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This paper describes cyclic Air/Fuel ratio (AFR) measurements carried out with a novel device (fUEGO) based on a production Universal Exhaust Gas Oxygen sensor, but modified to give an improved frequency response. The results are compared to AFR calculated from a fast CO/CO2 analyser and a fast response flame ionization detector (FID). The direct comparison of the two different methods for determining the cyclic AFR reveals that the electrochemical device is in reasonable agreement with the more complex carbon balance method and can provide reliable cyclic AFR measurements with a reduced requirement for equipment and data post processing. The fUEGO however is sensitive to elevated levels of uHC's (unburned hydrocarbons) during misfires or partial burns and readings during such situations usually show deviations compared to the carbon balance method.

A fast response NO detector has been developed to study fast transient emissions from internal combustion engines. The device combines the standard ChemiLuminescence Detector (CLD) measurement technique used in conventional NO detectors with the rapid sampling system of an existing Fast Flame Ionisation Detector (FFID) hydrocarbon detector. The 10-90% response time of the fast NO detector is approximately 3 milliseconds and enables resolution of transient NO concentration within individual engine cycles. Both the fast NO and fast HC detectors were fitted in the exhaust port of a firing SI engine. With the probe tips at the same position, simultaneous fast transient NO and HC concentration data have been recorded during steady state and transient engine load conditions. Cycle-by-cycle NO concentration, HC concentration, and cylinder pressure are compared and features of the transient NO and HC concentration are discussed.

The Fast-response Flame Ionisation Detector is used to measure levels of un-burnt hydrocarbons in the cylinder and exhaust of engines. Its fast response allows uHC emission processes to be resolved within an engine cycle. This paper describes a method for obtaining even greater detail by post-processing the output of the device using a Finite-Impulse Response (FIR) digital filter. The specification of the filter can be obtained by understanding the flow regimes within the sampling system. Examples from in-cylinder and exhaust sampling are presented with suggestions for implementation and further improvement.

Fast Response Flame Ionisation Detectors can be used to observe events within the combustion chamber of engines to help understand the processes by which hydrocarbons escape combustion. In order to understand the timing of events it is necessary to establish the transit time of the measuring system, in particular the times associated with gas transport through the sampling capillaries. To this end, a quasi steady state flow model has been developed to evaluate the transit time for all parts of the cycle. These predictions can deviate significantly from those using steady-state assumptions. Experimental validation is presented.

A fast-response FID has been used to study the concentration of hydrocarbon material at four different locations in a firing SI engine. These were: on the flat surface of the cylinder head, at the exhaust valve seat crevice, just downstream of the exhaust seat in the exhaust port and 20mm downstream from the valve stem in the exhaust manifold. A close-fitting sleeve arrangement enabled the sample tube to be positioned accurately flush with the head face and also to be slid away from the wall into the bulk gases whilst maintaining a gas-tight seal. In this way, wall effects could be noted by moving the probe position without stopping the engine and directly comparing with hydrocarbon levels in the bulk gas. Using propane in a fully-warmed up engine, results showed the presence of HCs residing in a 2mm layer adjacent to the wall after EVO and during the exhaust stroke. These could be detected flowing over the valve seat after EVO and were also observed at the manifold location.

Hydrocarbon wall quenching has been studied using a 19mm diameter, 1m long combustion tube, open at one end. Mixtures of propane, heptane, iso-octane and gasoline, initially quiescent, were burnt with the ignition source at the closed end. The post-flame HC levels were measured at a series of axial locations using a fast FID. The results indicate that the effective quench layer thickness increases significantly as the molecular weight of the fuel is increased. The diffusion/mixing time constant of the quench layer was found to be approximately 0.1s for propane, 0.4s for iso-octane and 1.0s for gasoline. The axial variation of residual HC levels suggests that flame stretch is a factor influencing the extent of the quench layer.

Using a novel, high frequency response FID unit, hydrocarbon measurements in the spark plug gap of a firing gasoline engine have been made. These measurements have been correlated with the pressure development, and a significant correlation was found. The method described can be used on any engine fitted with a modified sparking plug.