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Journal Article

Se (IV)-Doped Monodisperse Spherical TiO2 Nanoparticles for Adhesively Bonded Joint Reinforcing: Synthesis and Characterization

2024-04-27
Abstract This study focused on the synthesis and characterization of monodisperse spherical TiO2 nanoparticles doped on the surface with Se (IV) in order to increase the mechanical properties of the bonded joint reinforcing. Work will begin with the synthesis of monodisperse quasi-spherical TiO2 nanoparticles with a modal diameter of less than 20 nm, using the sol-gel technique. Se (IV) selenium surface doping changed the specimen’s chemistry and physics. Different initial concentrations of the doping element will be tested. Next, a physicochemical characterization of the different solid systems will be carried out in order to determine the effect of the doping element on the properties of titanium dioxide. Their morphology and size will be studied through transmission electron microscope observations; volume chemical composition by X-ray diffraction analysis, EDX (energy-dispersive X-ray), and XRF (X-ray fluorescence).
Journal Article

Microstructural and Corrosion Behavior of Thin Sheet of Stainless Steel-Grade Super Duplex 2507 by Gas Tungsten Arc Welding

2024-03-21
Abstract Super duplex stainless steel (SDSS) is a type of stainless steel made of chromium (Cr), nickel (Ni), and iron (Fe). In the present work, a 1.6 mm wide thin sheet of SDSS is joined using gas tungsten arc welding (GTAW). The ideal parameter for a bead-on-plate trial is found, and 0.216 kJ/mm of heat input is used for welding. As an outcome of the welding heating cycle and subsequent cooling, a microstructural study revealed coarse microstructure in the heat-affected zone and weld zone. The corrosion rate for welded joints is 9.3% higher than the base metal rate. Following the corrosion test, scanning electron microscope (SEM) analysis revealed that the welded joint’s oxide development generated a larger corrosive attack on the weld surface than the base metal surface. The percentages of chromium (12.5%) and molybdenum (24%) in the welded joints are less than those in the base metal of SDSS, as per energy dispersive X-ray (EDX) analysis.
Journal Article

100 Years of Corrosion Testing—Is It Time to Move beyond the ASTM D130? The Wire Corrosion and Conductive Deposit Tests

2023-09-22
Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.
Journal Article

Effect of Silicon Carbide/Tungsten Carbide on Mechanical and Corrosion Properties of Aluminum 6061 Hybrid Metal Matrix Composites

2023-07-04
Abstract Aluminum hybrid composites are driving a new trend in metal matrix composites for high strength-to-weight ratio applications such as the automotive industry (piston–cylinder, brakes, shafts), aircraft (engines, airframe), aerospace (space panels), and marine (body frame). Al 6061 is chosen as the matrix for its compatibility and excellent castability in the current work. The reinforcements were silicon carbide (SiC) of size 65μ and tungsten carbide (WC) of 3–5μ due to their enhancing mechanical and corrosion behavior with low density. Composites were prepared through stir casting using different quantities of SiC wt.% 10 and 15, while WC is 0–6% by weight in 2% increments. The results show that mechanical properties such as tensile strength and hardness enhanced due to the gradual strengthening of grains leads to high wear resistance. SEM images of tensile failure show that pits, voids, cracks, burrs, and grain fractures characterize composite failure.
Journal Article

Predicting Mechanical Properties of Friction Welded AISI 1020/AISI 1018 Steel and AISI 431/AISI 1018 Steel Joints

2023-01-05
Abstract The joining of dissimilar AISI 1020/AISI 1018 steel and AISI 431/AISI 1018 steel carries significant importance in automotive applications to lower the cost of manufacturing and obtain the mechanical properties of different materials. However, the joining of these materials by fusion welding is difficult particularly for a rod-to-plate joint configuration such as solidification cracking, wider heat affected zone (HAZ), HAZ softening, high residual stresses, and distortion of joint configuration. So, to overcome the issues in fusion welding of AISI 1020/AISI 1018 steel and AISI 431/AISI 1018 steel, rotary friction welding (RFW) was employed to develop the rod-to-plate joints. The parametric empirical relationships (PERs) were developed using regression equations incorporating RFW parameters to predict tensile strength (TS) and weld interface hardness (WIH) of rod-to-plate joints.
Journal Article

Friction Stir Welding of Aluminum Lithium Alloys: Experimental Investigation of Mechanical Characteristics Using Grey Relational Theory

2022-12-06
Abstract In the current research, an aluminum alloy AA8090 is welded using the friction stir welding (FSW) technique. The main objective is to eliminate the chances of defects in the weld joint, which were observed in the conventional joining process. Experiments were planned according to the one factor at a time (OFAT) approach. The input process parameters involved during the present work are welding speed (WS), rotational speed (RS), tilt angle (TA), and dwell time (DT). However, the response variables investigated at different input parametric combinations are tensile strength (TS), percentage elongation (EL), microhardness (MH), and macroscopic structure. Due to the combination of both attributes of optimization (the higher the better in TS and the lower the better in EL), the multi-performance quality characteristics optimization approach, i.e., grey relational analysis (GRA), is implemented.
Journal Article

Understanding Conductive Layer Deposits: Test Method Development for Lubricant Performance Testing for Hybrid and Electric Vehicle Applications

2022-11-07
Abstract Advances in hybrid vehicles and electric vehicles (EV) are creating a need for a new generation of lubricants and new lubricant performance tests. Copper corrosion is one prominent concern for hybrid vehicles and EVs and is routinely assessed using a coupon test. This is characterized as metal dissolution, a surface tarnish, or a corrosion layer where a corrosion product remains on the surface and is characterized by a qualitative visual rating. This deficiency does not provide insight into the nature of the corrosion deposit. In an electric drive unit, there are multiple sources of the electric potential present, which can significantly alter the formation of a corrosion deposit which is not assessed in the coupon tests. The formation of a conductive corrosion deposit can result in catastrophic failure of the electric drive unit, either through direct shorting of the motor winding or failure of the power electronics.
Journal Article

Machine Learning Models for Weld Quality Monitoring in Shielded Metal Arc Welding Process Using Arc Signature Features

2022-05-31
Abstract Welding is a dominant joining process employed in fabrication industries, especially in critical areas such as boiler, pressure vessels, and marine structure manufacturing. Online monitoring of welding processes using sensors and intelligent models is increasingly used in industries for predicting weld conditions. Studies are conducted in a Shielded Metal Arc Welding (SMAW) process using sound, current, and voltage sensors to predict the weld conditions. Sensor signatures are acquired from the good weld and defective weld conditions established in this study. Signal processing is carried out, and time-domain statistical features are extracted. Statistical features are also extracted from the power waveform derived from the current and voltage data for all the weld conditions. Classification And Regression Tree (CART) and Support Vector Machine (SVM) algorithms are used to build the statistical models to predict the weld conditions.
Journal Article

Investigation of Hot Corrosion Behavior on QE22A-Magnesium Silver Alloy through Steaming Method

2022-03-03
Abstract The hot corrosion studies for the die-casted magnesium (Mg) silver (Ag) alloys are carried out through the steam heating route. The Magnesium Silver (QE22A) alloy is fixed under the top lid of the pressure cooker (2 liters) and filled with water and 5% salt (NaCl) solution. The specimens are treated with different time intervals (10, 20, and 30 minutes), with the steam temperature maintained at 100°C around the specimen. The results showed an increase in the corrosion rate with the increase in the steaming time. Further, after the specimens have cooled down to room temperature, similar experiments are repeated for the second and third cycles. Here the formation of the oxide layers over the specimen has reduced the corrosion rate. The structural, surface study was carried out through scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive spectroscopy (EDS) to know the corrosion behavior on the specimen.
Journal Article

TOC

2021-12-08
Abstract TOC
Journal Article

Effect of Ball Milling on the Tensile Properties of Aluminum-Based Metal Matrix Nanocomposite Developed by Stir Casting Technique

2021-06-16
Abstract Combining ball milling with stir casting in the synthesis of nanocomposites is found effective in increasing the strength and ductility of the nanocomposites. In the first step, the nanoparticles used as reinforcement are generated by milling a mixture of aluminum (Al) and manganese dioxide (MnO2) powders. A mixture of Al and MnO2 powders are mixed in the ratio of 1:2.4 by weight and milled at 300 rpm in a high-energy planetary ball mill for different durations of 120 min, 240 min, and 360 min to generate nano-sized alumina (Al2O3) particles. It is supposed that the powders have two different roles during milling, firstly, to generate nano-sized Al2O3 by oxidation at the high-energy impact points due to collision between Al and MnO2 particles, and secondly, to keep nano-sized Al2O3 particles physically separate by the presence of coarser particles.
Journal Article

Effect of Fuel-to-Air Ratio on Oxidation and Interfacial Structure in Galvanizing of a Dual-Phase Steel

2021-04-19
Abstract Automotive-grade high-strength steels are galvanized for improved corrosion resistance. However, selective oxidation of alloying elements during annealing heat-treatment may influence the subsequent zinc (Zn) coating quality. The formation of internal and external oxides depends on the alloy composition, especially the Si/Mn ratio, and the oxygen potential of the annealing atmosphere. In this work, a dual-phase (DP) steel was intercritically annealed with varied fuel-to-air ratios in a direct-fired furnace and then galvanized in a Zn bath with 0.2 wt% Al. The type of internal and external oxides and the interfacial structures between the steel substrate, the Al-Fe-Zn inhibition layer, and the Zn coating were examined by using site-specific focused ion beam (FIB) and transmission electron microscopy (TEM).
Journal Article

Microstructural Characterization and Hot Corrosion Behavior of Plasma-Sprayed Fe17Cr2Ni0.18C/Fly Ash Cenosphere-Based Composite Coating

2021-03-12
Abstract The current investigation studies the microstructure and high-temperature hot corrosion behavior of plasma-sprayed coatings. The composition of Fe17Cr2Ni0.18C and fly ash cenosphere powder is maintained in the 0%, 5%, 10%, and 15% ratio by weight percent, respectively. Both powder mixtures were thoroughly blended correspondingly and coated on T22 boiler steel tubings. Thermocyclic hot corrosion studies were examined in a liquid salt condition of Na2SO4—60% V2O5 for 17 cycles of 51 h at 600°C on bare and coated steels. Thermogravimetric practice was used to establish the kinetics of hot corrosion of uncoated and coated steels. As-coated samples are studied for microstructure and microhardness. X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive spectroscopy, and X-ray mapping characterization techniques have been utilized for structural analysis of the as-coated and hot-corroded samples.
Journal Article

Repairing Volume Defects of Al-Cu Alloy Joints by Active-Passive Filling Friction Stir Repairing

2020-11-12
Abstract In this study, active-passive filling friction stir repairing (A-PFFSR) process was employed to repair the volume defects in friction stir welding (FSW) joints of Al-Cu alloy. The volume defects with varied geometries were first machined into taper holes, which are similar to keyhole defect by a rotational tool with a threaded pin. Then, the keyhole defect was effectively filled with the materials around the keyhole and an additional filler using a number of nonconsumable pinless tools with the shoulders having six spiral flutes. The macro/microstructures, microhardness, and tensile properties of the repaired joints were investigated. The influences of plunge speed on macro/microstructures and mechanical properties of the repaired joints have been analyzed too. It was noticed that decreasing plunge speed was effective to improve the frictional heat and material flow, which increased joint surface integrity avoiding interfacial drawbacks.
Journal Article

Establishing Long-Term Corrosion Protection of Copper-Based Alloys in Modern Transmissions

2020-11-11
Abstract Automatic transmissions utilize solenoids to manage the flow of transmission fluid throughout the transmission and engage the appropriate clutches during a gear change. Because of the small clearances between sliding interfaces in a solenoid, compatibility between materials and fluids is essential to long-term functionality. The accumulation of films formed from corrosive species on these components can lead to premature failure. Copper (Cu) corrosion strip tests are found in almost all lubricant specifications; however, they do not necessarily provide assurances in the field. Long-duration, powered solenoid soak tests are undertaken to evaluate the long-term functionality of the transmission. The complexity of oil-based corrosion mechanisms, including the temperature dependence of these processes, can be difficult to evaluate even with this advanced level of testing.
Journal Article

Susceptibility of Aluminum Alloy 7075 T6 to Stress Corrosion Cracking

2020-09-22
Abstract One of the most important aluminum (Al) alloys among the 7XXX series is 7075 in the T6 temper condition. However, 7075 T6 alloy is proven to be susceptible to stress corrosion cracking (SCC) and has caused many service failures of airplanes. In this research, the susceptibility of 7075 T6 alloys to SCC is approached according to many variables of stress, sodium chloride (NaCl) concentration, pH variation, and aeration. The testing method selected was the three-point bending under complete immersion for a period of 40 days. The results indicate that the threshold for SCC in 7075 T6 alloy lies between 220 and 340 MPa in environments containing as low as 0.5% NaCl concentrations in both neutral and acid solutions. The cracking direction found was different from the expected using other techniques such as tensile or notched specimens, which opens a new gate for testing and monitoring SCC in the 7XXX series.
Journal Article

Materials and Technologies for Lightweighting of Structural Parts for Automotive Applications: A Review

2020-09-14
Abstract Reducing the weight of automotive components is one of the most achievable solutions for lowering the transport carbon footprint. This is the reason for the rapid increase over the last few years in the replacement of conventional alloys (i.e., steel and cast iron) with low-density materials (i.e., aluminum alloys, composites) and in the redesign of components shape in order to remove the unnecessary material (e.g., related to the introduction of additive manufacturing or high-strength materials). Despite this general trend, the use of higher-density metals and massive geometries is still predominant in the production of structural components, especially for heavy vehicles and safety-relevant parts. Aim of the present review is to summarize how this current situation can be overcome. The analysis started with an investigation about the materials that can be used for the production of structural parts, the potential reduction of the component weight and its costs.
Journal Article

Enabling Dissimilar Joining of Coated Steels to Aluminum through Impact Spot Welding

2020-09-09
Abstract Direct welding of coated steels to aluminum alloys is challenging due to high energy requirements, decreased weldability, and unstable weld quality. The present study reports the application of a new design approach in vaporizing foil actuator welding (VFAW), where an asymmetric preform shape on the target sheet generated the requisite standoff, enabling direct spot welding of a typical automotive aluminum alloy (6022 T4) and two different zinc-coated steels, galvanized high-strength low-alloy 350 and galvannealed dual-phase 590. The use of the new approach enabled for the first time the ability to spot weld through coating without any preweld surface preparation. Characterization using lap-shear and peel testing revealed strong joints for both the weld pairs (AA 6022 T4-HSLA 350 and AA 6022 T4-DP 590). The weld interface characterized by scanning electron microscopy (SEM) revealed a hierarchical structure and the presence of a typical wavy region.
Journal Article

Development of a Thin-Wall Magnesium Automotive Door Inner Panel

2020-08-11
Abstract Cast magnesium (Mg) door inner panels can provide a good combination of weight, functional, manufacturing, and economical requirements. However, several challenges exist including casting technology for thin-wall part design, multi-material incompatibility, and relatively low strength versus steel. A project was supported by the US Department of Energy to design and develop a lightweight frame-under-glass door having a thin-wall, full die-cast, Mg inner panel. This development project is the first of its kind within North America. The 2.0 mm Mg design, through casting process enablers, has met or exceeded all stiffness and side-impact requirements, with significant mass reduction and part consolidation. In addition, a corrosion mitigation strategy has been established using industry-accepted galvanic isolation methods and coating technologies. The performance of the Mg design has been demonstrated through component and vehicle tests.
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