPF was visualized using X-ray computed tomography (CT). It was revealed that the form of ash accumulation changed depending on the amount of soot accumulation before active regeneration, i.e., a large amount of soot accumulation resulted in plug ash, whereas a small amount of soot accumulation resulted in wall ash. To clarify ash accumulation mechanisms, soot and ash transport behavior in DPF during active regeneration process was directly observed using a high-speed camera through an optically accessible D-shaped cut DPF covered with a quartz glass plate.

We have proposed the application of EGR gas dissolved fuel which might improve spray atomization through effervescent atomization instead of high injection pressure. In this paper, the purpose is to evaluate the influence of the application of CO2 gas dissolved fuel on the combustion characteristics and emissions inside the single cylinder, direct injection diesel engine. As a result, by use of the fuel, smoke was reduced by about 50 to 70%. The amount of NOx was reduced at IMEP=0.3 MPa, but it was increased at IMEP=0.9 MPa.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

White smoke emission is observed at the tailpipe of diesel vehicles when unburned hydrocarbons (HCs) are adsorbed on a diesel oxidation catalyst (DOC) under low exhaust gas temperature. The purpose of this study is to gain a better understanding of white smoke emission derived from HCs, and to reduce emission levels. First, the components of HCs and the particle size distribution of white smoke emission were analyzed. It was clarified that semi-volatile organic compounds (SVOC) and water are condensed around soluble organic fraction and the order of particle size in white smoke is submicron scale. Additionally, the correlation between the behavior of white smoke emission and the amount/quality of HCs adsorbed on a DOC were investigated by examining the change of zeolite content in the DOC. It was found that the heavy HCs ratio in adsorbed HCs on DOC increases with a decrease in zeolite content when DOC inlet gas temperature is 120 °C.

The CO2 gas dissolved fuel for the diesel combustion is effective to reduce the NOx emissions to achieve the internal EGR (Exhaust Gas Recirculation) effect by fuel. This method has supplied EGR gas to the fuel side instead of supply EGR gas to the intake gas side. The fuel has followed specific characteristics for the diesel combustion. When the fuel is injected into the chamber in low pressure, this CO2 gas is separated from the fuel spray. The distribution characteristics of the spray are improved and the improvement of the thermal efficiency by reduction heat loss in the combustion chamber wall, and reduce soot emissions by the lean combustion is expected. Furthermore, this CO2 gas decreases the flame temperature. Further, it is anticipated to reduce NOx emissions by the spray internal EGR effect.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

n-Tridecane is a low boiling point component of gas oil, and has been used as a single-component fuel for diesel spray and combustion experiments. However, no reduced chemical kinetic mechanisms for n-tridecane have been presented for three-dimensional modeling. A detailed mechanism developed by KUCRS (Knowledge-basing Utilities for Complex Reaction Systems), contains 1493 chemical species and 3641 reactions. Reaction paths during ignition process for n-tridecane in air computed using the detailed mechanism, were analyzed with the equivalence ratio of 0.75 and the initial temperatures of 650 K, 850 K, and 1100 K, which are located in the cool-flame dominant, negative-temperature coefficient, and blue-flame dominant regions, respectively.

Fuel design approach has been proposed as the control technique of spray and combustion processes in diesel engine to improve thermal efficiency and reduce exhaust emissions. In order to kwow if this approach is capable of controlling spray flame structure and interaction between the flame and a combustion chamber wall, the present study investigated ignition and flame characteristics of dual-component fuels, while varying mixing fraction, fuel temperature and ambient conditions. Those characteristics were evaluated through chemiluminescence photography and luminous flame photography. OH radical images and visible luminous flame images were analyzed to reveal flame shape aspect ratio and its fractal dimension.

Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

In this study, it is purpose to make clear the effect of cavitation phenomenon on the spray atomization. In this report, the cavitation phenomenon inside the nozzle hole was visualized and the pressure measurements along the wall of the nozzle hole were carried out by use of 25-times enlarged acrylic nozzle. For the representatives of regular gasoline, single and two-component fuels were used as a test fuel. In addition, various cavitating flow patterns same as experimental conditions were simulated by use of Barotropic model incorporated in commercial code of Star-CD scheme, and compared with experimental results.

Methyl butanoate (MB) and methyl decanoate (MD) are surrogates for biodiesel fuels. According to computational results with their detailed reaction mechanisms, MB and MD indicate shorter ignition delays than long alkanes such as n-heptane and n-dodecane do at an initial temperature over 1000 K. The high ignitability of these methyl esters was computationally analyzed by means of contribution matrices proposed by some of the authors. Due to the high acidity of an α-H atom in a carbonyl compound, hydroperoxy radicals are generated out of the equilibrium between forward and backward reactions of O₂ addition to methyl ester radicals by the internal transfer of an α-H atom in the initial stage of an ignition process. Some of the hydroperoxy methyl ester radicals can generate OH to activate initial reactions. MB has an efficient CH₃O formation path via CH₃ generated by the β-scission of an MB radical which has a radical site on the α-C atom to the carbonyl group.

This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.

LES of non-evaporative diesel spray have been performed to investigate the effects of breakup models of Modified TAB, WAVE and KHRT model on computational results. KIVALES that is LES version of KIVA code was used for base code. In our KIVALES, CIP scheme was incorporated in order to suppress the numerical diffusion. Results showed that the breakup model is significantly affected on the calculated spray shape, because the droplet diameter determined by breakup models affects on the transmittance of the droplet momentum into the ambient gas, the evolution of the vortex structure in the gas phase and the droplet dispersion by the vortex structure.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

A diesel engine operating in premixed charge compression ignition (PCCI) mode promises the reduction of engine-out emissions of NOx and particulate matter. A serious issue for PCCI operation with the early injection timing during the compression stroke is the difficulty of controlling the mixture formation process. In this study, a mixed fuel consisting of high volatility fuel and high ignitability one is applied in order to develop a control technique for the mixture preparation. In particular, we focuses on a flash boiling phenomenon of mixed fuel. For pure substance, the quality of flashing spray is dominated by the degree of superheat. In contrast, that of mixed fuel is affected much by low boiling point fuel.