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Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

The ignition of lubricating oil droplet has been proved to be the main factor for pre-ignition and the following super-knock in turbocharged gasoline direct injection engine. In this paper, the ignition process of lubricating oil droplet in combustible ambient gaseous mixture was investigated in a rapid compression machine (RCM). The pre-ignition induction by oil droplet of the ambient gaseous mixture was analyzed under different initial droplet volume and effective temperature conditions. The oil droplet was suspended on a tungsten fiber in the combustion chamber and the ignition process was recorded by a high-speed camera through the quartz window mounted at the end of the combustion chamber. The pressure traces were also obtained by a sensor in order to get the ignition delay and analyze the combustion process in detail.

Compression ratio and specific heat ratio are two dominant factors influencing engine thermal efficiency. Therefore, ultra-lean burn may be one method to deal with increasingly stringent fuel consumption and emission regulations in the approaching future. To achieve high efficiency and clean combustion, innovative combustion modes have been applied on research engines including homogeneous charge compression ignition (HCCI), spark-assisted compression ignition (SACI), and gasoline direct-injection compression ignition (GDCI), etc. Compared to HCCI, SACI can extend the load range and more easily control combustion phase while it is constrained by the limit of flame propagation. For SACI with ultra-lean burn in engines, equivalence ratio (φ), rich-fuel mixture around spark plug, and supercharging are three essentials for combustion stability.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Compressed Natural Gas (CNG), because of its low cost, high H/C ratio, and high octane number, has great potential in automotive industry, especially for heavy-duty commercial vehicles. However, relative slow flame speed of natural gas leads to long combustion duration and low thermal efficiency and tends to cause knock combustion at high load, which will aggravate engine thermal load and reliability. Enhancing turbulence intensity in combustion chamber is an effective way to accelerate flame propagation speed and improve combustion performance. In this study, the flow simulations of several piston bowls with different inner-convex forms were carried out using three-dimensional computational fluid dynamics (3D-CFD) software CONVERGE. The numerical results showed the piston bowls with inner-convex could disturb the charge swirl motion and enhance turbulence of different intensity. A hexagram geometry bowl was proved to have the best function in strengthening turbulence intensity.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

In this research, propane flash boiling sprays discharged from a five-hole gasoline direct injector were studied in a constant volume vessel. The fuel temperature (Tfuel) ranged from 30 °C to 90 °C, and the ambient pressure (Pamb) varied from 0.05 bar to 11.0 bar. Different flash boiling spray behavior compared to that under sub-atmospheric conditions was found at high Pamb. Specifically, at the sub-atmospheric pressures, the individual flashing jets merged into one single jet due to the strong spray collapse. In contrast, at Pamb above 3.0 bar and Tfuel above 50 °C, the spray collapse was mitigated and the flashing jets were separated from each other. Further analyses revealed that the mitigation of spray collapse at high Pamb was ascribed to the suppression of jet expansion. In addition, it was found that the spray structure was much different at similar Rp, indicating that Rp lacked the generality in describing the structure of flash boiling sprays.

In order to meet increasingly stringent fuel consumption and emission regulations, more attentions are paid to improve engine efficiency. A large amount of energy-saving technologies have been applied in automotive field especially in gasoline engines. It is well known that lean burn and ultra-high compression ratio technologies are two basic and important methods to increase efficiency. In this paper, a rapid compression machine was employed to study combustion process of lean iso-octane mixture at ultra-high compression ratios (16 to 19:1). Regardless of flammability of the mixture, spark was triggered at the timing right after the end of compression, then, the flame propagation and/or auto-ignition can be recorded using high-speed photography simultaneously. The effects of equivalence ratio (φ), compression ratio (ε), dilution ratio, and effective temperature (Teff) on the combustion process was investigated.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

This study compared the combustion and emission characteristics of Homogeneous Charge Compression Ignition (HCCI) and Direct Injection Compression Ignition (DICI) modes in a boosted and high compression ratio (17) engine fueled with gasoline and gasoline/diesel blend (80% gasoline by volume, denoted as G80). The injection strategy was adjusted to achieve the highest thermal efficiency at different intake pressures. The results showed that Low Temperature Heat Release (LTHR) was not observed in gasoline HCCI. However, 20% additional diesel could lower down the octane number and improve the autoignition reactivity of G80, which contributed to a weak LTHR, accounting for approximately 5% of total released heat. The combustion efficiency in gasoline DICI was higher than those in gasoline HCCI and G80 HCCI, while the exhaust loss and heat transfer loss in DICI mode were higher than those in HCCI mode.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from initial boiling point of gasoline to final boiling point of diesel. Recent experimental results have shown WDF by blending 50% gasoline and 50% diesel (G50) exhibits much lower soot emissions than diesel at medium load with similar thermal efficiency. However, the engine performances fueled by G50 at both low load end and high load end are still unknown. In this study, the combustion and emission characteristics of G50 and diesel are compared over a wide load range from 0.2 MPa IMEP to 1.4 MPa IMEP at a light-duty diesel engine. The results shown that at 0.2 MPa IMEP, G50 exhibits low combustion stability and thermal efficiency. With the increase of load, the poor combustion quality of G50 is improved. G50 can achieve soot-free combustion up to 1.0 MPa IMEP, while diesel cannot.

Natural gas is one of the promising alternative fuels due to the low cost, worldwide availability, high knock resistance and low carbon content. Ignition quality is a key factor influencing the combustion performance in natural gas engines. In this study, the effect of pre-chamber geometry on the ignition process and flame propagation was studied under varied initial mixture temperatures and equivalence ratios. The pre-chambers with orifices in different shapes (circular and slit) were investigated. Schlieren method was adopted to acquire the flame propagation. The results show that under the same cross-section area, the slit pre-chamber can accelerate the flame propagation in the early stages. In the most of the cases, the penetration length of the flame jet and flame area development are higher in the early stages of combustion.

Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.

A conceptual approach to help understand and simulate droplet induced pre-ignition is presented. The complex phenomenon of oil-fuel droplet induced pre-ignition has been decomposed to its elementary processes. This approach helps identify the key fluid properties and engine parameters that affect the pre-ignition phenomenon, and could be used to control LSPI. Based on the conceptual model, a 3D CFD engine simulation has been developed which is able to realistically model all of the elementary processes involved in droplet induced pre-ignition. The simulation was successfully able to predict droplet induced pre-ignition at conditions where the phenomenon has been experimentally observed. The simulation has been able to help explain the observation of pre-ignition advancement relative to injection timing as experimentally observed in a previous study [6].

Homogeneous Charge Induced Ignition (HCII) combustion utilizes a port injection of high-volatile fuel to form a homogeneous charge and a direct injection of high ignitable fuel near the Top Dead Center (TDC) to trigger combustion. Compared to Conventional Diesel Combustion (CDC) with high injection pressures, HCII has the potential to achieve diesel-like thermal efficiency with significant reductions in NOx and PM emissions with relatively low-pressure injections, which would benefit the engine cost saving remarkably. In the first part of current investigation, experiments were conducted at medium load with single diesel injection strategy. HCII exhibited great potential of using low injection pressures to achieve low soot emissions. But the engine load for HCII was limited by high heat release rate. Thus, in the second and third part, experiments were performed at high and low load with double diesel injection strategy.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

High boost and direct injection are effective ways for energy saving in gasoline engines. However, the occurrence of super-knock at high load has become a main obstacle for further improving power density and fuel economy. It has been known that super-knock can be induced by pre-ignition, and oil droplet auto-ignition is found to be one of the possible mechanisms. In this study, experiments were conducted in a single-cylinder thermal research engine (TRE), in which different types of oil and surrogates were directly injected into the cylinder and then led to pre-ignition and super-knock. The effect of oil injection timing, oil injection quantity, different gasoline and different oil were tested. All the oil in this work could induce pre-ignition, even though their combustion phasing was much later than that in the case of n-hexadecane.

Particle Number (PN) have already been a big issue for developing high efficiency internal combustion engines (ICEs). In this study, controlled spark-assisted stratified compression ignition (SSCI) with moderate end-gas auto-ignition was used for reducing PN in a high compression ratio gasoline direct injection (GDI) engine. Under wide open throttle (WOT) and Maximum Brake Torque timing (MBT) condition, high external cooled exhaust gas recirculation (EGR) was filled in the cylinder, while two-stage direct injection was used to form desired stoichiometric but stratified mixture. SSCI combustion mode exhibits two-stage heat release, where the first stage is associated with flame propagation induced by spark ignition and the second stage is the result of moderate end-gas auto-ignition without pressure oscillation at the middle or late stage of the combustion process.

Homogeneous Charge Induced Ignition (HCII) combustion is believed to be a promising approach to achieve clean and high efficiency combustion. HCII can be realized by using port-injection of the high-volatile fuel (gasoline) to prepare in-cylinder homogeneous charge and direct injection of the high-ignitable fuel (diesel) near the top dead center to control the start of combustion. In the current study, a numerical study was carried out to understand the mixing and auto-ignition process in HCII combustion. A multicomponent chemical kinetic mechanism for gasoline and diesel, consisting of n-heptane, iso-octane, ethanol, toluene, diisobutylene and n-decane, has been developed for predicting their ignition and oxidation. The final mechanism consists of 104 species and 398 reactions. This mechanism was validated with the experimental data of ignition delay times and laminar flame speeds for each component and real transportation fuels.

A 1-Dimensional (1-D) model of fluid dynamic and chemistry kinetics following hot spot auto-ignition has been developed to simulate the process from auto-ignition to pressure wave propagation. The role of wall effect on the physical-chemical interaction process is numerically studied. A pressure wave is generated after hot spot auto-ignition and gradually damped as it propagates. The reflection of the wall forms a reflected pressure wave with twice the amplitude of the incident wave near the wall. The superposition of the reflected and forward pressure waves reinforces the intensity of the initial pressure wave. Wall effect is determined by the distance between the hot spot center and the cylinder wall. Hot spot auto-ignition near the wall easily initiates detonation under high-temperature and high-pressure conditions because pressure wave reflection couples with chemical reactions and propagates in the mixture with high reactivity.