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India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).

With the introduction of EU6d and CN6 all vehicles with gasoline direct injection and many with port fuel injection engine will be equipped with a gasoline particulate filter (GPF). A range of first generation filter technologies has been introduced successfully, helping to significantly reduce the tailpipe particulate number emissions. The continued focus on particulate emissions and the increasing understanding of their impact on human health, combined with the advanced emission regulations under RDE conditions results in the desire for filters with even higher filtration efficiency, especially in the totally fresh state. At the same time, to balance with the requirements on power and CO2, limitations exist with respect to the tolerable pressure drop of filters. In this paper we will report on a new generation of gasoline particulate filters for uncatalyzed applications.

Gasoline particulate filter (GPF) is considered a suitable solution to meet the increasingly stringent particle number (PN) regulations for both gasoline direct injection (GDI) and multi-port fuel injection (MPI) engines. Generally, GDI engines emit more particulate matter (PM) and PN. In recent years, GDI engines have gained significant market penetration in the automobile industry owing to better fuel economy and drivability. In this study, an accelerated ash loading method was tested by doping lubricating oil into the fuel for a GDI engine. Emission tests were performed at different ash loads with different driving cycles and GPF combinations. The results showed that the GPF could significantly reduce particle emissions to meet the China 6 regulation. With further ash loading, the filtration efficiency increased above 99% and the effects on fuel consumption and backpressure were found to be limited, even with an ash loading of up to 50 g/l.

Quantitative in-use pressure measurements were taken from packaging ceramic substrates with the SoftMountSM technology and two more traditional technologies, stuffing and tourniquet. Each technology was assessed using four separate mat materials. Mat selection enhanced the application of the SoftMountSM technology through the reduced pressures applied to the substrate during packaging. High temperature and low temperature thermal cycling studies were performed on the canned converters for the three packaging technologies so that an evaluation could be made of converter durability. The SoftMountSM packaging technology yielded the lowest pressures of all the processes studied, regardless of mat type. The laminar hybrid mat evaluated yielded the best combination of pressure and durability performance. Low temperature residual shear strengths following thermal cycling of the converters showed good correlation between the SoftMountSM technology and the stuffing method.

An analytical model for estimating shear and bending stresses during canning of cordierite ceramic catalyst supports is presented. These stresses arise when the radial pressure distribution is nonuniform due, primarily, to variations in gap bulk density (GBD ) of intumescent mat around the perimeter of the substrate. Variations in GBD can occur during canning, regardless of the canning technique, due to anisotropic can stiffness or component tolerances or mat overlap. The model helps relate shear and bending stresses to substrate size and orientation, elastic modulii, cell size and wall porosity. If these stresses approach the corresponding strength of substrate, a shear crack may develop during or after the canning process depending on the magnitude of stress. A special test fixture was developed to measure the shear strength of ceramic catalyst supports, with different cell sizes, before and after the application of washcoat.

This paper focuses on the effect of temperature on biaxial strength of curved, symmetrically laminated, automotive windshields. In view of their aspheric curvature, the measurement of biaxial strength requires a special ring-on-ring test fixture with compliant loading and support rings. The key factors that affect strength are (i) fatigue behavior of surface flaws, (ii) expansion mismatch between glass and PVB interlayer, and (iii) interfacial bond integrity. These, in turn, depend on the operating temperature which for automotive windshields can range from −40°C in winter to +50°C in summer. The data show that the biaxial strength is 21% higher at −40°C and 28% lower at +50°C than that at room temperature. An assessment of fatigue and interfacial bond integrity shows that strength changes of these magnitudes are predominantly caused by residual stresses arising from expansion mismatch between glass and PVB interlayer.

One approach to the remediation of NOx generated under lean automotive engine conditions is its controlled storage and then periodic release and reaction under enriched conditions. This process is being considered for automotive exhaust systems that will be operated pre–dominantly lean for reasons of fuel economy. Because of the special characteristics of alkali and alkaline earth elements in the presence of NOx, they are being considered for use, in conjunction with γ–alumina–based washcoats and precious metal catalysts, as NOx catalyst coatings on cellular supports. It is known that alumino–silicates will react with alkali and alkaline earth elements to form stable ceramic phases when mixtures of the components are held in direct contact at elevated temperatures.

The monolithic, large frontal area (LFA), extruded ceramic substrates for diesel flow-through catalysts offer unique advantages of design versatility, longterm durability, ease of packaging and low Cost [1, 2]*. This paper examines the effect of cell density and cell size on catalyst light-off performance, back pressure, mechanical and thermal durability, and the steady-state catalytic activity. The factors which affect these performance characteristics are discussed. Certain trade-offs in performance parameters, which are necessary for optimum systems design, are also discussed. Following a brief discussion of design methodology, substrate selection, substrate/washcoat interaction and packaging specifications, the durability data for ceramic flow-through catalysts are summarized. A total of over 18 million vehicle miles have been successfully demonstrated by ceramic LFA catalysts using the systems design approach.

High temperature modulus of rupture (MOR) data, published previously, show that the ceramic catalyst supports get stronger with temperature due to the absence of water vapor and closure of microcracks which would otherwise act as stress concentrators [1, 2 and 3]*. The increased MOR value is partially responsible for the excellent durability of ceramic catalyst supports at high temperature. In this paper, we will present the compressive strength data of ceramic substrates at high temperature, namely the crush strength along B-axis and biaxial compressive strength of the whole substrate. Since the honeycomb strength is directly related to that of the individual cell wall, the compressive strength should also increase with temperature similar to the modulus of rupture. Accordingly, the ceramic substrates are capable of supporting higher mounting pressures exerted by the intumescent mat at high temperature [4].

The motorcycle emissions regulations for both two-stroke and four-stroke engines, which are receiving worldwide attention, will go into effect in the very near future. To meet these regulations, the motorcycles will require a catalyst in conjunction with the muffler due to space limitations. The combination of high engine speeds, high vibrational acceleration, high HC and CO emissions, high oxidation exotherms, and stringent durability requirements, points to cordierite ceramic substrate as an ideal catalyst support. However, as an integral unit within the muffler, its packaging design must be capable of withstanding isothermal operating conditions which may exceed the upper intumescent temperature limit of the ceramic mat. This paper describes a durable packaging design for the ceramic catalyst which employs a hybrid ceramic mat, special end rings and gaskets, and high strength stainless steel can.

The stringent durability requirements approaching 100,000 vehicle miles for automotive substrates and 290,000 vehicle miles for large frontal area diesel substrates for 1994+ model year vehicles call for advanced packaging designs with thick ceramic mats and high mount densities. The latter result in high mounting pressure on the substrate and enhance its mechanical integrity against engine vibrations, road shocks and back pressure forces. A novel measurement technique which applies a uniform biaxial compressive load on the lateral surface of ceramic substrates, thereby simulating canning loads, is described. The biaxial compressive strength data obtained in this manner help determine the maximum mounting pressure and mat density for a durable packaging design. The biaxial compressive strength data for both round and non round substrates with small and large frontal area are presented.