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It is well known that ethanol can be used in spark-ignition (SI) engines as a pure fuel or blended with gasoline. High enthalpy of vaporization of alcohols can affect air-fuel mixture formation prior to ignition and may form thicker liquid films around the intake valves, on the cylinder wall and piston crown. These liquid films can result in mixture non-homogeneities inside the combustion chamber and hence strongly influence the cyclic variability of early combustion stages. Starting from these considerations, the paper reports an experimental study of the initial phases of the combustion process in a single cylinder SI engine fueled with commercial gasoline and anhydrous ethanol, as well as their blend (50%vol alcohol). The engine was optically accessible and equipped with the cylinder head of a commercial power unit for two-wheel applications, with the same geometrical specifications (bore, stroke, compression ratio).

Alternative diesel fuels from renewable sources (biodiesels) have increased significantly interest due to their potential CO₂ emission benefits, capability to reduce unburned hydrocarbons and particulate matter emissions, biodegradability and non-toxicity. Biodiesels undergo ageing effects due to autoxidation processes of their molecular chains. Ageing leads to a variety of decomposition products like peroxides, alcohols, aldehydes and carboxylic acids. They are detectable as alterations of chemical properties, odor and taste (rancidity). The characteristics of Rapeseed Methylester (RME), RME aged and diesel sprays have been analyzed for different injection strategies in engines. The tests have been performed on a Bosch second generation common rail solenoid-driven fuel injection system capable of 160 MPa maximum injection pressure, fitted on EURO5 diesel engine for passenger car applications.

This paper reports the study of the effects of alternative diesel fuel and the impact for the air-fuel mixture preparation. The injection process characterization has been carried out in a non-evaporative high-density environment in order to measure the fuel injection rate and the spatial and temporal distribution of the fuel. The injection and vaporization processes have been characterized in an optically accessible single cylinder Common Rail diesel engine representing evaporative conditions similar to the real engine. The tests have been performed by means of a Bosch second generation common rail solenoid-driven fuel injection system with a 7-holes nozzle, flow number 440 cc/30s @100bar, 148deg cone opening angle (minisac type). Double injection strategy (pilot+main) has been implemented on the ECUs corresponding to operative running conditions of the commercial EURO 5 diesel engine.

The match among the increasing performance demands and the stringent requirements of emissions and the fuel consumption reduction needs a strong evolution in the two-wheel vehicle technology. In particular, many steps forward should be taken for the optimization of modern small motorcycles and scooters at low engine speeds and high loads. To this aim, detailed understanding of thermo-fluid dynamic phenomena that occur in the combustion chamber is fundamental. In this work, low-cost solutions are proposed to optimize ported fuel injection spark ignition (PFI SI) engines for two-wheel vehicles. The solutions are based on the change of phasing and on the splitting of the fuel injection in the intake manifold. The experimental activities were carried out in the combustion chamber of a single-cylinder 4-stroke optical engine fuelled with European commercial gasoline. The engine was equipped with a four-valve head of a commercial scooter engine.

High spatial and temporal resolution optical techniques were applied in a spark ignition (SI) engine in order to investigate the thermal and fluid dynamic phenomena occurring during the combustion process. The experiments were realized in the combustion chamber of an optically accessible single-cylinder port-fuel injection (PFI) SI engine. The engine was equipped with a four-valve head and with an external boost device. Two fuel injection strategies at closed-valve and open-valve occurring at wide open throttle were tested. Cycle-resolved digital imaging was used to follow the flame kernel growth and flame front propagation. Moreover, the effects of an abnormal combustion due to the firing of fuel deposition near the intake valves and on the piston surface were investigated. Natural emission spectroscopy in a wide wavelength range from ultraviolet to infrared was applied to detect the radical species that marked the combustion phenomena in the selected operating conditions.

The flame front propagation in normal and abnormal combustion was investigated. Cycle-resolved flame emission imaging was applied in the combustion chamber of a port fuel injection boosted spark ignition engine. The engine was fuelled with a mixture of 90% iso-octane and 10% n-heptane by volume (PRF90). The effect of fuel injection phasing was studied. The combustion process was followed from the flame kernel formation until the opening of the exhaust valves. Different phenomena correlated to the abnormal combustion were analysed. Detailed information on ignition surfaces, end-gas auto-ignitions and knock were obtained. The appearance of autoignition centres in the end gas was evaluated in terms of timing, location and frequency of occurrence.

An experimental evaluation of the impact of the diesel/biodiesel blends is presented in terms of engine performances and pollutant emission analysis. In-cylinder combustion evolution and injection law characterization were carried out on a single cylinder engine, on an optical single cylinder engine and on an injection test rig. Different diesel/biodiesel blends were tested at three operating points, representative of the NEDC cycle. Increasing the biodiesel percentage a reduction mainly in terms of smoke emission was observed. The engine performance as well as the other pollutant emissions were not substantially changed. Therefore this study confirms the benefits of the biodiesel use also on the current automotive engines, reducing simultaneously their environmental impact in terms of GHG and smoke emissions.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367°C and the half conversion of CO reached at 141°C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

A satisfactory answer to the future severe normative on emissions and to the market request for spark ignition engines seems to be the use of downsized engines for passenger cars. Downsizing permits the increase in engines power and torque without the increase in cylinder capacity. The downsizing benefits are evident at part loads; on the other hand, more work should be done to optimize boosted engines at higher and full load. To this goal, a detailed knowledge of the thermo-fluid dynamic processes that occur in the combustion chamber is fundamental. The aim of this paper is the experimental investigation of the effect of the fuel injection in the intake manifold on the combustion process and pollutant formation in a boosted spark ignition (SI) engine. The experiments were performed on a partially transparent single-cylinder port fuel injection (PFI) SI engine, equipped with a four-valve head and boost device.

Four perovskite catalysts LaBO3 (B = Cr, Mn, Fe, Ni), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS, TEM, O2-TPD and CO-TPR analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-LaNiO3 showed the best performance with a peak carbon combustion temperature of 431 °C and the half conversion of CO reached at 156 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

Several Li-Cr delafossite catalysts were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, characterized and tested as catalysts for the combustion of diesel soot. These catalysts already showed appreciable activity at 350 °C even under loose contact conditions. An in situ SCS method was tailored to the preparation of a LiCr0.9O2 -catalyzed trap based on a SiC wall-flow monolith. Engine bench tests on these catalytic traps showed that the presence of the catalyst enabled both a more complete regeneration and a one-third fold reduction of the regeneration time compared to the case of a non-catalytic trap.

The growing demands on fuel economy and always stricter limitations on pollutant emissions has increased the interest in the ignition phenomena to guarantee successful flame development for all the spark ignition (SI) engine operating conditions. The initial size and the growth of the flame have a strong influence on the further development of the combustion process. In particular, for the new FIAT generation of turbocharged SI engines, the first times of spark ignition combustion are not yet fully understood. This is mainly due to the missing knowledge concerning the detailed physical and chemical processes taking place during the all set of the flame propagation. These processes often occur simultaneously, making difficult the interpretation of measurements. In the present paper, flame dynamic was followed by UV-visible emission imaging in an optical SI engine.

Aim of this work is to develop a general purpose model for combustion and knocking prediction in SI engines, by coupling a thermo-fluid dynamic model for engine simulation with a general detailed kinetic scheme, including the low-temperature oxidation mechanism, for the prediction of the auto-ignition behavior of hydrocarbons. A quasi-D approach is used to describe the in-cylinder thermodynamic processes, applying the conservation of mass and energy over the cylinder volume, modeled as a single open system. The complex chemistry model has been embedded into the code, by using the same integration algorithm for the conservation equations and the reacting species, and taking into account their mutual interaction in the energy balance. A flame area evolution predictive approach is used to evaluate the turbulent flame front propagation as function of the engine operating parameters.

The modern common rail Diesel engines are normally optimised for being fuelled with the commercial Diesel fuel. Consequently, the ECU calibrations are defined to realize the best compromise between performances and emissions. If the engine is fuelled with an alternative biofuel with different characteristics (net heating value, stoichiometric A/F ratio, density, viscosity, etc.) it is clear that the calibration must be modified. Interest in fuels from renewable sources and their use in transportation has grown over the last decade. This is because of their biodegradability, potential improvements in exhaust emissions and benefits on the virtuous CO2 cycle of the earth. This paper demonstrates that it is possible to optimise emissions and performances of a light duty C.R. Diesel engine fuelled with a vegetable derived fuel (Rapeseed Methyl-Ester) pure or blended with commercial Diesel fuel.

Nano-structured bulk Li-substituted La-Cr perovskites were prepared, characterized, tested in comparison with the reference LaCrO3. The progressive increase in the Li content of the catalysts induces an increase in the catalytic activity owing to the enhancement of the amount of weakly chemisorbed oxygen O-species, key players in the soot oxidation mechanism. However, beyond 20% Cr substitution with Li, part of this latter metal was segregated as LiCrO2. The best single-phase catalyst (La0.8Cr0.8Li0.2O3) was already active well below 350°C. Catalytic traps were prepared by in situ combustion synthesis within cordierite and SiC wall-flow filters on the basis of the above catalysts and tested on real diesel exhaust gases in an engine bench, fully confirming the encouraging results obtained on powder catalysts.

This paper illustrates the results of an experimental investigation on the liquid fuel spray from a multi-jet common rail injection system both under non evaporative and evaporative conditions. Tests have been taken using a 5 hole, 0.13 mm diameter, 150° spray angle, micro-sac nozzle having a flow rate of 270 cm3/30 sec@10 MPa exploring different injection strategies. Experiments have been taken, under non evaporative conditions, injecting the fuel within stagnant inert gas, at different density, in a high-pressure optically-accessible cylindrical vessel with three large quartz windows. Under evaporative conditions, the experiments have been taken within a crank-case scavenged single-cylinder 2-stroke direct injection Diesel engine provided of optical accesses to the combustion chamber. It allows to study the fuel injection process under thermodynamic conditions similar to those currently reached in modern direct injection diesel engines.

Interest in fuels from renewable sources and their use in transport has grown over the last decade. This is because of their biodegradability, potential improvements in exhaust emissions and benefits on the virtuous CO2 cycle of the earth. Biodiesel fuels can be derived from rapeseed, sunflowers, and other kind of seeds or from UFO (Used Fried Oil). This paper analyses the results of an experimental study fuelling a Common Rail Diesel Engine with a 100% rapeseed Biofuel, with a blend of rapeseed and UFO biodiesel and compares it with commercial diesel fuel Other papers by the same authors compared the different physic-chemical characteristics of biofuels, against diesel fuel and the consequent different spray characteristics that affect the combustion phenomenon. These characteristics are correlated with the different performances and emissions obtained in the experimental activity when a modern Common Rail light duty diesel engine is adopted.

This paper illustrates the results of an experimental characterization of a high pressure diesel spray injected by a common rail (CR) injection system both under non-evaporative and evaporative conditions. Tests have been made injecting the fuel with a single hole injector having a diameter of 0.18 mm with L/D=5.56. The fuel has been sprayed at 60, 90 and 120 MPa, with an ambient pressure ranging between 1.2 to 5.0 MPa. The spray evolution has been investigated, by the Mie scattering technique, illuminating the fuel jet and acquiring single shot images by a CCD camera. Tests under non-evaporative conditions have been carried out in an optically accessible high pressure vessel filled with inert gas (N2) at diesel-like density conditions. The instantaneous fuel injection rate, obtained with a time resolution of 10 microseconds, has been also evaluated by an AVL Fuel Meter working on the Bosch Tube principle.

The paper aims at providing information about the spray structure and its evolution within the combustion chamber of a heavy duty direct injection (HDDI) diesel engine. The spray penetration is investigated, firstly under quiescent conditions, injecting the fuel in a vessel under ambient temperature and controlled back pressure by both numerical and experimental analyses using the STAR-CD code and the imaging technique, respectively. Experimental results of fuel injection rate, fuel penetration, and spray cone angle are used as initial conditions to the code and for the comparison of predictions. The experimental investigation is carried out using a mechanical injection pump equipped by the heavy duty eight cylinder engine. Only one of its plungers has been activated and the fuel is discharged through a seven holes mechanical injector, 0.40 mm in diameter.

The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.